Article
Chemistry, Physical
Ning Li, Gang Wu, Shibo Xi, Fengxia Wei, Ming Lin, Jinjun Qiu, Jin-Cheng Zheng, Jiabao Yi, Debbie Hwee Leng Seng, Coryl Jing Jun Lee, D. V. Maheswar Repaka, Xiaoming Liu, Zicong Marvin Wong, Qiang Zhu, Shuo-Wang Yang, He-Kuan Luo
Summary: In this article, a pair of isostructural graphene-like 2D coordination polymers (GCPs) synthesized by the coordination of benzenehexathiol (BHT) ligands with Cu(I) and Cu(II) ions, respectively, is reported. Spectroscopic characterizations indicate the coexistence of Cu(I) and Cu(II) in both GCPs with a near 1:1 ratio and a fractional oxidation state of +1.5 on average, forming a unique pair of Creutz-Taube mixed-valence 2D structures. Density functional theory calculations uncover an intramolecular pseudo-redox mechanism where the radicals on BHT ligands can oxidize Cu(I) or reduce Cu(II) ions upon coordination, leading to isostructures with distinct electron configurations. This study demonstrates for the first time that Cu(I) or Cu(II) can be used to achieve 2D isostructures, suggesting the possibility of neutral periodic structures hosting different numbers of total electrons as ground states, which may have implications for 2D materials.
Review
Biochemistry & Molecular Biology
Yingman Sun, Xiaodi Jiang, Yiwei Liu, Dong Liu, Chen Chen, Chengyu Lu, Shuze Zhuang, Abhinav Kumar, Jianqiang Liu
Summary: Metal organic frameworks (MOFs) are versatile materials with interesting chemical and structural properties, finding applications in various fields such as catalysis, sensing and drug delivery. Among them, copper-based MOF nanomaterials have unique biological activity and potential in medicine, especially in the treatment of cancer and other diseases.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Olaya Gomez-Paz, Rosa Carballo, Ana B. Lago, Inmaculada Prieto, Ezequiel M. Vazquez-Lopez
Summary: Three coordination compounds were synthesized and characterized from the reaction of copper(ii) bromide with the flexible bis-tetrazole organosulfur ligand, 1,2-bis(1-methyl-1H-tetrazole-5-ylthio)ethane (bmtte). Different reaction conditions led to the formation of polymeric 2 & INFIN;Cu2Br4(bmtte) (1), trinuclear [Cu3Br4(bmtte)(2)] (2), and tetranuclear [Cu2Br2(bmtte)](2) (3) compounds with different structures. The thermal stability, aqueous behavior, and reactivity of the compounds were investigated, and a new polymeric compound (8Cu4I4)-Cu-2(bmtte)(2) (4) was prepared through solid-state reaction and microwave irradiation. The redox behavior of the compounds was analyzed by cyclic voltammetry.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Zeliang Cheng, Pinyue Zhang, Ziyang Wang, Haicheng Jiang, Wenjian Wang, Dandan Liu, Lina Wang, Guangshan Zhu, Xiaoqin Zou
Summary: A Cu(I) coordinated COF membrane is designed for C3H6/C3H8 separation, which exhibits high porosity and crystallinity. The COF MMMs blended with 6FDA-DAM polymer show selective and permeable separation of C3H6, with significantly improved performance compared to other reported COF MMMs.
Article
Chemistry, Multidisciplinary
Ping Lu, Zhaoyang Qi, Jie Chen, Changshen Ye, Ting Qiu
Summary: A new method of using Ce(III) as a molecular scalpel to modulate the microenvironment of metal-organic frameworks (MOFs) is proposed for high-efficiency adsorption of aromatic sulfur-containing compounds from liquid hydrocarbon fuels. This method results in the fabrication of abundant high-efficiency Cu(I) and Cu-unsaturated coordination sites and improvement of the pore structures, leading to superior adsorptive capacities compared to other materials. The molecular engineering of MOFs shows great potential for adsorption desulfurization.
Article
Chemistry, Inorganic & Nuclear
Yu-Mei Wan, Hai-Xia Zhang, Jian Zhang
Summary: The new Cu(I) based boron imidazolate framework, BIF-105, exhibited efficient photocatalytic performance for CO2 reduction with high selectivity for CO under visible light irradiation.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Zhen-Zhen Xue, Yi-Lin Wang, Yue Zhang, Guang-Yu Fan, Song-De Han, Jie Pan
Summary: In this study, two isostructural Cu(I)-organic frameworks with hybrid layered structures and three-dimensional supramolecular frameworks were successfully synthesized. The prepared solids exhibited excellent chemical stability and sorption performance, making them promising adsorbents with high efficiency and selectivity.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Wei-Jie Zhang, Wan-Tao Chen, Chen-Hui Li, Wen-Zhu Sun, Jia-Wen Ye, Ling Chen, Hai-Ping Wang, Xiao-Ming Chen
Summary: In this study, a flexible Cu(I)-CP was developed for fast and reversible detection of CH2Cl2 through luminescence response. The material showed a quick response time of 11 seconds and distinguished the presence of CH2Cl2 with a reversible change in luminescence. Crystallographic analysis revealed that the luminescence response of the material was correlated with the effect of CH2Cl2 on the CuMIDLINE HORIZONTAL ELLIPSISCu distance.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Engineering, Environmental
Seung-Ik Kim, Ah-Reum Kim, Hyun Jin Bae, Seo-Yul Kim, Seenu Ravi, Ki Chul Kim, Youn-Sang Bae
Summary: Developing styrene selective adsorbents is crucial in petrochemical industry. The Cu(I)-loaded MOF demonstrates remarkable performance with high ST/EB selectivity and uptake, showing potential for ST/EB separation. This Cu(I) incorporation strategy may pave a new way for styrene selective adsorbents development.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Mei-Mei Wang, Yun-Ke Cui, Jia-Tai Wen, Yan-Shan Wang, Meng-Hui Jia, Shu-Zhen He, Wei-Kang Wang, Juan Xu
Summary: In this study, copper oxide catalysts derived from metal-organic frameworks were successfully synthesized, and the switching between radical and nonradical mechanisms in persulfate activation process was achieved by varying the annealing temperature. The obtained catalysts demonstrated high performance in the degradation of bisphenol A, with the synergy of radical and nonradical mechanisms. This work provides new insights into flexibly regulating persulfate activation mechanisms via rational catalysts design.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Inorganic & Nuclear
Despoina Andriotou, Sylvain Duval, Christophe Volkringer, Angel M. Arevalo-Lopez, Pardis Simon, Herve Vezin, Thierry Loiseau
Summary: The reactivity of 2,3-pyridine-dicarboxylic acid and 2,5-pyridine-dicarboxylic acid as complexing agents towards the niobium(IV) tetrachloride precursor has been investigated, resulting in the isolation of four crystalline coordination complexes. The complexes exhibit stable coordination structures formed by the interaction between the ligands and the niobium(IV) center.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Despoina Andriotou, Sylvain Duval, Christophe Volkringer, Angel M. Arevalo-Lopez, Pardis Simon, Herve Vezin, Thierry Loiseau
Summary: The reactivity of 2,3-pyridine-dicarboxylic and 2,5-pyridine-dicarboxylic acids as ligands towards the niobium(IV) tetrachloride precursor was studied, resulting in the formation of four crystalline mononuclear coordination complexes with different molecular arrangements. Each complex showed an eightfold coordination of the niobium(IV) center and exhibited unique structural characteristics. Magnetic measurements, EPR and XPS were used to analyze the d(1) configuration of the niobium(IV) centers, revealing an anti-ferromagnetism transition at very low temperatures for certain complexes.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Jing Wu, Yunli Wang, Jin-Peng Xue, Dapeng Wu, Jia Li
Summary: A novel Cl-decorated trinuclear-Cu cluster-based MOF (NbU-7-Cl) was synthesized using a stepwise synthesis strategy, allowing for the design and modification of multifunctional materials. The insertion of chloride ions alters the symmetry and adsorption energy, resulting in improved adsorption capacity and separation performance.
INORGANIC CHEMISTRY
(2023)
Article
Multidisciplinary Sciences
Li-Hao Xu, Shen-Hui Li, Heng Mao, Yan Li, Ao-Shuai Zhang, Sen Wang, Wei-Min Liu, Jing Lv, Tao Wang, Wei-Wei Cai, Le Sang, Wen-Wen Xie, Chan Pei, Zheng-Zheng Li, Ying-Nan Feng, Zhi-Ping Zhao
Summary: This study presents a strategy to create highly flexible metal-organic framework nanosheet membranes for alcohol-water separation. The membranes exhibited ultrafast transport channels and achieved high flux and separation performance.
Article
Chemistry, Physical
Gerson J. Leonel, Cameron B. Lennox, Joseph M. Marrett, Tomislav Friscic, Alexandra Navrotsky
Summary: This study investigates the effect of changes to the divalent metal node on the thermodynamic stability of zeolitic imidazolate frameworks. The use of nodes with larger ionic radius metals stabilizes the porous sodalite topology. Contrary to popular belief, the 2D frameworks are energetically stable, shedding light on the energetic landscape of these materials.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Physical
Nour Dissem, Najmeddine Ferhi, Thierry Maris, Adam Duong
Summary: Four new coordination polymers of mixed ligands have been synthesized and characterized. These polymers exhibit high thermal stability and show different structures, with hydrogen bonds playing a significant role in structure formation.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Organic
Aaron Gabriel Nunez Avila, Benoit Deschenes-Simard, E. Joseph Arnold, Mathieu Morency, Daniel Chartrand, Thierry Maris, Gilles Berger, Graeme M. Day, Stephen Hanessian, James D. Wuest
Summary: The nitrogen-rich compound 6-azidotetrazolo[5,1-a]phthalazine (ATPH) exhibits high polymorphism and diverse molecular organization due to its ability to form various N-H···N and C-H···N interactions. Crystal structures of ATPH reveal a polymorphic landscape with stacked sheets and herringbone packing. Exploring this landscape provides insights into fields such as energetic materials and molecular crystallization.
JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Rafal Wysokinski, Wiktor Zierkiewicz, Mariusz Michalczyk, Thierry Maris, Steve Scheiner
Summary: The arrangement and interaction of [PdCl4](2-) dianions in a crystal are studied and analyzed by quantum calculations. It is found that the interaction is highly repulsive with a large positive interaction energy, but the repulsion can be reduced by placing ligands nearby. When the ligands acquire a positive charge, it indicates an exothermic association. Increasing the charge on the counterions does not significantly enhance stability, and in fact, reduces the electrostatic attraction. The ability of counterions to promote the interaction is attributed to the hydrogen bonds they form with dianions.
Article
Chemistry, Organic
Sebastien Neron, Mathieu Morency, Liguo Chen, Thierry Maris, Dominic Rochefort, Radu Iftimie, James D. Wuest
Summary: Benzoquinones and 4,4'-diphenoquinones are attractive candidates for green carbon-based batteries. Although diphenoquinones are less explored, they have been synthesized and characterized. Experimental and computational studies show that diphenoquinones form chains or sheets in the solid state and have higher reduction potentials compared to benzoquinones. These findings are important for the development of carbon-based electrochemical devices.
JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Khaoula Chair, Cesar Augusto Luna Caceres, Sanil Rajak, Olivier Schott, Gustavo E. Ramirez-Caballero, Thierry Maris, Garry S. Hanan, Adam Duong
Summary: Carbon dioxide is an important trace gas in the atmosphere and its high concentration leads to serious issues. The use of solar energy for the photochemical reduction of CO2 is a promising strategy, but it faces challenges that need to be addressed for it to become a sustainable alternative for fuel and chemical generation. In this study, molecular photocatalysts were designed and demonstrated remarkable photocatalytic properties for CO2 reduction to CO. The mechanistic pathways of the reaction were investigated using a combination of structural characterization, experimental data, and density functional theory calculations.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Norbert M. Villeneuve, Joshua Dickman, Thierry Maris, Graeme M. Day, James D. Wuest
Summary: Mixed crystals are formed when components of the structure are randomly replaced by analogues, and their properties can be adjusted by changing the ratio of components. However, there are no clear rules to predict when two compounds can form mixed crystals. Through various methods, it has been discovered that mixed crystals can have compositions and properties that vary continuously over wide ranges. The results of experiments and computational modeling show that predictions about mixed crystallization can be made reliably.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Multidisciplinary
Adela Abidi, Emmanuelle Fortin, Kariane Larocque, Mohamed Essalhi, Nour Dissem, Daniel Chartrand, Thierry Maris, Adam Duong
Summary: In this paper, a facile method was reported for synthesizing eight structurally diverse compounds 1-8 with a hydrogen bonding functional group - diaminotriazine (DAT) along with pyridine and polyether groups for 1-4 and DAT linked via C-C bond to a 2-pyridone for 5-8. The successful synthesis of 1-8 was confirmed by various analytical techniques. The molecular structures and aggregations in the solid state of these compounds were elucidated using single crystal X-ray diffraction.
Article
Chemistry, Organic
Sebastien Neron, Mathieu Morency, Cedric Malveau, Thierry Maris, Radu Iftimie, James D. Wuest
Summary: This study explores the formation of diphenoquinhydrone, a compound similar to quinhydrone, and demonstrates that the intermolecular interactions in diphenoquinhydrone are stronger than in simple quinhydrone analogues. These findings illustrate that the principles of modular construction underlying the formation of classical quinhydrone can be applied to the synthesis of a broad range of hydrogen-bonded charge-transfer materials with designed component positioning.
JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Mohamed Essalhi, Midhun Mohan, Nour Dissem, Najmedinne Ferhi, Adela Abidi, Thierry Maris, Adam Duong
Summary: In this study, two new metal-organic frameworks with square and rhombic microchannels were synthesized for CO2 capture. These materials showed high CO2 uptakes and demonstrated strong non-covalent interactions with CO2 molecules. They also exhibited excellent CO2 selectivity for gas mixtures, with IRH-7 showing a remarkable increase in selectivity compared to IRH-6.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Crystallography
Babacar Mbaye, Mouhamadou Birame Diop, Mouhamadou Sembene Boye, Thierry Maris, Aminata Diasse-Sarr, Libasse Diop
Summary: A dinuclear complex with two aqua-n-butyltinhydroxide dichloride bridges was obtained. The hydroxide bridges exhibited a static trans effect in the compound. Additional hydrogen bond patterns contributed to the formation of a 3D structure in the crystal.
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
(2023)
Article
Multidisciplinary Sciences
Amin Morteza Najarian, Filip Dinic, Hao Chen, Randy Sabatini, Chao Zheng, Alan Lough, Thierry Maris, Makhsud I. I. Saidaminov, F. Pelayo Garcia de Arquer, Oleksandr Voznyy, Sjoerd Hoogland, Edward H. H. Sargent
Summary: In this study, an organic scaffold was used to influence the geometric arrangement and electronic configuration of perovskite structures, resulting in the suppression of lone pair expression and templating symmetric octahedra. This design principle was extended to copper perovskite and quasi-two-dimensional systems. The resulting perovskite photodiodes exhibit improved performance compared to non-octahedral and lead analogues.
Article
Materials Science, Multidisciplinary
Yuxuan Che, Muhammad Rizwan Niazi, Ting Yu, Thierry Maris, Cheng-Hao Liu, Dongling Ma, Ricardo Izquierdo, Igor F. F. Perepichka, Dmytro F. F. Perepichka
Summary: We investigated nitrofluorene derivatives as adjustable electron-withdrawing groups for non-fullerene acceptors of the acceptor-donor-acceptor type. We reported their optoelectronic properties and performance in bulk heterojunction solar cells with PBDB-T donor polymer. Introducing up to four nitro groups to the fluorene unit resulted in deeper frontier orbital levels, reduced HOMO-LUMO gap, and red-shifted absorption bands. The best device performance was achieved with trinitrofluorene acceptors containing a solubilizing ester group, striking a balance between decreased voltage and increased photocurrent. The 2D brickwork packing of the tetranitrofluorene derivative, as determined by single crystal X-ray analysis, differed from the interpenetrating 3D network found in high-efficiency acceptors of the acceptor-donor-acceptor type, which might be the reason for the relatively poor charge transport properties. Steric hindrance between benzothiadiazole and nitrofluorene units could be alleviated by the use of furan linkers, which planarized the conjugated backbone but decreased solubility.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Organic
Johann O. E. Sosoe, Cedric Malveau, Thierry Maris, Radu Iftimie, James D. Wuest
Summary: In this study, we conducted a comprehensive investigation on benzene-1,2,4,5-tetramine (BTA), its oxidized form BTA-H-2, and related compounds using various methods. We obtained key insights into their properties and expect that these findings will accelerate the development of their applications in the field of materials science.
JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Mohamed Essalhi, Midhun Mohan, Gabriel Marineau-Plante, Adrien Schlachter, Thierry Maris, Pierre D. Harvey, Adam Duong
Summary: Various lanthanide metal-organic networks were synthesized and their structures and optical properties were studied. The results showed that the use of specific ligands can enhance the luminescent properties of the coordinated metal centers.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Nolwenn Paugam, Yves Pouliot, Gabriel Remondetto, Thierry Maris, Guillaume Brisson
Summary: This study characterized and compared the mechanisms of calcium phosphate precipitation in skimmed milk ultrafiltration permeate (MP) and MP preconcentrated by reverse osmosis (ROMP). The results showed that ROMP increased the rate of precipitated ions, especially calcium and phosphorus, in MP. Alkalinization and heating also significantly increased the precipitation of salts and transformed the calcium phosphate structure into complex forms.