Journal
INORGANIC CHEMISTRY
Volume 49, Issue 7, Pages 3095-3097Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic100323e
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Funding
- National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1011748] Funding Source: National Science Foundation
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Transition-metal-catalyzed decaborane alkyne hydroboration reactions have been developed that provide high-yield routes to the previously unknown di- and monoalkenyldecaboranes. These alkenyl derivatives should be easily modified starting materials for many biomedical and/or materials applications. Unusual catalyst product selectivity was observed that suggests quite different mechanistic steps, with the reactions catalyzed by the [RuCl2(p-cymene)](2) and [Cp*IrCl2](2) complexes giving the beta-E alkenylde-caboranes and the corresponding reactions with the [Rul(2)(p-cymene)](2) complex giving the a-alkenyldecaborane isomers.
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