Journal
INORGANIC CHEMISTRY
Volume 48, Issue 12, Pages 5187-5194Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic9000973
Keywords
-
Categories
Funding
- National Science Foundation [CHE 0715404, CHE 0541766]
- Natural Sciences and Engineering Research Council of Canada
Ask authors/readers for more resources
A new N,N'-bidentate ligand, 2-(3-isobutoxyanilino)pyridine (H(i)BuOap), was introduced and used as the ancillary ligand to support highly soluble diruthenium compounds. Thus, the new compounds Ru-2((i)BuOaP)(4)Cl (1), Ru-2 ((i)BuOaP)(4)(C CPh) (2), Ru-2(BuOaP)(4)(C CPh)(2) (3), and Ru-2((i)BuOaP)(4)(C (CSiPr3)-Pr-i) (4) were prepared and characterized by both voltammetric and spectroscopic methods, and their physical properties were found to be quite similar to those of the previously reported Ru-2(ap)(4)-based compounds. The spectroscopic properties of both anionic and cationic derivatives of compounds 2 and 3 were examined with spectroelectrochemistry. Density functional theory calculations performed on model compounds of 2 and 3 provide an in-depth picture of the electronic structures of Ru-2(ap)(4)-based alkynyl compounds and assignment of the observed electronic transitions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available