4.6 Article

Enhanced Flame Retardant Property of Fiber Reactive Halogen-Free Organophosphonate

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 51, Issue 34, Pages 11031-11037

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ie300964g

Keywords

-

Ask authors/readers for more resources

In this paper, we studied the synthesis, characterization, and flammability of the water-soluble, nonhalogenated organophosphorus flame retardant (FR) dimethyl-[1,3,5(3,5-triacryloylhexahydro)triazinyl]-3-oxoPropylphosphonate for application to cotton fabrics by nonpolymeric network The FR was synthesized in a one-step reaction from dimethyl phosphite and 1,3,5-triacryloylhexahydro-1,3,5-triazine under mild conditions, and its structure was fully characterized by H-1, C-13, and P-31 nuclear magnetic resonance (NMR), mass spectrometry (MS), and Fourier transform infrared spectroscopy (FT-IR). The finishing conditions to achieve a covalent bond between the FR and fibers were optimized, and the FR capability of the treated cotton was investigated by limiting oxygen index (LOI), flame test, thermogravimetric analysis (TGA), and micro cone calorimeter (MCC) tests. This study showed that fabrics treated with the FR are effectively flame resistant, and the FR property is enhanced by covalent bonding of the FR to fibers.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Textiles

Use of cottonseed protein as a strength additive for nonwoven cotton

Andres Villalpando, Michael Easson, H. N. Cheng, Brian Condon

TEXTILE RESEARCH JOURNAL (2019)

Article Chemistry, Multidisciplinary

Alkali Hydrolysis of Sulfated Cellulose Nanocrystals: Optimization of Reaction Conditions and Tailored Surface Charge

Jacobs H. Jordan, Michael W. Easson, Brian D. Condon

NANOMATERIALS (2019)

Article Chemistry, Physical

Effect of Nanocellulose on the Properties of Cottonseed Protein Isolate as a Paper Strength Agent

Jacobs H. Jordan, Huai N. Cheng, Michael W. Easson, Wei Yao, Brian D. Condon, Bruce C. Gibb

Summary: Research on using cellulose nanomaterials to improve the performance of cottonseed protein as a paper strength agent found that the addition of nanocellulose improved the elongation at break, tensile strength, and modulus of treated paper products. The cottonseed protein/nanocellulose composites interacted with the filter paper fibers, enhancing the dry strength of the paper.

MATERIALS (2021)

Article Food Science & Technology

Proximate Composition and Nutritional Attributes of Ready-to-Cook Catfish Products

John M. Bland, Casey C. Grimm, Peter J. Bechtel, Uttam Deb, Madan M. Dey

Summary: In order to increase the demand for U.S. farm-raised catfish, five healthy and convenient ready-to-cook products were developed as alternatives to basic fresh or frozen fillets. Analysis of the nutrient content and characteristics of the samples revealed unique differences between the Panko-breaded and marinated products, as well as a clear trend showing changes in moisture, protein, ash, and carbohydrate percentages.

FOODS (2021)

Article Biochemistry & Molecular Biology

Detection of Human Neutrophil Elastase by Fluorescent Peptide Sensors Conjugated to TEMPO-Oxidized Nanofibrillated Cellulose

Robert T. Mackin, Krystal R. Fontenot, Judson Vincent Edwards, Nicolette T. Prevost, Jacobs H. Jordan, Michael W. Easson, Brian D. Condon, Alfred D. French

Summary: Peptide-cellulose conjugates designed as optical protease sensors have potential applications in point-of-care (POC) detection. Nanocellulose, with its biocompatibility and high specific surface area, serves as a suitable transducer surface for sensitive detection of dilute biomarkers. Computational models were used to study the relationship between the sensor molecule and the transducer surface, providing insights for enhanced sensor activity design.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2022)

Article Polymer Science

Application of Lignin-Containing Cellulose Nanofibers and Cottonseed Protein Isolate for Improved Performance of Paper

Jacobs H. Jordan, Michael W. Easson, Huai N. Cheng, Brian D. Condon

Summary: The use of lignin-containing cellulose nanofibers and cottonseed protein as additives can improve the dry strength of filter paper, with the best results obtained using 10% protein solution and 2% nanofibers as additives.

POLYMERS (2022)

Article Chemistry, Multidisciplinary

Silver Nanoparticle-Intercalated Cotton Fiber for Catalytic Degradation of Aqueous Organic Dyes for Water Pollution Mitigation

Matthew Blake Hillyer, Jacobs H. Jordan, Sunghyun Nam, Michael W. Easson, Brian D. Condon

Summary: Researchers used silver nanoparticles immobilized within cotton fabric as a catalyst to successfully degrade azo dyes in water. The catalyst exhibited excellent durability and reusability, and showed high degradation capacity for different types of azo dyes.

NANOMATERIALS (2022)

Article Food Science & Technology

Instrumental Texture Differentiation of Channel (Ictalurus punctatus) and Hybrid (Channel x Blue, Ictalurus furcatus) Catfish Fillets

John M. Bland, Ryan Ardoin, Carissa H. Li, Peter J. Bechtel

Summary: An analysis of instrumental texture differences between channel and hybrid catfish fillets revealed significant variations in most texture attributes. Cold-storage type and thickness had some influence on the texture attributes, but the differences between channel and hybrid catfish could still be accurately determined, and TPA analysis provided high levels of differentiation between the two types.

FOODS (2022)

Article Materials Science, Textiles

Comparison of Focal Plane Array FTIR Pixel Binning Size for the Nondestructive Determination of Cotton Fiber Maturity Distributions

Michael Santiago Cintron, Doug J. J. Hinchliffe, Rebecca Hron

Summary: The study explores the use of a Focal-Plane Array (FPA) imaging system for determining maturity in small cotton fiber bundles. The system was adjusted to examine 140 points per sample, an improvement over the previous study. Results show a strong correlation between FPA and Cottonscope maturity determinations. The FPA IR system is suitable for non-destructively examining and imaging cotton maturity distributions.

FIBERS AND POLYMERS (2023)

Article Polymer Science

Preparation and evaluation of catfish protein as a wood adhesive

H. N. Cheng, Zhongqi He, Carissa H. Li, John M. Bland, Peter J. Bechtel

Summary: The study extracted protein from catfish skin and tested its effectiveness as a wood adhesive, finding that it performed well with similar or slightly better dry adhesive strength compared to cottonseed protein isolate. Additionally, a blend of catfish protein and cottonseed protein exhibited improved performance, suggesting that catfish protein may be a suitable material for wood adhesive applications.

INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION (2021)

Article Agricultural Economics & Policy

Consumers' willingness-to-pay for convenient catfish products: Results from experimental auctions in Arkansas

Saroj Adhikari, Uttam Deb, Madan Mohan Dey, Lin Xie, Nabin Babu Khanal, Casey C. Grimm, John M. Bland, Peter J. Bechtel

Summary: This study examined consumers' acceptance, preference, and willingness to pay for five newly developed convenient catfish products using experimental auction sessions. The research found that the acceptance level for panko-breaded products was higher than marinated products, and consumers preferred breaded products. The participants' age and being African-American catfish consumers were positively associated with their willingness to pay, while holding a bachelor's degree was negatively correlated with willingness to pay.

AQUACULTURE ECONOMICS & MANAGEMENT (2021)

Article Materials Science, Paper & Wood

Lignin-containing cellulose nanofibers with gradient lignin content obtained from cotton gin motes and cotton gin trash

Jacobs H. Jordan, Michael W. Easson, Stephanie Thompson, Qinglin Wu, Brian D. Condon

Summary: Agricultural waste and residues, such as cotton gin trash and cotton gin motes, were used to prepare lignin-containing cellulose nanofibers with gradient degrees of lignin content. The physical properties of the nanofibers were affected by the lignin content and other components, impacting thermal stability and crystallinity. The degree of polymerization was smaller after processing, with differences based on the source material, resulting in slightly different suspension viscoelastic behavior.

CELLULOSE (2021)

Article Chemistry, Multidisciplinary

Cellulose hydrolysis using ionic liquids and inorganic acids under dilute conditions: morphological comparison of nanocellulose

Jacobs H. Jordan, Michael W. Easson, Brian D. Condon

RSC ADVANCES (2020)

Article Nanoscience & Nanotechnology

Application of Brown Cotton-Supported Palladium Nanoparticles in Suzuki-Miyaura Cross-Coupling Reactions

Michael W. Easson, Jacobs H. Jordan, John M. Bland, Doug J. Hinchliffe, Brian D. Condon

ACS APPLIED NANO MATERIALS (2020)

Article Materials Science, Textiles

Investigation of bisphenol-substituted spirocyclic phosphazenes as cotton textile-based flame retardants

Michael W. Easson, Jacobs Harris Jordan, SeChin Chang, John M. Bland, Brian Douglas Condon

JOURNAL OF ENGINEERED FIBERS AND FABRICS (2020)

No Data Available