Journal
INORGANIC CHEMISTRY
Volume 49, Issue 4, Pages 1304-1306Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic902298y
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Funding
- National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0747587] Funding Source: National Science Foundation
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We prepared three structurally related (Mn3Mn2II)-Mn-III complexes that possess S approximate to 1 - 11 spin ground states as a result of variations in the geometry and identity of mu(2)-eta(1):eta(1) bridging groups. These complexes function as single-molecule magnets yet demonstrate other interesting behavior such as quasi-classical magnetization hysteresis and comparable magnetization reversal barriers (U-eff).
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