4.7 Article

Glyphosate and AMPA in the estuaries of the Baltic Sea method optimization and field study

Journal

MARINE POLLUTION BULLETIN
Volume 100, Issue 1, Pages 577-585

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.marpolbul.2015.08.015

Keywords

Glyphosate; AMPA; Herbicide; LC-MS/MS; Baltic Sea estuaries

Funding

  1. Leibniz Institute for Baltic Sea Research Warnemuende, Germany

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Water samples from ten German Baltic estuaries were collected in 2012 in order to study the presence of the herbicide glyphosate, its primary metabolite AMPA and their potential transport to the marine environment. For the analyses an LC-MS/MS based analytical method after derivatization with FMOC-Cl was optimized and validated for marine water samples. All investigated estuarine stations were contaminated with AMPA and nine of them also with glyphosate. Concentration ranges observed were 28 to 1690 ng/L and 45 to 4156 ng/L for glyphosate and AMPA, respectively with strong spatial and temporal fluctuations. Both contaminants were found at inbound sampling sites in the stream Muehlenfliess and concentrations decreased along the salinity gradient to the estuaries of the Baltic Sea. The data obtained in this study clearly depict the transport of glyphosate and AMPA to the Baltic Sea. Hence, detailed fate and risk assessment for both contaminants in marine environments are required. (C) 2015 Elsevier Ltd. All rights reserved.

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