Journal
HETEROCYCLES
Volume 81, Issue 5, Pages 1149-1155Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-10-11930
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Funding
- Academic Frontier Project for Private Universities
- MEXT (Ministry of Education, Culture, Sports, Science and Technology) [2007-2010]
- Grants-in-Aid for Scientific Research [20390002, 21790001] Funding Source: KAKEN
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Asymmetric N-H insertion of phenyldiazoacetates with anilines catalyzed cooperatively by achiral dirhodium(II) carboxylates and cinchona alkaloids is described. A new catalytic system of dirhodium(II) tetrakis(triphenylacetate), Rh(2)(TPA)(4), and dihydrocinchonine provides phenylglycine derivatives in up to 71% ee.
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