Ynamides: Versatile Tools in Organic Synthesis

On the Role of Metal Contaminants in Catalyses with FeCl3

(2009) Stephen L. Buchwald et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Coupling of 1,1-Dibromo-1-alkenes with Nitrogen Nucleophiles: A General Method for the Synthesis of Ynamides

(2009) Alexis Coste et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First total synthesis of antiostatin A1, a potent carbazole-based naturally occurring antioxidant

(2009) Carole Alayrac et al.   CHEMICAL COMMUNICATIONS

Synthesis of Tricyclic Fused 3-Aminopyridines through Intramolecular CoI-Catalyzed [2+2+2] Cycloaddition between Ynamides, Nitriles, and Alkynes

(2009) Pierre Garcia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Atropisomerism of α,β-Unsaturated Amidines: Stereoselective Synthesis by Catalytic Cascade Reaction and Optical Resolution

(2009) Naoya Shindoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation and Hydrozincation of Ynamides

(2009) Benoit Gourdet et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Amidation of Alkynyl Bromides: A Facile Route for the Preparation of Ynamides

(2009) Bangben Yao et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Synthesis of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation of Ynamides

(2009) Benoit Gourdet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A unique approach to aldol products for the creation of all-carbon quaternary stereocentres

(2009) Jaya Prakash Das et al.   Nature Chemistry

Synthesis of Amidines UsingN-Allyl Ynamides. A Palladium-Catalyzed Allyl Transfer through an Ynamido−π-Allyl Complex

(2009) Yu Zhang et al.   ORGANIC LETTERS

Highly Substituted 2-Amido-furans From Rh(II)-Catalyzed Cyclopropenations of Ynamides

(2009) Hongyan Li et al.   ORGANIC LETTERS

Highly Regioselective Au(I)-Catalyzed Hydroamination of Ynamides and Propiolic Acid Derivatives with Anilines

(2009) Søren Kramer et al.   ORGANIC LETTERS

Synthesis of KeteneN,N-Acetals by Copper-Catalyzed Double-Amidation of 1,1-Dibromo-1-alkenes

(2009) Alexis Coste et al.   ORGANIC LETTERS

A rhodium(I)-xylyl-BINAP catalyzed asymmetric ynamide-[2+2+2] cycloaddition in the synthesis of optically enriched N,O-biaryls

(2009) Jossian Oppenheimer et al.   TETRAHEDRON

Lithiation and functionalization of 1-alkynylimidazoles at the 2-position

(2009) Christophe Laroche et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed Intermolecular Ene–Yne Coupling: Development of an Atom-Efficient Mizoroki–Heck-Type Reaction

(2008) Anders T. Lindhardt (neé Hansen) et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Cycloaddition of Nitrile Oxides and Alkynes: Practical Synthesis of Isoxazoles

(2008) Scott Grecian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Stereoselective Additions of Diphenyldithiophosphinic Acid toN-(1-Alkynyl)amides and 1-Alkynyl Sulfides

(2008) Shigenari Kanemura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Silylcupration and Copper-Catalyzed Carbomagnesiation of Ynamides: Application to Aza-Claisen Rearrangement

(2008) Hiroto Yasui et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis

(2008) Gwilherm Evano et al.   CHEMICAL REVIEWS

Gold-Catalyzed Synthesis of Chroman, Dihydrobenzofuran, Dihydroindole, and Tetrahydroquinoline Derivatives

(2008) A. Stephen K. Hashmi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Irregularities in the Effect of Potassium Phosphate in Ynamide Synthesis

(2008) Karin Dooleweerdt et al.   JOURNAL OF ORGANIC CHEMISTRY

Coupling Reactions of Bromoalkynes with Imidazoles Mediated by Copper Salts: Synthesis of NovelN-Alkynylimidazoles

(2008) Christophe Laroche et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of α-Keto-Imides via Oxidation of Ynamides

(2008) Ziyad F. Al-Rashid et al.   JOURNAL OF ORGANIC CHEMISTRY

Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates

(2008) Andrea Buzas et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Copper-Catalyzed Aerobic Oxidative Amidation of Terminal Alkynes:  Efficient Synthesis of Ynamides

(2008) Tetsuya Hamada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed 1,2-Double Amination of 1-Halo-1-alkynes. Concise Synthesis of Protected Tetrahydropyrazines and Related Heterocyclic Compounds

(2008) Yasuhiro Fukudome et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Sequential Metal-Catalyzed C−N Bond Formation in the Synthesis of 2-Amido-indoles

(2008) Pei-Yuan Yao et al.   ORGANIC LETTERS

Nickel-Catalyzed Highly Regioselective Multicomponent Coupling of Ynamides, Aldehydes, and Silane: A New Access to Functionalized Enamides

(2008) Nozomi Saito et al.   ORGANIC LETTERS

Reactive Intermediates from DMDO Oxidation of Ynamides. Trapping of a de novo Chiral Push−Pull Carbene via Cyclopropanation

(2008) Ziyad F. Al-Rashid et al.   ORGANIC LETTERS

Synthesis of Functionalized Oxazolones by a Sequence of Cu(II)- and Au(I)-Catalyzed Transformations

(2008) Florin M. Istrate et al.   ORGANIC LETTERS

Mo−Au Combo Catalysis for Rapid 1,3-Rearrangement of Propargyl Alcohols into α,β-Unsaturated Carbonyl Compounds

(2008) Masahiro Egi et al.   ORGANIC LETTERS

Application of Ynamides in the Synthesis of 2-Amidoindoles

(2008) Karin Dooleweerdt et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Alkenylative Cyclization via Insertion of Alkene into Ruthenacyclopentene

(2008) Miwako Mori et al.   ORGANOMETALLICS

Synthesis of carbazoles by dehydro Diels–Alder reactions of ynamides

(2008) M. Fernanda Martínez-Esperón et al.   TETRAHEDRON

Gold-catalyzed cycloisomerizations of ene-ynamides

(2008) Sylvain Couty et al.   TETRAHEDRON

Highly efficient synthesis of α-amino amidines from ynamides by the Cu-catalyzed three-component coupling reactions

(2008) Ji Young Kim et al.   TETRAHEDRON LETTERS

Synthesis of optically enriched 1,2-aminoalcohols by [2,3]-Wittig rearrangements of 3-aza-allylic alcohol derivatives

(2008) Marion Barbazanges et al.   TETRAHEDRON LETTERS

Regio- and Stereoselective Hydrothiolation Reactions of Ynamides with Diphenyldithiophosphinic Acid: Straightforward Synthesis of KeteneN,S-Acetal Derivatives

(2007) Hiroto Yasui et al.   CHEMISTRY LETTERS