Benign catalysis with zinc: atom-economical and divergent synthesis of nitrogen heterocycles by formal [3 + 2] annulation of isoxazoles with ynol ethers

Gold-Catalyzed Regiospecific C−H Annulation of o -Ethynylbiaryls with Anthranils: π-Extension by Ring-Expansion En Route to N-Doped PAHs

(2018) Zhongyi Zeng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc-catalyzed reaction of isoxazoles with thioynol ethers involving an unprecedented 1,2-sulfur migration

(2018) Xin-Qi Zhu et al.   CHEMICAL COMMUNICATIONS

Transition-metal-free oxidative cyclization of N-propargyl ynamides: stereospecific construction of linear polycyclic N-heterocycles

(2018) Cai-Ming Wang et al.   GREEN CHEMISTRY

Gold-Catalyzed [4 + 1]-Annulation Reactions between 1,4-Diyn-3-ols and Isoxazoles To Construct a Pyrrole Core

(2018) Rahul Dadabhau Kardile et al.   ORGANIC LETTERS

Gold-catalyzed [4+3]- and [4+2]-annulations of 3-en-1-ynamides with isoxazoles via novel 6π-electrocyclizations of 3-azahepta trienyl cations

(2018) Sovan Sundar Giri et al.   Chemical Science

Highly Enantioselective Copper- and Iron-Catalyzed Intramolecular Cyclopropanation of Indoles

(2017) Huan Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in transition-metal-catalyzed reactions of alkynes with isoxazoles

(2017) Long Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ynol Ethers as Ketene Equivalents in Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition Reactions

(2017) Paul A. Wender et al.   ORGANIC LETTERS

α-Imino Gold Carbenes from 1,2,4-Oxadiazoles: Atom-Economical Access to Fully Substituted 4-Aminoimidazoles

(2017) Zhongyi Zeng et al.   ORGANIC LETTERS

Gold-Catalyzed Formal [3 + 2] Cycloaddition of Ynamides with 4,5-Dihydro-1,2,4-oxadiazoles: Synthesis of Functionalized 4-Aminoimidazoles

(2017) Wei Xu et al.   ORGANIC LETTERS

Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold

(2017) Wen-Bo Shen et al.   Nature Communications

Reversal of Regioselectivity in Catalytic Arene-Ynamide Cyclization: Direct Synthesis of Valuable Azepino[4,5-b]indoles and β-Carbolines and DFT Calculations

(2017) Long Li et al.   ACS Catalysis

Tandem Bond-Forming Reactions of 1-Alkynyl Ethers

(2016) Thomas G. Minehan   ACCOUNTS OF CHEMICAL RESEARCH

Friedel-Crafts-Type Intermolecular C−H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts

(2016) Qin Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Annulation of Alkynyl Aryl Ethers with Allyl Pivalates To Give 2,3-Bismethylenechromanes through Double C−H Bond Cleavage

(2016) Yasunori Minami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development of Gold-catalyzed [4+1] and [2+2+1]/[4+2] Annulations between Propiolate Derivatives and Isoxazoles

(2016) Rajkumar Lalji Sahani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Synthesis of Quinolines from Propargyl Silyl Ethers and Anthranils through the Umpolung of a Gold Carbene Carbon

(2016) Hongming Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Site Selective Formal [5+2] and [4+2] Annulations of Isoxazoles with Heterosubstituted Alkynes by Platinum Catalysis: Rapid Access to Functionalized 1,3-Oxazepines and 2,5-Dihydropyridines

(2016) Wen-Bo Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dioxazoles, a new mild nitrene transfer reagent in gold catalysis: highly efficient synthesis of functionalized oxazoles

(2016) Ming Chen et al.   CHEMICAL COMMUNICATIONS

Switchable Synthesis of Pyrroles and Pyrazines via Rh(II)-Catalyzed Reaction of 1,2,3-Triazoles with Isoxazoles: Experimental and DFT Evidence for the 1,4-Diazahexatriene Intermediate

(2016) Nikolai V. Rostovskii et al.   JOURNAL OF ORGANIC CHEMISTRY

The chemistry of ynol and thioynol ethers

(2016) Vincent James Gray et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Biologically active γ-lactams: synthesis and natural sources

(2016) J. Caruano et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent progress towards gold-catalyzed synthesis of N-containing tricyclic compounds based on ynamides

(2016) Fei Pan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Gold-Catalyzed Intermolecular Ynamide Amination-Initiated Aza-Nazarov Cyclization: Access to Functionalized 2-Aminopyrroles

(2016) Chao Shu et al.   ORGANIC LETTERS

Rh(II)-Catalyzed Transannulation of N-Sulfonyl-1,2,3-Triazoles with 2,1-Benzisoxazoles or 1,2-Benzisoxazoles

(2016) Xiaoqiang Lei et al.   ORGANIC LETTERS

Synthesis of fused isoquinolines via gold-catalyzed tandem alkyne amination/intramolecular O–H insertion

(2016) Yuan Pan et al.   Organic Chemistry Frontiers

Recent Developments in the Synthesis and Reactivity of Isoxazoles: Metal Catalysis and Beyond

(2015) Feng Hu et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Ring Expansion of Cyclic Hemiaminals for the Synthesis of Medium-Ring Lactams

(2015) Wanxiang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc-Catalyzed Alkyne Oxidation/CH Functionalization: Highly Site-Selective Synthesis of Versatile Isoquinolones and β-Carbolines

(2015) Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Dearomatization of Indoles through a Michael/Friedel-Crafts-Type Cascade To Construct Polycyclic Spiroindolines

(2015) Xiaohu Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed CH Annulation of Anthranils with Alkynes: A Facile, Flexible, and Atom-Economical Synthesis of Unprotected 7-Acylindoles

(2015) Hongming Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A rapid and selective synthesis of α,α-fluorohalo esters via fluorohalogenative or difluorinative hydration of ynol ethers

(2015) Liang Hu et al.   CHEMICAL COMMUNICATIONS

Atom-Economic Synthesis of Fully Substituted 2-Aminopyrroles via Gold-Catalyzed Formal [3+2] Cycloaddition between Ynamides and Isoxazoles

(2015) Xin-Yu Xiao et al.   Chemistry-An Asian Journal

Generation of α-Imino Gold Carbenes through Gold-Catalyzed Intermolecular Reaction of Azides with Ynamides

(2015) Chao Shu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(II)-Catalyzed Formal [3 + 2] Cycloaddition of N-Sulfonyl-1,2,3-triazoles with Isoxazoles: Entry to Polysubstituted 3-Aminopyrroles

(2015) Xiaoqiang Lei et al.   ORGANIC LETTERS

Atom-economic generation of gold carbenes: gold-catalyzed formal [3+2] cycloaddition between ynamides and isoxazoles

(2015) Ai-Hua Zhou et al.   Chemical Science

Enantioselective Palladium-Catalyzed Insertion of α-Aryl-α-diazoacetates into the OH Bonds of Phenols

(2014) Xiu-Lan Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Hydroarylation, Hydroalkenylation, and Hydrobenzylation of Ynol Ethers with Organohalides: A Regio- and Stereoselective Entry to α,β- and β,β-Disubstituted Alkenyl Ethers

(2014) Weijian Cui et al.   JOURNAL OF ORGANIC CHEMISTRY

Mild Aminoacylation of Indoles and Pyrroles through a Three-Component Reaction with Ynol Ethers and Sulfonyl Azides

(2014) Joshua S. Alford et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent progress towards transition metal-catalyzed synthesis of γ-lactams

(2014) Long-Wu Ye et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Photochemical One-Pot Three-Component Synthesis of Tetrasubstituted Imidazoles

(2014) Stefan Pusch et al.   ORGANIC LETTERS

Ynamides in Ring Forming Transformations

(2013) Xiao-Na Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Pd-catalyzed addition of boronic acids to ynol ethers: a highly regio- and stereoselective synthesis of trisubstituted vinyl ethers

(2013) Yihui Bai et al.   CHEMICAL COMMUNICATIONS

Synthesis of Cyclopentadiene-Fused Chromanones via One-Pot Multicomponent Reactions

(2013) Mehdi Ghandi et al.   JOURNAL OF ORGANIC CHEMISTRY

C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle

(2013) Timo Stahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Strategy for Efficient Synthesis of Medium and Large Ring Lactones without High Dilution or Slow Addition

(2013) Wanxiang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterocycle–Heterocycle Strategies: (2-Nitrophenyl)isoxazole Precursors to 4-Aminoquinolines, 1H-Indoles, and Quinolin-4(1H)-ones

(2013) Keith C. Coffman et al.   ORGANIC LETTERS

Chain-Walking Strategy for Organic Synthesis: Catalytic Cycloisomerization of 1,n-Dienes

(2012) Takuya Kochi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Using Nazarov Electrocyclization to Stage Chemoselective [1,2]-Migrations: Stereoselective Synthesis of Functionalized Cyclopentenones

(2011) David Lebœuf et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Nazarov Reaction Catalyzed by Chiral Tris(oxazoline)/Copper(II)

(2010) Peng Cao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ynamides: Versatile Tools in Organic Synthesis

(2010) Gwilherm Evano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ynamides: A Modern Functional Group for the New Millennium

(2010) Kyle A. DeKorver et al.   CHEMICAL REVIEWS

One-Pot Synthesis of Highly Functionalized Pyridines via a Rhodium Carbenoid Induced Ring Expansion of Isoxazoles

(2008) James R. Manning et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY