4.5 Article

The role of the counter-ions present in syntheses on the thermal stabilization of strontium and/or calcium apatites

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ELSEVIER
DOI: 10.1016/j.mseb.2015.05.003

Keywords

Hydroxyapatite; Doping; Co-substitution; Temperature-programmed desorption; Strontium

Funding

  1. FAPITEC/SE
  2. CAPES
  3. CNPq

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The goal of this work was to study the thermal stabilization of calcium apatites in which the Ca2+ ions were substituted for Sr2+ in increasing concentrations via ionic co-substitutions. Two distinct standard syntheses were proposed for comparative purposes: one using counter-ions that were not easily incorporated into the apatite structure (NH4+/NO3-) and.one using counter-ions that can be easily incorporated into the structure (Na+/Cl-). After calcination, only the apatites synthesized in the presence of NH4+/NO(3)(-)presented phase transformation. In contrast, the apatites synthesized in the presence of Na+/Cl- formed a solid solution after calcination, with Na+, Ca2+, Sr2+ and Cl- sharing the same apatite lattice. Wavelength dispersive X-ray fluorescence spectroscopy (WDXRF), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and temperature-programmed desorption (TPD) techniques showed that the counter-ions present during the syntheses that are associated with CO32- play an important role in the thermal stabilization of the apatites. (C) 2015 Elsevier B.V. All rights reserved.

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