4.7 Article

Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane

Journal

INORGANIC CHEMISTRY
Volume 53, Issue 17, Pages 8851-8853

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic5015972

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Funding

  1. MICINN [CTQ2008-00061/BQU]
  2. Universidad de Alcala [UAH GC2013-002]
  3. Factoria de Cristalizacion (CONSOLIDER-INGENIO)
  4. MEC
  5. UAH

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The treatment of [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(4)] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(3)(mu(3)-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].

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