4.5 Article

Synthesis and electrochemical study of Mg1.5MnO3: A defect spinel cathode for rechargeable magnesium battery

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ELSEVIER
DOI: 10.1016/j.mseb.2015.08.008

Keywords

Magnesium; Defect oxide spinel; Nanocrystalline materials; Electrochemistry; X-ray photoelectron spectroscopy

Funding

  1. Department of Energy's National Energy Technology Laboratory's program DOE-NETL [DE-FE0004000]
  2. Center for Complex Engineered Multifunctional Materials (CCEMM)
  3. Edward R. Weidlein Chair Professorship funds

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Mg1.5MnO3, a defect oxide spinel (space group: Fd3m; unit cell: 0.833294 nm) of particle size similar to 100 nm derived by the Pechini route was tested as a cathode for rechargeable magnesium battery. Cyclic voltammetry illustrates a reversible reaction occurring in the 0.3-2.0 V potential window versus magnesium. The spinel however exhibits a low capacity of similar to 12.4 mAh/g up to 20 cycle when cycled at a current rate of similar to C/27. X-ray photoelectron spectroscopy surface probe of magnesiated/de-magnesiated electrodes confirms the oxidation state change of Mn during intercalation/de-intercalation of Mg-ion from the Mg1.5MnO3 electrode. The low capacity of Mg1.5MnO3 electrode mainly stem from the kinetic limitation of Mg-ion removal from the defect oxide spinel as the electrochemical impedance spectroscopy results of electrodes show that charge transfer resistance, R-e increases in the de-magnesiated state. (C) 2015 Elsevier B.V. All rights reserved.

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