4.6 Article

On the Use of Porous and Nonporous Fillers in the Fabrication of Silicon Carbide Membranes

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 52, Issue 30, Pages 10269-10275

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ie401116b

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Funding

  1. U.S. Department of Energy [DE-SC0003586]
  2. National Science Foundation [CBET-0854427]
  3. Div Of Chem, Bioeng, Env, & Transp Sys
  4. Directorate For Engineering [0854427] Funding Source: National Science Foundation

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Hydrogen-permselective asymmetric silicon carbide (SiC) membranes were prepared in this study by incorporating highly porous SiC nanofibers into the membrane structure using a sacrificial interlayer-based technique. The resulting membranes were characterized with permeation studies, nitrogen adsorption experiments, and electron microscopy analysis. Their characteristics were compared with those of SiC membranes prepared with the same approach but making use, instead, of fine, nonporous SiC powders as fillers.

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