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Acetylene hydrogenation over Pd/MgO nanocrystalline system: Effect of the synthesis route on catalytic performance

PUBLISHED June 30, 2023 (DOI: https://doi.org/10.54985/peeref.2306p8263363)

NOT PEER REVIEWED

Authors

Ekaterina Ilyina1 , Daria Yurpalova2 , Dmitriy Shlyapin2 , Gregory Veselov1 , Danil Shivtsov1 , Vladimir Stoyanovskii1 , Aleksey Vedyagin1
  1. Boreskov Institute of Catalysis
  2. Center of New Chemical Technologies BIC

Conference / event

8th Asian Symposium on Advanced Materials ASAM-8, July 2023 (Novosibirsk, Russian Federation)

Poster summary

In this work, a series of 1 wt.% Pd/MgO catalysts was synthesized. Such methods as aerogel preparation, xerogel preparation, and incipient wetness impregnation were used. It was shown that the preparation route affects texture and dispersion of the active metal. The Pd/MgO catalysts were investigated in the process of acetylene hydrogenation to ethylene (4% C2H2 + 96% H2; 20 – 90 °C). It was found that the aerogel method is promising for the synthesis of Pd/MgO catalyst for selective hydrogenation of acetylene to ethylene.

Keywords

Aerogel, Incipient wetness impregnation, Acetylene hydrogenation, Xerogel, Pd/MgO, Catalysis

Research areas

Chemical Engineering, Material Sciences, Nanoengineering, Chemistry

References

  1. A. Borodziński, G. Bond, Catal. Rev. Sci. Eng. 48 (2006) 91-144.
  2. D.A. Shlyapin, D.V. Glyzdova, T.N. Afonasenko et al. Kinet. Catal. 60 (2019) 446-452.
  3. Z. Guan, M. Xue, Z. Li, R. Zhang, B. Wang, Appl. Surf. Sci. 503 (2020) 144142.
  4. Y. He, J. Fan, J. Feng, C. Luo, P. Yang, D. Li, J. Catal. 331 (2015) 118-127.

Funding

  1. Ministry of Science and Higher Education of the Russian Federation (No. AAAA-A21-121011390054-1)

Supplemental files

No data provided

Additional information

Competing interests
No competing interests were disclosed.
Data availability statement
The datasets generated during and / or analyzed during the current study are available from the corresponding author on reasonable request.
Creative Commons license
Copyright © 2023 Ilyina et al. This is an open access work distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Ilyina, E., Yurpalova, D., Shlyapin, D., Veselov, G., Shivtsov, D., Stoyanovskii, V., Vedyagin, A. Acetylene hydrogenation over Pd/MgO nanocrystalline system: Effect of the synthesis route on catalytic performance [not peer reviewed]. Peeref 2023 (poster).
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