Article
Engineering, Environmental
Hui Liu, Xudong Liu, Zhujiang Wang, Huimin Yi, Yingxue Fu, Lin Wu, Fenghua Shen, Pingshan Wang, Min Liu, Zhang Lin, Kaisong Xiang, Liyuan Chai
Summary: Converting SO2 into H2S is crucial in sulfur recovery and sulfur chemistry. However, the comproportionation of H2S and SO2 leads to undesired sulfur deposition. This study introduces a new electrolysis paradigm utilizing a gas-permeable catalyst membrane (Au/PTFE) to synthesize and separate H2S in situ, preventing sulfur deposition. The catalyst membrane electrolysis demonstrates high efficiency and operational stability, with 99.6% H2S Faraday efficiency and 99.1% separation efficiency.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Hao Wang, Jingxian Wu, Zhihuang Xiao, Zhejie Ma, Ping Li, Xinwei Zhang, Hongying Li, Xiangchen Fang
Summary: The study investigated the effects of sulfidation factors on the structure and performance of Mo-based catalysts, finding that the optimal sulfidation conditions were around 500 degrees C for 1 hour, with two simultaneous MoS2 formation routes identified during the process. A relationship between catalyst structure and catalytic performance was established, suggesting that edge Mo atoms cooperate with neighboring surface Mo sites to catalyze the reaction.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Analytical
Ya-Long Zheng, Zuo-Hu Chai, Wei Tang, Shuai Yan, Fang Dai, Bo Zhou
Summary: Reactive sulfur species (RSS) play essential roles in pathophysiological processes and are difficult to differentiate simultaneously using a single fluorescent probe. The mitochondria-targetable fluorescent probe NIR-NBD can distinguish Cys/Hcy/H2S, GSH, and SO2 by displaying multiple signal patterns and exhibits excellent selectivity and sensitivity. It has been successfully applied for monitoring mitochondrial SO2 and biothiols, visualizing endogenous SO2 generation, and exploring the role of biothiols in apoptosis.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Chemistry, Analytical
Shaohui Han, Hui Zhang, Jingpei Wang, Lei Yang, Minhuan Lan, Benhua Wang, Xiangzhi Song
Summary: By introducing an active triple bond into the molecular structure, sensors with good selectivity for distinguishing and detecting H2S and SO2 can be constructed. These sensors can not only detect the target substances in a dual-ratiometric manner, but also be successfully applied in living cells and zebrafish.
ANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Physical
Qiu Xu, Chungang Wang, Zongling Shang, Chao Zhang, Xinchao Wang, Qiang Liu, Lingling Dang, Yanchun Liu, Fengyu Zhao
Summary: This study investigates the transformation of lactones to diols over Cu/Al2O3 and CuLax/Al2O3 catalysts, and discusses the promoting role of LaOx species in improving the selectivity and stability of the catalysts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Multidisciplinary
Eva Martinez-Ahumada, Mariana L. Diaz-Ramirez, Miriam de J. Velasquez-Hernandez, Vojtech Jancik, Ilich A. Ibarra
Summary: MOFs have potential for capturing toxic gases, but their vulnerability to highly corrosive gases is a main drawback, although some examples have shown high chemical stability to certain gases. Understanding the role of different chemical functionalities within the pores of MOFs is crucial for achieving superior captures of toxic gases.
Article
Chemistry, Inorganic & Nuclear
Samuel G. Dunning, Nishesh Kumar Gupta, Joseph E. Reynolds, Monica Sagastuy-Brena, J. Gabriel Flores, Eva Martinez-Ahumada, Eli Sanchez-Gonzalez, Vincent M. Lynch, Aida Gutierrez-Alejandre, Julia Aguilar-Pliego, Kwang-Soo Kim, Ilich A. Ibarra, Simon M. Humphrey
Summary: This study presents the synthesis and unique properties of an environmentally friendly metal-organic framework material, Mn-CUK-1. Mn-CUK-1 exhibits reversible and efficient capture of H2O, SO2, and H2S, with the highest reported H2S capacity-to-surface area ratio among chemically stable MOFs. Mn-CUK-1 also displays temperature-induced structural flexibility and stepwise adsorption characteristics.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Analytical
Yuki Takimoto, Akira Monkawa, Kohki Nagata, Tomoko Gessei, Masahiro Kobayashi, Mariko Kinoshita, Toshiya Mori, Hiroyuki Kagi
Summary: A localized surface plasmon resonance (LSPR) sensor coated with a common metal-organic framework, zeolitic imidazolate framework-8 (ZIF-8), has been developed for detection of SO2 and H2S. Sensitivity to SO2 and H2S was enhanced by ZIF-8 and increasing relative humidity. The sensor could detect 0.1-20 ppm SO2 and 0.1-10 ppm H2S within 5 minutes at 70% relative humidity. The sensor's sensitivity and LSPR spectrum could be recovered multiple times by heating at 200 degrees C if exposed to lower concentrations of SO2 and H2S.
SENSORS AND ACTUATORS B-CHEMICAL
(2023)
Article
Chemistry, Physical
Hector R. Colon-Mercado, Scott A. Mauger, Maximilian B. Gorensek, Cy H. Fujimoto, Aaron A. Lando, Prabhu Ganesan, Benjamin H. Meekins, Noah D. Meeks
Summary: This research achieved the most efficient SO2-depolarized electrolysis (SDE) operation at high sulfuric acid concentrations through the optimization of operating conditions and cell components. Open porosity in the porous transport media (PTM) plays a significant role in SDE performance.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Inorganic & Nuclear
Ren Jian, Jiao Qing-Ze, Wang Tong, Geng Yun-Feng, Li Han-Sheng, Wu Qin, Shi Da-Xin, Zhao Yun, Feng Cai-Hong
Summary: The CoMoSx/CeO2-?-Al2O3 catalyst prepared by introducing a small amount of CeO2 showed improved catalytic activity, with 1.5% CeO2 content exhibiting the best performance. Under optimized conditions, SO2 can be efficiently converted to S.
CHINESE JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Environmental Sciences
Wenyu Sun, Matias Berasategui, Andrea Pozzer, Jos Lelieveld, John N. Crowley
Summary: The OH-initiated oxidation of SO2 is the dominant first step in the transformation of this atmospherically important trace gas to particulate sulfate. This study addressed an important omission in the kinetic database for this reaction and highlighted significant discrepancies in recommended parameterizations. The presence of water vapor significantly enhances the rate coefficients of the reaction.
ATMOSPHERIC CHEMISTRY AND PHYSICS
(2022)
Article
Chemistry, Physical
Baoliang Li, Qu Zhou, Ruochen Peng, Yiming Liao, Wen Zeng
Summary: In this study, the adsorption behaviors of four typical SF6 decomposing gases on MoS2 and Sc-MoS2 surfaces were investigated using density functional theory. It was found that Sc-MoS2 has excellent adsorption properties for SO2, SOF2, and SO2F2, but weak adsorption for H2S. The introduction of Sc atom as the active center significantly enhanced the adsorption effect for target gases.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Hegen Zhou, Hua Jin, Yanli Li, Yi Li, Shuping Huang, Wei Lin, Wenkai Chen, Yongfan Zhang
Summary: The adsorption and hydrogenation of carbon dioxide on gamma-Al2O3(110) surface-supported copper clusters of different sizes were studied using density functional theory calculations. It was found that CO2 activation was more pronounced at the partially hydroxyl-covered interface. The catalytic mechanisms of CO2 conversion to methanol were explored, and the formate pathway was identified as the preferred reaction pathway. However, surface hydroxylation had a negative effect on the catalytic activity in CO2 conversion.
Article
Chemistry, Applied
Chun Zhang, Chao Zhang, Jie Tang, Shengqing Ye, Mingliang Ma, Jie Wu
Summary: A method for the synthesis of gamma-keto sulfones through a metal-free reaction involving cyclopropanols, DABCO, (SO2)2, and alkyl halides is described. The reaction proceeds efficiently under mild conditions in the absence of any catalysts, additives, or oxidants, with a good tolerance towards various functional groups. The proposed mechanism involves the formation of a gamma-keto sulfinate intermediate in situ, which then undergoes nucleophilic substitution with alkyl halides to yield gamma-keto sulfones.
ADVANCED SYNTHESIS & CATALYSIS
(2021)
Article
Engineering, Environmental
Akash Bhimrao Shirsath, Mariam L. Schulte, Bjarne Kreitz, Steffen Tischer, Jan-Dierk Grunwaldt, Olaf Deutschmann
Summary: CO2 methanation via the Sabatier reaction using green H2 is a promising technique for achieving carbon-neutral energy balance. Nickel-based catalysts, due to their low cost and high activity, are commonly used. This study combined numerical simulations with microkinetics and mass transport limitations to compare the performance of two catalysts at different temperatures. Incorporating spectroscopy studies, the importance of integrating modeling with experiments was demonstrated to improve accuracy in multiscale models.
CHEMICAL ENGINEERING JOURNAL
(2023)