4.6 Article

Catalytic Activity of Green and Recyclable Nanometric Tin Oxide-Doped Silica Nanospheres in the Synthesis of Imines

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 51, Issue 48, Pages 15626-15632

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ie302301p

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Funding

  1. Department of Science and Technology-SERC, New Delhi [SR/FT/CS-113/2010(G)]
  2. Basic Science Research Program through the NRF
  3. Ministry of Education, Science and Technology [2011-0010538]
  4. Business for Cooperative R&D between Industry, Academy, and Research Institute [C0031452]

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Nanometric tin oxide particles were effectively doped over silica nanospheres without any free zones via sol-gel technique in an aqueous medium. X-ray diffraction pattern of the prepared composite specifies the formation of amorphous and cassiterite character of the silica and tin oxide particles, respectively. High thermal stability of the prepared materials substantiated ceramic properties of the prepared nanomaterials and has an influence on decreasing the reaction temperature of organic reactions. High surface area associated with prompt porosity values and their solubility in variety of solvents favors the catalytic activity of the prepared nanomaterials in imine formation reactions. The ease of recovery, excellent product yield, and intrinsic stability of the catalyst make this protocol economical and sustainable.

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