4.7 Article

•NO2-Mediated meso-Hydroxylation of Iron(III) Porphyrin

Journal

INORGANIC CHEMISTRY
Volume 48, Issue 5, Pages 1790-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic800864w

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Funding

  1. CSIR, New Delhi, India
  2. DST, New Delhi, India

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(NO2)-N-center dot generated from (NO)-N-center dot and air add to iron(III) porphyrin upon nitration, which isomerized spontaneously to hydrolysis, yielding a meso-hydroxylated cation that seized by the end oxidation product, a nitrate ion, through extensive hydrogen bonding.

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