Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 36, Issue 24, Pages 2192-2197Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201500494
Keywords
8-shape; coumarin; fluorescence; macrocycles
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Funding
- National Natural Science Foundation of China [21374107]
- Fundamental Research Funds for the Central Universities [WK 2060200012]
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Cyclic polystyrene (PS) with a pendant coumarin group is prepared by the combination of atom transfer radical polymerization and click chemistry. Fluorescence resonance energy transfer process is observed in the fluorescence measurement of coumarin-containing PS, and cyclic PS exhibits stronger emission than that of its linear precursor. When cyclic PS is irradiated under UV light at lambda = 365 nm, 8-shaped PS is achieved due to the dimerization of pendant coumarin group. Subsequently, 8-shaped PS can be divided into single macrocycle under UV irradiation at lambda = 254 nm via the photocleavage of coumarin dimer. The photoinduced coupling and dissociation are monitored by UV/vis spectra and gel permeation chromatography (GPC).
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