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Frost-resistant polymeric material based on unsaturated polyketone and chlorine-containing epoxy oligomers

PUBLISHED July 03, 2023 (DOI: https://doi.org/10.54985/peeref.2307p4784616)



Konstantin Dubkov1 , Oleg Sidorov2 , Dmitriy Belyakov2 , Sergej Semikolenov1
  1. Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
  2. Soyuz Federal Center for Dual-Use Technologies, Russia

Conference / event

The 8th Asian Symposium on Advanced Materials (ASAM-8), July 2023 (Novosibirsk, Russian Federation)

Poster summary

It is promising to use a new type of reactive oligomers, namely, unsaturated polyketones (UPKs) as a basis for creation of polymeric compositions with enhanced properties. In this work, a new polymeric material was formulated using UPK containing 7.8 wt. % oxygen in the form of C=O groups, chlorine-containing epoxy oligomers, quinol ether as a cross-linking agent for UPK, isomethyl tetrahydrophthalic anhydride as a cross-linking agent for epoxy oligomers, and ionic liquid as a catalyst for curing epoxy oligomers. The developed polymeric material exhibits elastic properties in a wide temperature range and is characterized by an increase in deformation with a decrease in temperature from +50°C to –50°C, as well as by a low swelling capacity (no more than 5.5% at 70°C) in mineral oil. This material is promising for application in a wide temperature range (including low temperatures) in various fields of technology.


Polymeric materials, Modification, Epoxy oligomers, Unsaturated polyketone

Research areas

Material Sciences


  1. Dubkov K.A., Semikolenov S.V., D.E. Babushkin, et al., J. Polym. Sci. A, 44(2006) 2510-2520.
  2. Dubkov K.A., Panov G.I., Parmon V.N., Russ. Chem. Rev., 2017, 86, 510–529.
  3. Sidorov O.I., Dubkov K.A., et al., Polym. Sci., Ser. D, 11(2018) 215-224.
  4. Sidorov O.I., Evseev N.E., et al., Polym. Sci., Ser. D, 13(2020) 85-88.


No data provided

Supplemental files

No data provided

Additional information

Competing interests
No competing interests were disclosed.
Data availability statement
The datasets generated during and / or analyzed during the current study are available from the corresponding author on reasonable request.
Creative Commons license
Copyright © 2023 Dubkov et al. This is an open access work distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Dubkov, K., Sidorov, O., Belyakov, D., Semikolenov, S. Frost-resistant polymeric material based on unsaturated polyketone and chlorine-containing epoxy oligomers [not peer reviewed]. Peeref 2023 (poster).
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