Article
Engineering, Environmental
Yanru Sun, Jun Li, Hongzhong Li
Summary: Large core-shell-like Fe2O3/MgO microspheres were synthesized via hydrothermal precipitation method, with particle morphology dominated by PVP and diameter affected by nucleation rate and growth rate. The diameter of the microspheres decreased with increasing PVP concentration and urea concentration. The core-shell-like microspheres showed good sintering resistance and cycle stability when used as oxygen carriers for chemical looping dry reforming.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Chemical
F. Miccio, E. Landi, A. Natali Murri, M. Minelli, F. Doghieri, A. Storione
Summary: Methane reforming is an industrial process for hydrogen production, with a high CO2 footprint that can be mitigated by using renewable methane or recycling carbon dioxide. The research investigated methane reforming assisted by an oxygen carrier, which shows potential for hydrogen and carbon monoxide production. The study developed three different granular materials based on CeO2 for fluidized beds, with different calcination temperatures. The materials calcined at the highest temperature showed the best attrition resistance, while those sintered at lower temperature exhibited the best oxygen supply capacity.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2023)
Article
Green & Sustainable Science & Technology
Giuseppe Cristian Piso, Piero Bareschino, Paola Brachi, Claudio Tregambi, Giovanna Ruoppolo, Francesco Pepe, Erasmo Mancusi
Summary: In this study, the Chemical Looping Reforming of biogas was proposed and numerically investigated to achieve the clean, efficient, and cost-effective utilization of renewable carbonaceous fuels. The effects of biogas composition and process parameters on the reaction performances were assessed and discussed, including the conversion degree, syngas yield, and syngas composition.
Article
Chemistry, Applied
Jinchen Ma, Xue Zhang, Peng Peng, Xin Tian, Mengshuang Li, Ying Li, Zuwei Xu, Haibo Zhao
Summary: In this study, LaFeO3 perovskite with an ordered porous structure was synthesized via the sol-gel method and used as an oxygen carrier for chemical looping dry reforming (CLDR) of ethane. The performance and characteristics of the oxygen carrier and the CLDR process were comprehensively investigated. Results showed that LaFeO3 efficiently converted ethane into syngas (H2 and CO), and the deposited carbon on the oxygen carrier could be effectively removed by CO2. The highest C2H6 conversion, CO yield, and CO selectivity were achieved at 800 degrees C and 12,000 L/(kg center dot h).
FUEL PROCESSING TECHNOLOGY
(2023)
Article
Energy & Fuels
Tobias Proell, Anders Lyngfelt
Summary: The combination of chemical-looping combustion (CLC) and steam methane reforming (SMR) is a promising method for CO(2) capture and hydrogen production. By optimizing the dimensions of the SMR tube, it is possible to improve the performance and reduce the necessary tube length. Simulation results show that using smaller tube diameters can significantly decrease the required tube length for equivalent gas conversion.
Article
Energy & Fuels
Ivan Gogolev, Toni Pikkarainen, Juho Kauppinen, Carl Linderholm, Britt-Marie Steenari, Anders Lyngfelt
Summary: Chemical looping combustion (CLC) of biomass is a promising technology for power generation with integrated carbon capture, but the alkali content of biomass may lead to bed agglomeration and oxygen carrier absorption issues. Studies have shown that gas-phase alkali emissions in CLC operation can be up to 15 times higher than in OCAC operation, mainly due to steam accelerating the decomposition of alkali compounds in the biomass.
Article
Energy & Fuels
Ratnakumar V. Kappagantula, Gordon D. Ingram, Hari B. Vuthaluru
Summary: Chemical Looping Combustion technologies have the ability to capture carbon dioxide and are modeled using a specialized Fluidized Bed Reactor block in Aspen Plus. Sensitivity studies showed that solid volume fraction decreases with bed height and superficial velocity, while the height to diameter ratio of the fluidized bed is an important variable in reactor design.
Article
Engineering, Environmental
Dingshan Cao, Cong Luo, Fan Wu, Liqi Zhang, Xiaoshan Li
Summary: Chemical looping steam methane reforming (CL-SMR) is a novel process using solid oxygen carriers to produce syngas and hydrogen from methane. This study screened perovskites and found LaFeO3-CeO2 as an optimal oxygen carrier with high hydrogen production, stable reaction performance, and high purity hydrogen. CeO2 loading provides lattice oxygen for syngas production and enhances hydrogen production.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Yuchun Zhang, Hetong Li, Yue Jiang, Lei Dai, Peng Fu, Zhiyu Li
Summary: Hydrogen energy is an important new energy source, and chemical looping steam reforming is an effective method for hydrogen production. In this study, modified Fe-based oxygen carriers were used, and it was found that LaNi0.1Fe0.9O3- had the best performance for hydrogen production.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Energy & Fuels
Hengjun Gai, Peiyi Yang, Qiang Zhang, Mengqi Lin, Hongbing Song, Meng Xiao, Tingting Huang, Quanhong Zhu
Summary: Circulating fluidized bed reactors are widely used in the energy industry for gas-solid reactions. They can be classified into two categories based on fluidization regimes: dilute-dense and dual-dense. The concept of dual-dense gas-solid circulating fluidization has not been well understood, hindering its commercial application. This review provides a detailed analysis of the dual-dense system, including mechanism, structural and operating parameters, particle circulation prediction, gas-solid flow simulation, and potential applications, while identifying existing controversies and unresolved issues.
Article
Energy & Fuels
Petteri Peltola, Falah Alobaid, Tero Tynjaelae, Jouni Ritvanen
Summary: This article provides a brief review of the modeling of chemical looping combustion (CLC), a next-generation CO2 capture technology, in bubbling and circulating fluidized bed reactors. The article presents a summary of published mathematical reactor models, with a focus on a macroscopic modeling approach that combines transport equations with semiempirical correlations to describe key fluidized bed phenomena. The article highlights important aspects to be considered in the modeling of CLC in a dual fluidized bed reactor system and identifies research needs. So far, semiempirical reactor models have been validated based on experimental results, but there is limited research on dynamic process simulation of CLC.
Article
Chemistry, Applied
Kun Zhao, Rongjiang Zhang, Yunfei Gao, Yan Lin, Anqi Liu, Xiaobo Wang, Anqing Zheng, Zhen Huang, Zengli Zhao
Summary: This study investigated the use of perovskites as oxygen carriers for chemical looping steam methane reforming, finding that La0.95Ce0.05Ni0.2Fe0.8O3 and La0.95Ce0.05-Ni0.5Fe0.5O3 showed high efficiency in methane partial oxidation and steam splitting, potentially simplifying the separation step for pure hydrogen acquisition.
FUEL PROCESSING TECHNOLOGY
(2022)
Article
Energy & Fuels
Dulyapat Thiemsakul, Chaiyanan Kamsuwan, Ratchanon Piemjaiswang, Pornpote Piumsomboon, Benjapon Chalermsinsuwan
Summary: The Internally circulating fluidized bed reactor (ICFB) combines the conventional circulating fluidized bed (CFB) reactor system into a single compact column, utilizing different fluidizing velocities to circulate solid particles for methane dry reforming. Studies showed that reactor design significantly impacts methane conversion in the ICFB, offering potential cost reduction and simplification of operation compared to conventional CFB reactors.
Article
Energy & Fuels
Anders Lyngfelt, David Pallares, Carl Linderholm, Fredrik Lind, Henrik Thunman, Bo Leckner
Summary: Chemical looping combustion (CLC) has the potential to avoid the high costs and energy penalties of existing CO2 capture technologies. It transfers oxygen to the fuel using an oxygen carrier, separating air and fuel. This results in separate streams of CO2 and H2O, with relatively pure CO obtained after condensation of H2O. The circulation of oxygen and heat to the fuel reactor is crucial in CLC, which is typically a dual fluidized bed process. While many oxygen carriers have been successfully used in pilot operation, little consideration has been given to achieving sufficient circulation in an industrial-scale system.
Article
Engineering, Environmental
Jing Yang, Yujie Ren, Jinsuo Lu, Hongpan Liu, Zhiqiang Zhang, Heliang Pang, Keomounlath Bounkhong
Summary: The study investigated a new PG-CuFe2O4 oxygen carrier for reducing lignite in Chemical Looping Gasification (CLG) process, successfully capturing H2S and producing syngas with high proportions of CO and H2. Experimental results showed that PG-CuFe2O4 had excellent H2S capture ability, with Fe3O4, Cu, and FeS playing important roles in the H2S capture during the reduction process.
CHEMICAL ENGINEERING JOURNAL
(2021)