4.7 Article

Fc-Fc Electronic Interaction through Equatorial Pathways of a Diruthenium Core

Journal

INORGANIC CHEMISTRY
Volume 49, Issue 4, Pages 1322-1324

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic902378h

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Funding

  1. National Science Foundation [CHE 0715404]
  2. Purdue Research Foundation

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Diruthenium compounds bearing one (3) and two (4) ferrocene carboxylate ligands were prepared and characterized, and the electronic coupling between two equatorially adjacent Fc centers in compound 4 is significant, but weaker than those between Fc centers placed on the opposite axial sites.

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