Journal
INORGANIC CHEMISTRY
Volume 48, Issue 11, Pages 4628-4630Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic900376h
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Funding
- National Basic Research Program of China [2007CB925101]
- NSFC [20671087]
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A multinary molecular nanocluster, in which a T3 supertetrahedral [Sn4Ga4Zn2Se20](8-) core was neutralized and covalently terminated by four [(TEPA)Mn](2+) (TEPA = tetraethylenepentamine) metal complexes, was synthesized and characterized. The cluster is assembled into, through hydrogen bonding and van de Waals forces, a superlattice that is chemically stable and free of strong covalent coupling. The four different cations were distributed within the cluster in such a manner that both the local charge balance and global charge compensation by the metal complex could be satisfied.
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