4.7 Article

Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2•2H2O polymeric chain (4-L1 = mono-N (4-picolyl)cyclen)

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 13, Issue 11, Pages 1314-1316

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2010.07.024

Keywords

Coordination polymer; Bridging ligand; Functionalized macrocycle ligand; Copper(II) complexes

Funding

  1. CNRS (Centre National de la Recherche Scientifique)
  2. University of Brest
  3. European Union [D35-WG-0011-05]
  4. Region Bretagne

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A new coordination complex [Cu(4-L1)](NO3)(2)center dot 2H(2)O (1) based on the functionalized cyclen mono-N (4-picolyl)cyclen (4-L1) has been prepared and characterized by X-ray diffraction. The structure of 1 can be described as a monodimensional coordination polymer in which the macrocycle ligand acts as bridging ligand. Examination of the inter-chain distances revealed the presence of hydrogen bonds between oxygen atoms of the nitrate anions and the hydrogen atoms of two secondary amines of the macrocycle ligands, affording isolated double-chain units. The overall structure of 1 consists of alternating succession of cationic layers of infinite double-chain units and anionic nitrate-water H-bonded layers. (C) 2010 Elsevier B.V. All rights reserved.

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