Journal
INORGANIC CHEMISTRY
Volume 48, Issue 18, Pages 8653-8655Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic900611u
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Funding
- NNSF of China [20701041]
- NSF of Chongqing [CSTC200713134234]
- SIP of Chongqing Municipal Education Commission [KJ070812]
- MSF of Chongqing Normal University [08XLZ09]
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The 3-D 12-connected metal-organic framework [Cu12Br2(CN)(6/2)(SCH3)(6)][Cu(SCH3)(2)], containing dodecanuclear copper clusters, has been solvothermally synthesized and exhibits efficient yellow luminescence. The emission mechanism was studied in detail to elucidate the relationship of the luminescent properties and crystal structures, which is helpful for the design and synthesis of more efficient luminescent materials.
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