Article
Chemistry, Physical
Patrick Ryan Galligan, Yixin Xu, Tsz Wing Tang, Hongwei Liu, Mohsen Tamtaji, Yanguang Zhou, Zhengtang Luo
Summary: Hexagonal boron carbon nitride (hBCN) thin films with varying carbon doping levels were synthesized using chemical vapor deposition (CVD). The film with the highest carbon doping exhibited the highest thermal conductivity, surpassing that of hexagonal boron nitride (hBN). Molecular dynamics simulations revealed that aligning carbon to form graphene-like channels increased the high frequency phonon group velocities, leading to higher thermal conductivity. The aligned carbon channels were effective in overcoming phonon scattering, particularly in the LA mode. This research demonstrates an effective method of producing optimized hBCN thin films for thermal interface material applications, as a lower cost alternative to hBN.
Article
Materials Science, Ceramics
Hirokazu Katsui, Katsuyoshi Harada, Zheng Liu, Naoki Kondo, Mikinori Hotta
Summary: Boron carbon oxynitride (BCNO) phosphor films with tunable chemical compositions and photo-luminescence spectra were successfully grown by chemical vapor deposition. The films exhibited a dense, uniform microstructure and a turbostratic boron nitride (BN) structure. The films showed multiple emission peaks under excitation and the peak intensities could be enhanced by adjusting the concentrations of carbon and oxygen in the films.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Eugenio Calandrini, Kirill Voronin, Osman Balci, Maria Barra-Burillo, Andrei Bylinkin, Sachin M. Shinde, Subash Sharma, Felix Casanova, Luis E. Hueso, Andrei Chuvilin, Clifford Mcaleese, Ben R. Conran, Xiaochen Wang, Kenneth Teo, Valentyn S. Volkov, Andrea C. Ferrari, Alexey Y. Nikitin, Rainer Hillenbrand
Summary: This work reports the observation of phonon polaritons (PhPs) in wafer-scale multilayer hexagonal boron nitride (hBN) grown by chemical vapor deposition. PhPs are visualized using infrared nanoimaging, and their lifetimes are measured. PhP nanoresonators are also demonstrated. These results are of significant importance for applications in infrared spectroscopy and photodetectors based on PhPs.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Max Franck, Jaroslaw Dabrowski, Markus Andreas Schubert, Christian Wenger, Mindaugas Lukosius
Summary: In this study, the growth of hexagonal boron nitride (hBN) on epitaxial Ge(001)/Si substrates using high-vacuum chemical vapor deposition from borazine was systematically investigated for the first time. The research findings suggest that the process pressure and growth temperature have certain influences on the morphology, growth rate, and crystalline quality of hBN films.
Article
Chemistry, Multidisciplinary
Paolo Giusto, Daniel Cruz, Tobias Heil, Nadezda Tarakina, Maddalena Patrini, Markus Antonietti
Summary: By chemically vapor depositing BCN thin films from a single source precursor, high transparency and refractive index values for reflective mirrors and lenses are achieved. These wide-bandgap semiconductor materials, with positive valence band, demonstrate stability against oxidation making them ideal for protective coatings and charge transport layers in solar cells. The simple and low-hazard method can open up possibilities for BCN thin films in optics and optoelectronics.
Review
Engineering, Environmental
Tao Xu, Kai Zhang, Qiran Cai, Nanyang Wang, Liyun Wu, Qian He, Han Wang, Yi Zhang, Yufeng Xie, Yagang Yao, Ying Chen
Summary: This paper briefly reviews the development history of boron nitride nanotubes (BNNTs) and updates the recent advances in their synthesis and applications. It focuses on the CVD method, discussing the experiment devices, precursors, catalyst, temperature, and growth mechanisms. It also summarizes the advanced applications of BNNTs in composites, water purification membranes, biological applications, and optical devices, and discusses future challenges and opportunities.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Physics, Applied
Rong Fan, Qiuyan Chen, Zongping Chen
Summary: In this study, the role of the edge during the growth of hexagonal boron nitride (hBN) by chemical vapor deposition (CVD) was investigated. The researchers demonstrated two types of hydrogen-induced edge evolution of single-crystal hBN domains over time on liquid Cu via CVD. The results were well explained by the kinetic Wulff construction theory and provide insights into the production of large-scale single-crystalline hBN.
APPLIED PHYSICS EXPRESS
(2022)
Article
Chemistry, Physical
Ying Wang, Kai Zhang, Liyun Wu, Xuhua He, Qian He, Nanyang Wang, Zhengyang Zhou, Chaowei Li, Yue Hu, Yagang Yao
Summary: This study presents an efficient method for growing high-quality boron nitride nanotubes (BNNTs) using low-melting-point precursors, namely magnesium diboride (MgB2), magnesium nitride (Mg3N2), and diboron trioxide (B2O), through chemical vapor deposition at temperatures of 1000-1300 degrees C. The addition of Mg3N2 prevents the formation of high-melting-point Mg3B2O6, allowing MgB2 to maintain its catalytic capacity and improve the growth efficiency of BNNTs. Furthermore, BNNTs-based PDMS composites exhibit enhanced thermal conductivity compared to pure PDMS, suggesting their potential in thermal interface materials applications.
Article
Materials Science, Multidisciplinary
Hisashi Yamada, Sho Inotsume, Naoto Kumagai, Toshikazu Yamada, Mitsuaki Shimizu
Summary: Two different boron precursors, diborane and trimethyl boron, were investigated for h-BN growth, with the BN layer grown using TMB containing a higher amount of carbon atoms and exhibiting turbostratic BN structure compared to that grown using B2H6. The Raman peak frequencies and widths indicate that TMB induces a larger compressive strain and prevents the formation of highly crystalline h-BN thin films.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
(2021)
Review
Chemistry, Multidisciplinary
Peng-Xiang Hou, Feng Zhang, Lili Zhang, Chang Liu, Hui-Ming Cheng
Summary: The FCCVD is an important technique for synthesizing high-quality CNTs with various morphologies, offering advantages of simplicity, controllability, and scalability. Researchers review the controlled growth, properties, and applications of CNTs, discussing key challenges and prospects for the future.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Materials Science, Ceramics
Xianghui Zeng, Hui Chen, Jinfeng Wu, Wei Fang, Xing Du, Xuan He, Daheng Wang, Weixin Li, Lei Zhao
Summary: In this study, vertically aligned BNNSs were synthesized without any substrates using Fe-catalyzed thermal chemical vapor deposition method. The BNNSs exhibited improved crystallinity, high UV light emission, and excellent anti-oxidation behavior due to their unique structures. This environmentally friendly synthesis method allows for exploration of industrial upscaling applications.
CERAMICS INTERNATIONAL
(2022)
Review
Chemistry, Multidisciplinary
Jia Zhang, Biying Tan, Xin Zhang, Feng Gao, Yunxia Hu, Lifeng Wang, Xiaoming Duan, Zhihua Yang, PingAn Hu
Summary: Atomically thin hexagonal boron nitride (h-BN) is a promising 2D material with unique properties for applications in optoelectronics and electronics. Chemical vapor deposition (CVD) is considered a promising method for producing large-scale, high-quality h-BN films and heterostructures. The epitaxial growth of 2D materials onto h-BN and building heterostructures can lead to novel properties.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Physical
Yoon-jeong Kim, Minsung Kang, Yang Hui Kim, Eun-Kyung Suh, Minseok Yang, Se Yeon Cho, Dae-Young Jeon, Jeung Gon Kim, Jungmo Kim, Seokhoon Ahn
Summary: This paper introduces contorted hexabenzocoronene (c-HBC) derivatives as a potential universal precursor for synthesis of carbon materials with dimensions ranging from 1-D to 3-D. By controlling the assembly dimensions and intermolecular interactions of c-HBC derivatives, carbon products with different dimensions and high crystallinity can be synthesized. The use of copper vapor allows further control of crystallinity, and the carbonization process of c-HBC enables the growth of graphene-like structures on arbitrary substrates.
Article
Chemistry, Physical
Nan Zhao, Qianru Wu, Xiuyun Zhang, Tao Yang, Dong Li, Xueting Zhang, Chen Ma, Runluan Liu, Liantao Xin, Maoshuai He
Summary: The synthesis of SWNTs from plastic polymers using chemical vapor deposition (CVD) relies on a robust Co-MgO cobalt catalyst. This method extends the potential of plastic waste as a feedstock for high-value carbon nanomaterials.
Article
Chemistry, Multidisciplinary
Gaokai Wang, Jidong Huang, Siyu Zhang, Junhua Meng, Jingren Chen, Yiming Shi, Ji Jiang, Jingzhen Li, Yong Cheng, Libin Zeng, Zhigang Yin, Xingwang Zhang
Summary: A facile submicron-spacing vapor deposition (SSVD) method is reported for growing wafer-scale single crystal h-BN layers with controllable thickness on sapphire substrates. The epitaxial h-BN layer shows high crystalline quality and is demonstrated to have potential applications in a deep ultraviolet photodetector and a ZrS2/h-BN heterostructure. This method provides a promising path towards future 2D semiconductor-based electronics and optoelectronics.
Article
Polymer Science
Jamal Seyyed Monfared Zanjani, Burcu Saner Okan, Ilse Letofsky-Papst, Mehmet Yildiz, Yusuf Ziya Menceloglu
EUROPEAN POLYMER JOURNAL
(2015)
Article
Materials Science, Composites
Jamal Seyyed Monfared Zanjani, Burcu Saner Okan, Yusuf Ziya Menceloglu, Mehmet Yildiz
JOURNAL OF REINFORCED PLASTICS AND COMPOSITES
(2015)
Article
Materials Science, Multidisciplinary
Burcu Saner Okan, Jamal Seyyed Monfared Zanjani, Ilse Letofsky-Papst, Fevzi Cakmak Cebeci, Yusuf Z. Menceloglu
MATERIALS CHEMISTRY AND PHYSICS
(2015)
Article
Polymer Science
Burcu Saner Okan, Azucena Marset, Jamal Seyyed Monfared Zanjani, Pinar Akkus Sut, Ozlem Sen, Mustafa Culha, Yusuf Menceloglu
JOURNAL OF APPLIED POLYMER SCIENCE
(2016)
Article
Materials Science, Multidisciplinary
Jamal Seyyed Monfared Zanjani, Burcu Saner Okan, Yusuf Menceloglu
MATERIALS CHEMISTRY AND PHYSICS
(2016)
Article
Chemistry, Multidisciplinary
Burcu Saner Okan
TURKISH JOURNAL OF CHEMISTRY
(2017)
Article
Engineering, Manufacturing
Jamal Seyyed Monfared Zanjani, Burcu Saner Okan, Panagiotis-Nektarios Pappas, Costas Galiotis, Yusuf Ziya Menceloglu, Mehmet Yildiz
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2018)
Article
Materials Science, Multidisciplinary
Cem Balda Dayan, Ferdows Afghah, Burcu Saner Okan, Mehmet Yildiz, Yusuf Menceloglu, Mustafa Culha, Bahattin Koc
MATERIALS & DESIGN
(2018)
Article
Chemistry, Multidisciplinary
Leila Haghighi Poudeh, Ilse Letofsky-Papst, Fevzi Cakmak Cebeci, Yusuf Menceloglu, Mehmet Yildiz, Burcu Saner Okan
Article
Polymer Science
Elcin Cakal Sarac, Leila Haghighi Poudeh, Jamal Seyyed Monfared Zanjani, Zeki Semih Pehlivan, Fevzi Cakmak Cebeci, Ismail Aydin, Yusuf Menceloglu, Burcu Saner Okan
JOURNAL OF APPLIED POLYMER SCIENCE
(2019)
Article
Chemistry, Multidisciplinary
Leila Haghighi Poudeh, Dilek Cakiroglu, Fevzi Ccommaakmak Cebeci, Mehmet Yildiz, Yusuf Z. Menceloglu, Burcu Saner Okan
Article
Materials Science, Multidisciplinary
Mohib Ullah, Jamal Seyyed Monfared Zanjani, Leila Haghighi Poudeh, Mohammad Siddiq, Burcu Saner Okan, Mehmet Yildiz, Yusuf Menceloglu
DIAMOND AND RELATED MATERIALS
(2017)
Article
Engineering, Manufacturing
Jamal Seyyed Monfared Zanjani, Burcu Saner Okan, Cagatay Yilmaz, Yusuf Menceloglu, Mehmet Yildiz
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2017)
Article
Chemistry, Multidisciplinary
Jamal Seyyed Monfared Zanjani, Burcu Saner Okan, Yusuf Ziya Menceloglu, Mehmet Yildiz
Article
Chemistry, Multidisciplinary
Leila Haghighi Poudeh, Burcu Saner Okan, Jamal Seyyed Monfared Zanjani, Mehmet Yildiz, Yusuf Menceloglu