Article
Chemistry, Applied
Cheng Li
Summary: A consecutive reaction kinetics model (CRK) was developed in this study to fit long-term retrogradation kinetics curves for 10 rice starches with distinct molecular structures. Results showed that the nucleation and crystal growth steps of starch retrogradation were controlled by distinct starch fine molecular structures, providing practical applications for regulating the nutritional properties of starch-based foods.
Article
Chemistry, Applied
Cheng Li, Yiming Hu
Summary: A consecutive reaction kinetics model was developed to simulate the in vitro starch digestograms of retrograded rice starches, revealing that enzymatic binding is the rate-limiting step in the digestion process. Correlation analysis between CRK model-fitted parameters and starch structural parameters showed that enzymes exhibit distinct binding affinity and catalytic activity towards different starch chemical and physical structures.
FOOD HYDROCOLLOIDS
(2022)
Article
Polymer Science
Mengdi Chen, Jianna Bao, Mingfu Zheng, Xianming Zhang, Wenxing Chen
Summary: The MPP process can effectively increase the molecular weight of PC. Various analytical techniques were used to characterize the reaction products, revealing the presence of Fries rearrangement products. A reaction kinetic model was established to guide the MPP process of PC, which includes the Fries rearrangement reaction.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Engineering, Chemical
Dandan Lei, Xiao-Li Sun, Shasha Hu, Huibin Cheng, Qinghua Chen, Qingrong Qian, Qiao Xiao, Changlin Cao, Lireng Xiao, Baoquan Huang
Summary: Recycling waste PET fibers and recovering monomers is crucial for environmental and resource protection. By using a stepwise feeding process and adding the fibers to a glycolysis agent at an elevated temperature, the conversion rate of PET fibers and the yield of water-soluble products were significantly increased. However, the conversion rate and yield of fibers were lower than those of bottle flakes and particles.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Agricultural Engineering
Lin Hu, Xian-Yong Wei, Chenguang Wang, Mei-Ling Xu, Feng-Bin Zhang, Hai-Peng Lv, Zhi-Min Zong
Summary: This research systematically investigated the influence of methanolysis pretreatment on wheat straw, revealing significant changes in physicochemical structure and extracting oxygen-containing functional groups. The study also analyzed the pyrolysis kinetics and thermodynamics parameters, providing new insights into the pyrolysis process of biomass liquefaction residue.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Engineering, Environmental
Chun Chang, Shijie Wang, Pengkun Guo, Guizhuan Xu, Xiaoyang Zheng, Chaojun Du, Youzhou Jiao
Summary: This study investigates the production of methyl levulinate (ML) through metal sulfate-catalyzed methanolysis from high solid content of cellulose. The results show that high yields can be obtained under optimized reaction conditions, and the metal sulfate catalyst can be reused multiple times. The study also reveals that cellulose particles shrink over time.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Faisal Sultan, Muhammad Shahzad, Mehboob Ali, Anees Ur Rehman, Arshed Ali, Mohamed Altanji, Syed Inayat Ali Shah
Summary: This paper focuses on the participation of chemical species and the invariant region of the reaction mechanism, introducing a computational technique 'Spectral Quasi Equilibrium Manifold' (SQEM) for accurate grid points to achieve dimensional curves without compromising system accuracy.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Engineering, Environmental
Jian Cao, Guancong Jiang, Nannan Ye, Yao Qin, Xiaoyan Ji, Xin Feng, Jiahua Zhu, Yudan Zhu, Wenlong Xie, Xiaohua Lu
Summary: Porous catalysts have a significant role in heterogeneous reactions in the chemical industry, but quantitatively describing mass transfer and surface reaction behaviors in nano-confined space is still challenging. This study investigates the impact of confined mass transfer on reactivity in the synthesis of hydrogen peroxide (H2O2) and proposes optimization strategies.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Analytical
Zhenghua Lu, Zhenyu Liu, Xiaosheng Zhao, Yachuan Guo, Qingya Liu
Summary: In this study, it was found that methanolysis of oil shale resulted in higher oil yield compared to pyrolysis, with methanol promoting the conversion of oil shale at specific temperatures. Methanol extraction of pyrolysis products at low temperatures led to a decrease in yield, while coupling of methoxy moiety with organic matter at high temperatures resulted in the formation of oil components and increased yield. The complex reactions of methanol also led to its incorporation into the solid product, contributing to a higher solid yield in methanolysis compared to pyrolysis.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2021)
Article
Agriculture, Multidisciplinary
Cheng Li
Summary: The present study used a consecutive reaction kinetics model to fit the in vitro digestion curves for different starch fractions, and correlated the fitting parameters with starch molecular structures to understand the factors affecting the binding and catalytic rate constants. The results showed that the binding and catalytic rates were controlled by different starch structural features for different starch digestible fractions. These findings have important implications for understanding the nature of starch digestible fractions and developing foods with slow starch digestibility, such as rice.
JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE
(2023)
Article
Chemistry, Organic
Xiao-Ning Wang, Zhan-Cai Li, Yu Zhang, Bing-Xia Yan, Hong-Xing Zheng, Qiang Li, Chang-Qiu Zhao
Summary: A variety of menthyl-containing phosphinothioates were synthesized for the phosphorus-promoted cleavage of the C-S bond with lithium-naphthalene. The cleavage of C-S/P-S could be controlled by varying the amount of naphthalene and temperature. The retention of configuration about the P in P-S cleavage was utilized for stereospecific formation of the C-P bond.
ORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Multidisciplinary
Ryota Abe, Nobuyuki Komine, Kotohiro Nomura, Masafumi Hirano
Summary: Tris(acetylacetonato)lanthanum(iii) catalyst efficiently degrades various polyester materials, yielding high amounts of degradation products.
CHEMICAL COMMUNICATIONS
(2022)
Article
Environmental Sciences
Hossein Abedsoltan
Summary: This study presents the chemical recycling of poly (bisphenol-a carbonate) pellets using a hydrolysis technique with concentrated sulfuric acid as the catalyst. The effects of sulfuric acid concentration and reaction temperature on the hydrolysis rate were explored, and the catalyst reusability and the impact of hydrolysis on the polymer size reduction were also studied.
WASTE AND BIOMASS VALORIZATION
(2023)
Article
Engineering, Chemical
Pengcheng Zou, Kai Wang
Summary: A continuous tubular reaction technology is developed to safely intensify the methanolysis of amides. The kinetics of acetanilide methanolysis are determined and compared to hydrolysis, and the effects of various factors on the reaction performance are investigated. The method is also applied to test other amides.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Yuan-Yuan Cheng, Hong-Yu Hou, Yu Liu, Ji-Xin Yu, Bin Chen, Chen-Ho Tung, Li-Zhu Wu
Summary: This paper reports a direct strategy for the difunctionalization of alkenes using a single photocatalyst. The strategy allows for acylation at the more substituted alkene position with high chemo- and regioselectivity under extremely mild conditions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Automation & Control Systems
Minjeong Cho, Myungwan Han
JOURNAL OF PROCESS CONTROL
(2018)
Article
Engineering, Chemical
Minjeong Cho, Sanghwan Jo, Gunhyung Kim, Myungwan Han
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2014)
Article
Chemistry, Physical
Sujin Gong, Sunyoung Park, Won Choon Choi, Hwimin Seo, Na Young Kang, Myung Wan Han, Yong-Ki Park
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
(2014)
Article
Engineering, Chemical
Jongwon Lee, BeomSik Kim, Myungwan Han
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2019)
Article
Engineering, Chemical
Jongwon Lee, BeomSik Kim, Myungwan Han
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2019)
Article
Engineering, Chemical
Youngmin Jeong, Jonghyun Park, Myungwan Han
Summary: The power-to-gas (PTG) process involves transforming renewable electric energy into methane through electrolysis and methanation. Critical issues in the process include the fluctuating nature of renewable electric energy and the safe operation of the methanation reactor. A cooled recycle reactor with a multilayered catalyst is proposed for methanation, aiming to improve efficiency and flexibility but also posing design and control challenges.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Chemistry, Physical
Jinseong Jang, Myungwan Han
Summary: Methane tri-reforming combines steam reforming, dry reforming, and partial oxidation of methane in a single reactor, providing energy through the exothermic partial oxidation of methane. By optimizing the reactor structure and oxygen distribution, the heat and mass management issues in conventional tri-reformers can be addressed.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Engineering, Chemical
Jeongin Yang, Hyeongcheol Jeon, Myungwan Han
KOREAN CHEMICAL ENGINEERING RESEARCH
(2017)
Article
Engineering, Chemical
Jeongin Yang, Honggyu Lim, Sungkyu Lim, Gayoung Baek, Myungwan Han
KOREAN CHEMICAL ENGINEERING RESEARCH
(2016)
Article
Engineering, Chemical
Minjeong Cho, Jeongin Yang, Seunghyun Noh, Hongjae Joe, Myungwan Han
KOREAN CHEMICAL ENGINEERING RESEARCH
(2016)
Article
Engineering, Chemical
Gunhyung Kim, Minjeong Cho, Yeonghwan Jeon, Myungwan Han, Kyungsuk Kang
KOREAN CHEMICAL ENGINEERING RESEARCH
(2015)
Article
Engineering, Chemical
Sanghwan Jo, Gunhyung Kim, Minjeong Cho, Myungwan Han, Kyungsuk Kang
KOREAN CHEMICAL ENGINEERING RESEARCH
(2014)
Article
Engineering, Chemical
Jeongin Yang, Myungwan Han
KOREAN CHEMICAL ENGINEERING RESEARCH
(2018)
Article
Engineering, Chemical
Hyeongcheol Jeon, Myungwan Han
KOREAN CHEMICAL ENGINEERING RESEARCH
(2018)
Article
Engineering, Chemical
Jongwon Lee, Myungwan Han, Beomsik Kim
KOREAN CHEMICAL ENGINEERING RESEARCH
(2018)