The near-IR spectrum of Titan modeled with an improved methane line list

We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of similar to 5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to similar to 2.1 mu m. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 mu m. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 mu m and allow us to model regions, such as the 1.55 mu m window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 mu m and 2 mu m windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 mu m region to determine a D/H ratio of 1.77 +/- 0.20 x 10(-4), and a CO mixing ratio of 50 +/- 11 ppmv. In the 2 mu m window we detect absorption features that can be identified with the nu(5) + 3 nu(6) and 2 nu(3) + 2 nu(6) bands of CH3D. (C) 2011 Elsevier Inc. All rights reserved.