4.6 Article

Strategies for the Immobilization of Homogeneous Catalysts and Their Use in the Synthesis of Carbamates

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 47, Issue 21, Pages 8032-8036

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ie8002599

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Funding

  1. REPSOL.YPF
  2. PETRI [PTR95-0874.OP]
  3. Consolider Ingenio 2010 [CSD2006-0003]
  4. Generalitat de Catalunya [2005SGR007777]
  5. Distinction for Research Promotion

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Different methods of immobilization of N,N'-bis(salicylidene)ethylenediaminocobalt(II), [Co(salen)] complex, using K10 montmorillonite and silica have been used. These supported catalysts are active in the oxidative carbonylation of aniline using NaI as a promoter. The principal products obtained are N,N'-diphenylurea and I 1-butyl-N-phenylcarbamate.

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