4.6 Article

Long-term performance of passive materials for removal of ozone from indoor air

Journal

INDOOR AIR
Volume 22, Issue 1, Pages 43-53

Publisher

WILEY-BLACKWELL
DOI: 10.1111/j.1600-0668.2011.00734.x

Keywords

Activated carbon; Green materials; Field studies; Deposition velocity; Carbonyls; Emissions

Funding

  1. United States Green Building Council [00021625]
  2. Texas Higher Education Coordinating Board [003658-0279-2007]

Ask authors/readers for more resources

The health effects associated with exposure to ozone range from respiratory irritation to increased mortality. In this paper, we explore the use of three green building materials and an activated carbon (AC) mat that remove ozone from indoor air. We studied the effects of long-term exposure of these materials to real environments on ozone removal capability and pre-and postozonation emissions. A field study was completed over a 6-month period, and laboratory testing was intermittently conducted on material samples retrieved from the field. The results show sustained ozone removal for all materials except recycled carpet, with greatest ozone deposition velocity for AC mat (2.5-3.8 m/h) and perlite-based ceiling tile (2.2-3.2 m/h). Carbonyl emission rates were low for AC across all field sites. Painted gypsum wallboard and perlite-based ceiling tile had similar overall emission rates over the 6-month period, while carpet had large initial emission rates of undesirable by-products that decayed rapidly but remained high compared with other materials. This study confirms that AC mats and perlite-based ceiling tile are viable surfaces for inclusion in buildings to remove ozone without generating undesirable by-products.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Construction & Building Technology

A national survey of window-opening behavior in United States homes

Glenn Morrison, John Cagle, Gauri Date

Summary: This study surveyed window- and door-opening behavior nationwide, finding that frequency and duration of window opening are associated with factors such as income, housing type, climate region, and ethnicity. Different regions and climates also show variations in window-opening behavior.

INDOOR AIR (2022)

Article Construction & Building Technology

Accumulation of polychlorinated biphenyls in fabrics in a contaminated building, and the effect of laundering

Barbara Kolarik, Glenn C. Morrison

Summary: The study found that in a contaminated indoor environment, PCBs can adsorb to fabrics, and washing and drying can effectively remove PCBs from fabrics, with mechanical drying being more effective than air-drying.

INDOOR AIR (2022)

Editorial Material Construction & Building Technology

How should we define an indoor surface?

Jonathan P. D. Abbatt, Glenn C. Morrison, Vicki H. Grassian, Manabu Shiraiwa, Charles J. Weschler, Paul J. Ziemann

INDOOR AIR (2022)

Review Construction & Building Technology

Temperature and indoor environments

Tunga Salthammer, Glenn C. Morrison

Summary: From a thermodynamic perspective, temperature is clearly defined for ideal physical systems, but in indoor environments, it is influenced by complex factors. Processes such as diffusion, partitioning equilibria, and chemical reactions are greatly affected by temperature, while transport processes are influenced by spatial temperature, momentum, pressure gradients, and indoor material properties. The thermal comfort needs of occupants and building design requirements also play a significant role in indoor environmental conditions.

INDOOR AIR (2022)

Editorial Material Engineering, Environmental

Why Indoor Chemistry Matters: A National Academies Consensus Report

Rima Habre, David C. Dorman, Jonathan Abbatt, William P. Bahnfleth, Ellison Carter, Delphine Farmer, Gillian Gawne-Mittelstaedt, Allen H. Goldstein, Vicki H. Grassian, Glenn Morrison, Jordan Peccia, Dustin Poppendieck, Kimberly A. Prather, Manabu Shiraiwa, Heather M. Stapleton, Meredith Williams, Megan E. Harries

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2022)

Article Engineering, Environmental

Understanding Ozone Transport and Deposition within Indoor Surface Boundary Layers

Gen Pei, Yuan Xuan, Glenn Morrison, Donghyun Rim

Summary: Ozone-initiated oxidation reactions on indoor surfaces have a significant impact on the chemical composition of indoor air and human exposure to air toxins. This study investigates the mechanisms of ozone reactions with realistic indoor surfaces using microscope scanning and detailed Computational Fluid Dynamics (CFD) simulation. The results show that the indoor surface topography affects ozone mass transport and uptake, providing insights into indoor chemistry and air quality implications.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2022)

Article Multidisciplinary Sciences

The influence of personal care products on ozone-skin surface chemistry

Glenn Morrison, Azin Eftekhari, Aixing Fan, Francesca Majluf, Jordan E. Krechmer

Summary: Personal care products can reduce the impact of ozone on the skin, but it hasn't been proven that they can mitigate the effects of air pollution on skin health.

PLOS ONE (2022)

Article Environmental Sciences

Analytical method interferences for perfluoropentanoic acid (PFPeA) and perfluorobutanoic acid (PFBA) in biological and environmental samples

Jacqueline Bangma, James McCord, Nathan Giffard, Kate Buckman, Jonathan Petali, Celia Chen, Daniel Amparo, Barbara Turpin, Glenn Morrison, Mark Strynar

Summary: While high-resolution MS is suitable for novel PFAS identification and quantification, low-resolution MS/MS is the more commonly used and affordable approach for routine PFAS monitoring. However, the interference of chemical compounds in the quantitative ion channel hinders the verification of PFPeA and PFBA on low-resolution instrumentation. Adjustments to analytical methods, such as altering LC conditions and using matched internal standards, are recommended to investigate and confirm PFBA and PFPeA detections in both biological and environmental samples.

CHEMOSPHERE (2023)

Article Engineering, Environmental

Indoor monoterpene emission rates from commercial cannabis cultivation facilities in Colorado

Kaitlin Urso, William Vizuete, Ryan Moravec, Andrey Khlystov, Alicia Frazier, Glenn Morrison

Summary: In 2019, a study conducted by the Colorado Department of Public Health and Environment's Air Pollution Control Division found that biogenic VOC emissions in cannabis cultivation facilities vary widely, with the highest emissions occurring during post-harvest activities such as trimming. The dominant terpenes measured in all facilities were beta-myrcene, terpinolene, and D-limonene.

JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION (2023)

Article Engineering, Environmental

Ozone-Initiated Yield of Reactive Oxygen Species in a Model Indoor Surface Film

Glenn Morrison, Ryan Moravec, Zhenduo Yao

Summary: Recent evidence suggests that indoor ozone chemistry products contribute to cardiovascular pathophysiology through the formation of reactive oxygen species (ROS) on indoor surfaces. The yield of condensed-phase ROS on a model indoor surface film exposed to ozone was measured, and it was found that approximately 46% of the consumed ozone formed ROS. These ROS persisted on the surface for several hours and could continue to form even in the absence of ozone.

ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS (2023)

Article Engineering, Environmental

Cloth-Air Partitioning of Neutral Per- and Polyfluoroalkyl Substances (PFAS) in North Carolina Homes during the Indoor PFAS Assessment (IPA) Campaign

Clara M. A. Eichler, Naomi Y. Chang, Elaine A. Cohen Hubal, Daniel E. Amparo, Jiaqi Zhou, Jason D. Surratt, Glenn C. Morrison, Barbara J. Turpin

Summary: During the Indoor PFAS Assessment (IPA) Campaign, concentrations of nine neutral PFAS were measured in air and cotton cloth in 11 homes in North Carolina. The study found that fluorotelomer alcohols were the dominant species in indoor air, while perfluorooctane sulfonamidoethanols accumulated most significantly in cloth. Cloth-air partition coefficients were derived for different PFAS and were positively correlated with the octanol-air partition coefficient. Temperature was found to have the greatest effect on PFAS accumulation.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Article Environmental Sciences

Assessment of aldehyde contributions to PTR-MS m/z 69.07 in indoor air measurements

Lisa Ernle, Nijing Wang, Gabriel Bekoe, Glenn Morrison, Pawel Wargocki, Charles J. J. Weschler, Jonathan Williams

Summary: Proton transfer reaction-mass spectrometry (PTR-MS) is commonly used for monitoring volatile organic compounds in indoor and outdoor environments. However, the use of mass-to-charge ratio m/z 69.07 as an indicator of indoor isoprene can be affected by the presence of aldehydes, especially when ozone levels are high.

ENVIRONMENTAL SCIENCE-ATMOSPHERES (2023)

Article Engineering, Environmental

Reducing Transdermal Uptake of Semivolatile Plasticizers from Indoor Environments: A Clothing Intervention

Stephanie C. Hammel, Azin Eftekhari, Clara M. A. Eichler, Chih-Wei Liu, Leena A. Nylander-French, Lawrence S. Engel, Kun Lu, Glenn C. Morrison

Summary: This pilot study suggests that wearing precleaned clothing can significantly reduce environmental exposure to phthalates and phthalate alternatives. The transdermal uptake of semivolatile organic compounds is influenced by everyday clothing.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Article Environmental Sciences

Quantifying the impact of relative humidity on human exposure to gas phase squalene ozonolysis products

Pascale S. J. Lakey, Andreas Zuend, Glenn C. Morrison, Thomas Berkemeier, Jake Wilson, Caleb Arata, Allen H. Goldstein, Kevin R. Wilson, Nijing Wang, Jonathan Williams, Jonathan P. D. Abbatt, Manabu Shiraiwa

Summary: Studies have shown that the reaction of squalene with ozone can produce various products, and the yield depends on relative humidity. A new mechanism has been developed to simulate these reactions and control the concentrations of different products accordingly. Increasing relative humidity significantly impacts the concentrations of various products.

ENVIRONMENTAL SCIENCE-ATMOSPHERES (2023)

Article Chemistry, Analytical

Partitioning of reactive oxygen species from indoor surfaces to indoor aerosols

Glenn C. Morrison, Azin Eftekhari, Pascale S. J. Lakey, Manabu Shiraiwa, Bryan E. Cummings, Michael S. Waring, Brent Williams

Summary: Field studies suggest that indoor sources of reactive oxygen species (ROS) contribute to measured ROS on particulate matter (PM) in indoor air. This study supports the hypothesis that ozone-induced formation of organic peroxides (OPX) on indoor surfaces, and subsequent partitioning to aerosols, is sufficient to explain field observations.

ENVIRONMENTAL SCIENCE-PROCESSES & IMPACTS (2022)

No Data Available