4.6 Article

Evident improvement of nitrogen-doped graphene on visible light photocatalytic activity of N-TiO2/N-graphene nanocomposites

Journal

MATERIALS RESEARCH BULLETIN
Volume 65, Issue -, Pages 27-35

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2015.01.031

Keywords

Composite; Solvothermal; Semiconductor; Nanostructure

Funding

  1. National Natural Science Foundation of China (NSFC) [U1304212, 21274133]

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Nanocomposites N-TiO2/N-graphene (NTNG) are synthesized through the separate N-doping of titanium dioxide and graphene oxide avoiding the potential redoping of N-TiO2 with the aim clearly to investigate the individual N-doping effect of graphene oxide in NTNG on the photodegradation performance. The as-prepared nanocomposites are respectively characterized by XPS, IR, UV-vis diffused reflectance, XRD and TEM. The XPS results revealed the successful N-doping of TiO2 and graphene oxide. The visible light photodegradation performance of NTNG is higher than that of NTG. The fitted apparent first-order kinetics rate constant k(a) obviously indicated that the N-doping of graphene oxide in NTNG causes the 2.4-times increase of photodegradation activity compared with that of N-TiO2/graphene oxide (NTG) while the introduction of N-graphene totally results in the 5.5-times increase compared to that of N-TiO2 nanoparticles. (C) 2015 Elsevier Ltd. All rights reserved.

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