Article
Chemistry, Inorganic & Nuclear
Gavriilia T. Papanikolaou, Konstantinos N. Pantelis, Gerasimi Lazari, Luis Cunha-Silva, Albert Escuer, Theocharis C. Stamatatos
Summary: The use of Me3SiN3 in CuII chemistry led to the formation of an unusual 1-D coordination polymer composed of {Cu6(N3)12} repeating units, with metal ions bridged exclusively by mu-3-1,1,1 and mu-1,1 end-on N3- groups. Spectroscopic data support the presence of end-on azides and d-d transitions, while magnetic susceptibility measurements revealed an antiferromagnetic response in the repeating units of the polymer. This synthetic approach shows flexibility in generating purely inorganic-bridged coordination complexes and has potential applications in various fields such as molecular magnetism, catalysis, and photochemistry.
Article
Chemistry, Multidisciplinary
Qian Xie, Yongjie Cui, Zeng Chen, Ming Zhang, Chao Liu, Haiming Zhu, Feng Liu, Christoph J. J. Brabec, Xunfan Liao, Yiwang Chen
Summary: A series of random polymers with different surface electrostatic potential distributions were designed and applied in organic solar cells. The introduction of optimized structural units led to higher charge generation probability, conversion efficiency, and device stability.
Article
Chemistry, Inorganic & Nuclear
Olaf Stefanczyk, Kunal Kumar, TingYun Pai, Guanping Li, Shin-ichi Ohkoshi
Summary: The design and synthesis of high-dimensional materials based on secondary building blocks (SBUs) are crucial for the development of functional molecular materials. This study presents the synthesis of two new isostructural three-dimensional systems and investigates their magnetic and optical properties.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Meng-Yao Chao, Qing Li, Wen-Hua Zhang, David J. Young
Summary: Secondary building units in metal-organic frameworks, such as the linear trinuclear SBUs denoted as M-3, are essential both structurally and in terms of performance. While M-3 clusters are common, they are rarely discussed as a class and exhibit unprecedented metal diversity and ligand tolerance. Some M-3-based MOFs are stable under demanding conditions and can be used in applications like flue gas separation.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Xueyue Yu, Jiaming Gu, Xinyao Liu, Zhiyong Chang, Yunling Liu
Summary: Different secondary building units and N-rich organic ligand 4,4 & PRIME;,4 & DPRIME;-s-triazine-1,3,5-triyltri-p-aminobenzoate were assembled to construct six MOF materials and investigate the catalytic effects of different Lewis acid sites in the CO2 cycloaddition reaction. Compound 2, with larger pore sizes and multiple active sites, showed the best catalytic performance among the six compounds and outperformed many reported MOF-based catalysts. The comparison also revealed that Cu-paddlewheel and Zn4O exhibited better catalytic performances than In3O and Zr-6 cluster.
INORGANIC CHEMISTRY
(2023)
Review
Chemistry, Physical
Jun Guo, Xiaomin Xue, Haibin Yu, Yulong Duan, Fangfang Li, Ye Lian, Yi Liu, Meiting Zhao
Summary: Metal-organic frameworks (MOFs) are inorganic-organic hybrids composed of organic ligands and discrete metal ions/metallic secondary building units (SBUs). MOFs based on infinite SBUs (ISBUs) have shown unique physical and chemical properties. This review summarizes the synthesis methods and crystallographic structures of various ISBU MOFs, compares their properties with traditional MOFs, and highlights recent progress in gas adsorption and separation, energy conversion, photocatalysis, etc.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Review
Chemistry, Multidisciplinary
Sandip Mukherjee, Partha Sarathi Mukherjee
ACCOUNTS OF CHEMICAL RESEARCH
(2013)
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Chemistry, Multidisciplinary
Sandip Mukherjee, Partha Sarathi Mukherjee
CHEMICAL COMMUNICATIONS
(2014)
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Chemistry, Multidisciplinary
Dipak Samanta, Sandip Mukherjee, Yogesh P. Patil, Partha Sarathi Mukherjee
CHEMISTRY-A EUROPEAN JOURNAL
(2012)
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Chemistry, Multidisciplinary
Sandip Mukherjee, Partha Sarathi Mukherjee
CHEMISTRY-A EUROPEAN JOURNAL
(2013)
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Chemistry, Multidisciplinary
Bharat Kumar Tripuramallu, Sandip Mukherjee, Samar K. Das
CRYSTAL GROWTH & DESIGN
(2012)
Article
Chemistry, Multidisciplinary
Sandip Mukherjee, Dipak Samanta, Partha Sarathi Mukherjee
CRYSTAL GROWTH & DESIGN
(2013)
Article
Chemistry, Multidisciplinary
Sandip Mukherjee, Partha Sarathi Mukherjee
CRYSTAL GROWTH & DESIGN
(2014)
Article
Chemistry, Multidisciplinary
Bijan Roy, Sandip Mukherjee, Partha Sarathi Mukherjee
Article
Chemistry, Inorganic & Nuclear
Sandip Mukherjee, Yogesh P. Patil, Partha Sarathi Mukherjee
DALTON TRANSACTIONS
(2012)
Article
Chemistry, Inorganic & Nuclear
Sandip Mukherjee, Partha Sarathi Mukherjee
DALTON TRANSACTIONS
(2013)
Article
Chemistry, Inorganic & Nuclear
Soumavo Ghosh, Sandip Mukherjee, Piya Seth, Partha Sarathi Mukherjee, Ashutosh Ghosh
DALTON TRANSACTIONS
(2013)
Article
Chemistry, Inorganic & Nuclear
Sandip Mukherjee, Bappaditya Gole, You Song, Partha Sarathi Mukherjee
INORGANIC CHEMISTRY
(2011)
Article
Chemistry, Inorganic & Nuclear
Rituparna Biswas, Sandip Mukherjee, Paramita Kar, Ashutosh Ghosh
INORGANIC CHEMISTRY
(2012)
Article
Chemistry, Inorganic & Nuclear
Sandip Mukherjee, Yogesh P. Patil, Partha Sarathi Mukherjee
INORGANIC CHEMISTRY
(2012)
Article
Chemistry, Multidisciplinary
Koushik Acharyya, Sandip Mukherjee, Partha Sarathi Mukherjee
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2013)