Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 36, Issue 22, Pages 1987-1993Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201500367
Keywords
alternating copolymers; cyclic polymers; UV-induced Diels-Alder reactions
Categories
Funding
- Ministry of Science and Technology of China [2014CB932200, 2012CB933200]
- National Science Foundation of China [21374122, 51203171, 21474070]
- Chinese Academy of Sciences
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Cyclic polymers with alternating monomer sequence are synthesized for the first time based on the ring-closure strategy. Well-defined telechelic alternating polymers are synthesized by reversible addition-fragmentation chain transfer polymerization by copolymerizing the electron acceptor monomer of N-benzylmaleimide and donor monomer of styrene with a feed ratio of 1 between them. The corresponding cyclic alternating polymers are then produced by the UV-induced Diels-Alder click reaction to ring-close the linear alternating polymer precursors under highly diluted reaction solution.
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