Article
Energy & Fuels
Guilherme Muhlstedt, Jonathan Felipe Galdino, Diogo E. Andrade, Cezar O. R. Negrao
Summary: Gas hydrates may form in deep-water drilling operations when light compounds flow into the wellbore due to a kick. By inducing hydrate formation with tetrahydrofuran in water-based drilling fluid, researchers found that the resulting hydrate slurry is a time-dependent elastoviscoplastic material with irreversible microstructural changes under shear. The study also revealed that the hydrate slurry exhibits different rheological properties depending on whether it is formed statically or dynamically.
Article
Energy & Fuels
Weiguo Liu, Ran Liu, Mengmeng Zhang, Zaixing Liu, Chen Lang, Yanghui Li
Summary: Solid fluidization is a promising method for exploring hydrate resources. The rheological properties of hydrate slurry play a significant role in preventing blockages during pipeline transportation. This study found that the presence of hydrate substantially increases the apparent viscosity of mudflow, with higher water conversion rates leading to significantly increased viscosity of hydrate slurry.
Article
Engineering, Chemical
Tomoya Sagawa, Ryosuke Ezure, Hiroyuki Komatsu, Hideo Tajima
Summary: The flow pattern and rheological properties of SF6 hydrate slurry were investigated in this study. Three flow patterns, namely homogeneous flow, heterogeneous flow, and moving-bed flow, were observed as the flow velocity changed. Experimental relationships based on the Turian-Yuan equation were developed to predict the flow velocities at which the flow patterns change with an error of approximately 10%. The rheological properties of SF6 hydrate slurry exhibited Newtonian tendency at low solid fractions and pseudoplastic tendency at high solid fractions. The relative viscosity of the slurry could be estimated within 25% error using the Krieger-Dougherty model.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2023)
Article
Engineering, Chemical
Xiaofang Lv, Boyu Bai, Yi Zhao, Yang Liu, Qianli Ma, Chuanshuo Wang, Shidong Zhou, Shangfei Song, Bohui Shi
Summary: This paper focuses on the effects of water cut, polymerization inhibitor concentration, and temperature on the viscosity of natural gas hydrate slurry. It establishes a rheological model for the slurry and finds that water cut and polymerization inhibitor concentration increase the apparent viscosity, while temperature decreases it.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2022)
Article
Thermodynamics
Zaixing Liu, Yanghui Li, Jiguang Wang, Mengmeng Zhang, Weiguo Liu, Chen Lang, Yongchen Song
Summary: This study investigates the rheological characteristics of hydrate slurries formed in marine sediments using a high-pressure rheometer. The results indicate that the viscosity change is more significant with higher sediment concentration. Oscillatory measurements show that hydrate slurries display viscoelastic fluid characteristics. The yield stress sharply increases when the hydrate volume fraction exceeds a critical value.
Article
Physics, Multidisciplinary
Yongchao Rao, Zehui Liu, Shuli Wang, Lijun Li, Qi Sun
Summary: The development of oil and gas resources has shifted to the deep sea, where hydrate plugging in pipelines under high pressure and low temperatures is a critical issue. The use of swirl flow technology can expand the safe flow range of hydrates and improve the efficiency of hydrate slurry transportation.
Article
Energy & Fuels
Jiaqiang Jing, Lequan Zhuang, Rinat Karimov, Jie Sun, Xingtang Zhang, Hang Yang
Summary: There are multiple flow assurance challenges in deep-water energy development, with the coexistence of wax and hydrate posing one of the most difficult problems. An experimental study was conducted to investigate the impact of wax content, water cut, subcooling, and static time on CP hydrate-forming mixtures. The results revealed that wax inhibits hydrate nucleation and growth, but the viscosity of hydrate slurry is still higher in systems with wax due to wax-hydrate aggregates contributing to system viscosity. Additionally, wax increases the yield stress of the hydrate slurry, with a more significant effect at higher water cut and longer static times. The rating: 9/10.
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
(2023)
Article
Engineering, Chemical
Y. Salehy, P. Clain, A. Boufares, N. Chami, J-P. Torre, D. Dalmazzone, L. Fournaison, A. Delahaye
Summary: Recent studies have explored the potential use of hydrate slurries in indirect refrigeration systems, but pipeline clogging issues due to hydrate agglomeration can arise. Additives, such as Dioctyl sodium sulfosuccinate (AOT), are commonly utilized to mitigate these problems. This study investigates the rheological properties of CO2 hydrate slurries, specifically the impact of AOT. A capillary viscometer method and a dynamic loop were employed to assess fluid behavior and collect experimental data. The study reveals a shear-thinning behavior and emphasizes the potential of AOT in significantly improving the properties of CO2 hydrate slurries.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Engineering, Environmental
Peipei Su, Haitao Zhang, Lipeng Yang, Chunxian Xing, Shanshan Pan, Wei Lu, Suojiang Zhang
Summary: This study systematically investigates the effects of conductive additives on the rheological and electrochemical properties of suspension electrodes. The results show that different additives have different percolation thresholds and inflection points. The 1.5 wt.% KB-based suspension exhibits superior cycle and rate performances.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Xuewen Cao, Kairan Yang, Jiang Bian
Summary: A new CO2 hydrate slurry transport mode allowing partial dissociation of hydrate particles was proposed in this study to reduce costs and improve transportability. Experimental and multiphase flow model results showed that hydrate dissociation can decrease the viscosity of CO2 hydrate slurry flow, reducing pressure drop, increasing transportability, and decreasing the risk of hydrate blockage induced by agglomeration in pipes.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2021)
Review
Thermodynamics
Saeid Sinehbaghizadeh, Agus Saptoro, Amir H. Mohammadi
Summary: Global warming, caused by anthropogenic CO2 emissions, has become a pressing environmental concern. Natural gas hydrate reservoirs have emerged as a potential source of energy and a possible solution for CO2 sequestration. CO2 hydrates, as safe and non-flammable compounds, can be used in industrial processes if their approaches can be improved. Laboratory experiments, process modelling, and molecular dynamics simulations can aid in understanding the properties and mechanisms of CO2 hydrates. This review focuses on the sequestration of CO2, process flow diagrams, the effects of hydrate promoters and porous media, and the fundamental properties of CO2 hydrates at the molecular level.
PROGRESS IN ENERGY AND COMBUSTION SCIENCE
(2022)
Article
Engineering, Mechanical
Benedict Prah, Rin Yun
Summary: The study investigates the pressure drop and flow pattern analysis of CO2 hydrate slurry, finding that an increase in flow rate leads to an increase in pressure drop gradient. The CO2 hydrate slurry can be divided into active formation and less active formation regions, with flow regimes dependent on the fraction of hydrates in the slurry mixture.
JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY
(2021)
Article
Engineering, Marine
Weiqi Fu, Wei Wei, Hao Wang, Bingxiang Huang, Zhiyuan Wang
Summary: The rheological properties of CO2 hydrate slurry were experimentally studied using a new flow loop. The slurry was found to be a powerlaw fluid with strong shear-thickening behavior. The increase in volumetric hydrate concentration not only increased the apparent viscosity, but also enhanced the non-Newtonian behavior.
JOURNAL OF MARINE SCIENCE AND ENGINEERING
(2022)
Article
Engineering, Environmental
Youngki Lee, Hyeonjin Kim, Wonhyeong Lee, Dong Woo Kang, Jae W. Lee, Yun-Ho Ahn
Summary: This review explores the potential of clathrate hydrates as a technology for CO2 capture and separation, showcasing methods to improve CO2 hydrate formation and separate CO2 from gas mixtures. It also delves into additional applications such as cold energy storage and the advantages of the CH4-CO2 replacement method.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Thermodynamics
Zhongjin He, Fengyi Mi, Fulong Ning
Summary: Microsecond molecular simulations were conducted to investigate the impact of surface properties on CO2 hydrate formation in slit-nanopores of graphite and hydroxylated-silica surfaces. The results showed that different surface properties affect hydrate formation primarily by altering the aqueous CO2 concentration. Hydrophobic graphite surfaces adsorbed CO2 molecules strongly, reducing the aqueous CO2 concentration, while hydrophilic silica surfaces led to high aqueous CO2 concentration due to the adsorption of CO2 nanobubbles.
Article
Public, Environmental & Occupational Health
Steven Duret, Hong-Minh Hoang, Evelyne Derens-Bertheau, Anthony Delahaye, Onrawee Laguerre, Laurent Guillier
Article
Thermodynamics
Fabien Raoult, Stephanie Lacour, Bertrand Carissimo, Francois Trinquet, Anthony Delahaye, Laurence Fournaison
APPLIED THERMAL ENGINEERING
(2019)
Article
Thermodynamics
Ziad Youssef, Laurence Fournaison, Anthony Delahaye, Michel Pons
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID
(2019)
Article
Thermodynamics
P. E. Vende, F. Trinquet, S. O. L. Lacour, A. Delahaye, L. Fournaison
INTERNATIONAL JOURNAL OF THERMAL SCIENCES
(2019)
Article
Energy & Fuels
Thomas Dufour, Hong Minh Hoang, Jeremy Oignet, Veronique Osswald, Laurence Fournaison, Anthony Delahaye
Article
Thermodynamics
S. O. L. Lacour, F. Raoult, C. Tinet, L. Fournaison, A. Delahaye, F. Trinquet
EXPERIMENTAL THERMAL AND FLUID SCIENCE
(2019)
Article
Thermodynamics
R. Ben-Abdallah, D. Leducq, H. M. Hoang, L. Fournaison, O. Pateau, B. Ballot-Miguet, A. Delahaye
ENERGY CONVERSION AND MANAGEMENT
(2019)
Review
Thermodynamics
Cyrine Damak, Denis Leducq, Hong Minh Hoang, Daniele Negro, Anthony Delahaye
INTERNATIONAL JOURNAL OF REFRIGERATION
(2020)
Article
Thermodynamics
Mahdjouba Akerma, Hong-Minh Hoang, Denis Leducq, Anthony Delahaye
INTERNATIONAL JOURNAL OF REFRIGERATION
(2020)
Article
Thermodynamics
Steven Duret, Erwann Hamon, Hong-Minh Hoang, Valerie Stahl, Evelyne Derens-Bertheau, Anthony Delahaye, Onrawee Laguerre
INTERNATIONAL JOURNAL OF REFRIGERATION
(2020)
Article
Energy & Fuels
Fatima Doria Benmesbah, Livio Ruffine, Pascal Clain, Veronique Osswald, Olivia Fandino, Laurence Fournaison, Anthony Delahaye
Article
Food Science & Technology
Steven Duret, Hong-Minh Hoang, Laurent Guillier, Evelyne Derens-Bertheau, Claire Dargaignaratz, Stephanie Oriol, Anthony Delahaye, Onrawee Laguerre, Christophe Nguyen-the
Summary: Food refrigeration is crucial for maintaining microbiological quality but comes with high energy consumption. Increasing refrigeration temperature in the processing plant can reduce electrical power consumption, but may also lead to an increase in microbiologically defective products. Raising the cooling tunnel temperature saves more energy compared to increasing cold room temperature while achieving similar impacts on microbiology.
Article
Green & Sustainable Science & Technology
Yasmine Salehy, Anthony Delahaye, Hong Minh Hoang, Laurence Fournaison, Francois Cluzel, Yann Leroy, Bernard Yannou
Summary: This paper proposes a generic approach to assess the potential of adoption for sustainable refrigeration systems by describing their multiple performances. Through modeling and simulation of four supermarket refrigeration systems, the study shows that the electricity mix is the most influential parameter on cost and environmental impact. While CO2 refrigerant systems show promising performances, the maintenance score can be a limiting factor for their installation. The study also explores the impact of photovoltaic panels and financial support on improving cost and environmental performances.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Engineering, Chemical
Y. Salehy, P. Clain, A. Boufares, N. Chami, J-P. Torre, D. Dalmazzone, L. Fournaison, A. Delahaye
Summary: Recent studies have explored the potential use of hydrate slurries in indirect refrigeration systems, but pipeline clogging issues due to hydrate agglomeration can arise. Additives, such as Dioctyl sodium sulfosuccinate (AOT), are commonly utilized to mitigate these problems. This study investigates the rheological properties of CO2 hydrate slurries, specifically the impact of AOT. A capillary viscometer method and a dynamic loop were employed to assess fluid behavior and collect experimental data. The study reveals a shear-thinning behavior and emphasizes the potential of AOT in significantly improving the properties of CO2 hydrate slurries.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Thermodynamics
Walid Samah, Pascal Clain, Francois Rioual, Laurence Fournaison, Anthony Delahaye
Summary: This study focuses on the growth, adhesion, and detachment phenomena of ice by liquid jets on different types of surfaces. The results show that ice adheres less to superhydrophobic surfaces and hydrophobic surfaces detach the ice layer faster compared to untreated surfaces.
APPLIED THERMAL ENGINEERING
(2024)