4.7 Article

Iodine Capture by Hofmann-Type Clathrate NiII(pz)[NiII(CN)4]

Journal

INORGANIC CHEMISTRY
Volume 53, Issue 9, Pages 4269-4271

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic500048z

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Funding

  1. ANR [ANR-AA-RMNP-003-01]
  2. University of Montpellier II
  3. CNRS

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The thermally stable Hofmann-type clathrate framework Ni-II(pz)[Ni-II(CN)(4)] (pz = pyrazine) was investigated for the efficient and reversible sorption of iodine (I-2) in the gaseous phase and in solution with a maximum adsorption capacity of 1 mol of I-2 per 1 mol of Ni-II(pz)[Ni-II(CN)(4)] in solution.

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