Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 47, Issue 23, Pages 9248-9255Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ie801129b
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Funding
- Nation High Technology RD Program [2005AA516040]
- Nation Key Basic R&D Program of China [2004CD719705]
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The objective of this study was to investigate the direct deoxy-liquefaction of poplar leaves with two kinds of catalysts (T203, Z409). The optimum conditions were found to be at a temperature of 623 K with 3% T203 and 5% Z409. The effect of these catalysts on the products was investigated, and the obtained results were compared with similar experiments without catalyst. The oil yield of 10.18% was obtained without catalyst and reached 12.22% with 3% T203. Higher oil yield of 16.18% was observed when 5% Z409 was used. The relative contents of hydrocarbons (alkanes and aromatics) were high to 42.91 and 55.89% when using 3% T203 and 5% Z409 as catalysts, and some light alkanes such as C7H16 and C8H18 were also detected in the oil. The most striking characteristics of the oils were that H/C > 1.75, oxygen content < 5.78%, and higher heating value > 44.33 MJ kg(-1).
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