Journal
INORGANIC CHEMISTRY
Volume 48, Issue 8, Pages 3514-3516Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic900281g
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- EPFL
- EPFL and the Swiss National Science Foundation [119663]
- NANOKAT
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A mononuclear iron bis(carbonyl) pyridonate complex (1), which exhibits several common structural features with the active site of the iron-sulfur cluster-free [Fe]-hydrogenase, was synthesized and characterized. Spectroscopic data of 1 suggests a 2+ oxidation state for the Fe ion in the [Fe]-hydrogenase. Complex 1 serves as a precursor to other hydrogenase models.
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