Journal
INORGANIC CHEMISTRY
Volume 50, Issue 20, Pages 9918-9920Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic2010858
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- Grants-in-Aid for Scientific Research [23750141] Funding Source: KAKEN
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A new complex, [Re6S8Cl5PPY](3-) (PPY = 4-phenylpyridine), was synthesized and characterized. The complex showed red emission at 296 K in both the crystalline phase and CH3CN. The transient absorption spectrum of [Re6S8ClsPPY](3-) revealed that the emissive excited state involved the {Re-6(mu(3)-S)(8)} core-to-ligand charge-transfer character.
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