4.6 Article

Electrochemical Deammonification of Synthetic Swine Wastewater

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 51, Issue 38, Pages 12167-12172

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ie3015022

Keywords

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Funding

  1. Center for Electrochemical Engineering Research at Ohio University
  2. Department of Defense through the U.S. Army Construction Engineering Research Laboratory [W9132T-09-1-0001]

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The ammonia electrolysis process, which presents as only products nitrogen and hydrogen fuel, was evaluated for the deammonification of wastewater. The effects of cell voltage, pH, and flow rate were analyzed for single pass ammonia electrooxidation of synthetic swine wastewater. A surface response analysis was performed to obtain quadratic models that predict the NH3 conversion and hydrogen (H-2) production where pH was identified as the variable with the most statistic significance to explain changes in ammonia conversion with hydrogen production. NH3 conversions above 80% and specific energy consumption under 3 kW.h kg(-1) of NH3 without considering the energy that can be obtained from the H-2 produced, show that the ammonia electrolysis technology has promising potential for the deammonification of wastewater with less energy consumption than the conventional nitrification/denitrification process.

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