Terminal Oxo and Imido Transition-Metal Complexes of Groups 9-11

A General Mechanism for the Copper- and Silver-Catalyzed Olefin Aziridination Reactions: Concomitant Involvement of the Singlet and Triplet Pathways

(2013) Lourdes Maestre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A convenient synthesis of anthranilic acids by Pd-catalyzed direct intermolecular ortho-C–H amidation of benzoic acids

(2012) Ka-Ho Ng et al.   CHEMICAL COMMUNICATIONS

Spectroscopic capture and reactivity of S = 1/2 nickel(iii)–oxygen intermediates in the reaction of a NiII-salt with mCPBA

(2012) Florian Felix Pfaff et al.   CHEMICAL COMMUNICATIONS

High-valent oxo-molybdenum and oxo-rhenium complexes as efficient catalysts for X–H (X = Si, B, P and H) bond activation and for organic reductions

(2012) Sara C. A. Sousa et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

(2012) Aidan R. McDonald et al.   COORDINATION CHEMISTRY REVIEWS

Intrinsic properties and reactivities of mononuclear nonheme iron–oxygen complexes bearing the tetramethylcyclam ligand

(2012) Sam P. de Visser et al.   COORDINATION CHEMISTRY REVIEWS

Revisiting the Polyoxometalate-Based Late-Transition-Metal-Oxo Complexes: The “Oxo Wall” Stands

(2012) Kevin P. O’Halloran et al.   INORGANIC CHEMISTRY

Co(III) Imidos Exhibiting Spin Crossover and C–H Bond Activation

(2012) Evan R. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Trapping of an Elusive Copper–Tosylnitrene Intermediate Using Scandium Triflate

(2012) Subrata Kundu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Functionalization Reactivity of a Nickel–Imide

(2012) Stefan Wiese et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assembly and Properties of Heterobimetallic CoII/III/CaII Complexes with Aquo and Hydroxo Ligands

(2012) David C. Lacy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron Paramagnetic Resonance and Mössbauer Spectroscopy and Density Functional Theory Analysis of a High-Spin FeIV–Oxo Complex

(2012) Rupal Gupta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed sp3 C–H Amination

(2012) Raymond T. Gephart et al.   ORGANOMETALLICS

 -Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity

(2012) M. Srnec et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Capturing fleeting intermediates in a catalytic C-H amination reaction cycle

(2012) R. H. Perry et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes

(2012) Johannes Hohenberger et al.   Nature Communications

Dioxygen Activation in Soluble Methane Monooxygenase

(2011) Christine E. Tinberg et al.   ACCOUNTS OF CHEMICAL RESEARCH

Electrochemical evidence for catalytic water oxidation mediated by a high-valent cobalt complex

(2011) Derek J. Wasylenko et al.   CHEMICAL COMMUNICATIONS

Role of metal–oxo complexes in the cleavage of C–H bonds

(2011) A. S. Borovik   CHEMICAL SOCIETY REVIEWS

C–H oxidation by platinum group metal oxo or peroxo species

(2011) Meng Zhou et al.   CHEMICAL SOCIETY REVIEWS

ME and ME complexes of iron and cobalt that emphasize three-fold symmetry (E=O, N, NR)

(2011) Caroline T. Saouma et al.   COORDINATION CHEMISTRY REVIEWS

O–O Bond activation in H2O2 and (CH3)3C-OOH mediated by [Ni(cyclam)(CH3CN)2](ClO4)2: Different mechanisms to form the same Ni(iii) product?

(2011) Xavier Solans-Monfort et al.   DALTON TRANSACTIONS

The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates

(2011) John F. Berry   DALTON TRANSACTIONS

Direct-Coupling O2 Bond Forming a Pathway in Cobalt Oxide Water Oxidation Catalysts

(2011) Lee-Ping Wang et al.   Journal of Physical Chemistry Letters

Mechanism of N/O Bond Scission of N2O by an Unsaturated Rhodium Transient

(2011) José G. Andino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of Three-Coordinate Ni(III)-Imide Complexes

(2011) Vlad M. Iluc et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid C–H Bond Activation by a Monocopper(III)–Hydroxide Complex

(2011) Patrick J. Donoghue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

Chromium(v)-oxo and chromium(iii)-superoxo complexes bearing a macrocyclic TMC ligand in hydrogen atom abstraction reactions

(2011) Jaeheung Cho et al.   Chemical Science

Mechanism of Cobalt-Porphyrin–Catalyzed Aziridination

(2011) Kathrin H. Hopmann et al.   ACS Catalysis

Cp* Iridium Precatalysts for Selective C–H Oxidation via Direct Oxygen Insertion: A Joint Experimental/Computational Study

(2011) Meng Zhou et al.   ACS Catalysis

The mystery of cytochrome P450 Compound I

(2010) Christiane Jung   BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS

A scandium terminal imido complex: synthesis, structure and DFT studies

(2010) Erli Lu et al.   CHEMICAL COMMUNICATIONS

Scandium terminal imido complex induced C–H bond selenation and formation of an Sc–Se bond

(2010) Erli Lu et al.   CHEMICAL COMMUNICATIONS

C−H Bond Activations by Metal Oxo Compounds

(2010) Ahmet Gunay et al.   CHEMICAL REVIEWS

Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexes

(2010) Simone Friedle et al.   CHEMICAL SOCIETY REVIEWS

Replacement of an Oxo by an Imido Group in Oxotransferase Model Compounds: Influence on the Oxygen Atom Transfer

(2010) Nadia C. Mösch-Zanetti et al.   INORGANIC CHEMISTRY

Pseudotetrahedral d0, d1, and d2Metal−Oxo Cores within a Tris(alkoxide) Platform

(2010) Stanislav Groysman et al.   INORGANIC CHEMISTRY

Synthesis and Reactivity of Oxo-Peroxo-Vanadium(V) Bipyridine Compounds

(2010) Christopher R. Waidmann et al.   INORGANIC CHEMISTRY

Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis

(2010) James D. Blakemore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DFT Study of the Structure and Reactivity of the Terminal Pt(IV)-Oxo Complex Bearing No Electron-Withdrawing Ligands

(2010) Irena Efremenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen-Atom Abstraction from Ni(I) Phosphido and Amido Complexes Gives Phosphinidene and Imide Ligands

(2010) Vlad M. Iluc et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cp* Iridium Complexes Give Catalytic Alkane Hydroxylation with Retention of Stereochemistry

(2010) Meng Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Two-Coordinate Nickel Imido Complex That Effects C−H Amination

(2010) Carl A. Laskowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer

(2010) Shunichi Fukuzumi et al.   Nature Chemistry

Palladium-Catalyzed C−H Activation/C−N Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates

(2010) Zhuofeng Ke et al.   ORGANOMETALLICS

TERMINAL NITRIDO AND IMIDO COMPLEXES OF THE LATE TRANSITION METALS

(2009) John F. Berry   COMMENTS ON INORGANIC CHEMISTRY

Computational Study of Methane C−H Activation by First-Row Late Transition Metal LnM═E (M: Fe, Co, Ni) Complexes

(2009) Aaron W. Pierpont et al.   INORGANIC CHEMISTRY

Activation of Carbon−Hydrogen and Hydrogen−Hydrogen Bonds by Copper−Nitrenes: A Comparison of Density Functional Theory with Single- and Multireference Correlation Consistent Composite Approaches

(2009) Sammer M. Tekarli et al.   Journal of Chemical Theory and Computation

Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O2or Air

(2009) Yang-Hui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

(2009) Jonathan F. Hull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of a Co(i) [N2P2] complex with azides: evidence for a transient Co(iii) imido species

(2008) Wayne A. Chomitz et al.   CHEMICAL COMMUNICATIONS

Coinage Metal Catalyzed C−H Bond Functionalization of Hydrocarbons

(2008) M. Mar Díaz-Requejo et al.   CHEMICAL REVIEWS

Spin State, Structure, and Reactivity of Terminal Oxo and Dioxygen Complexes of the (PNP)Rh Moiety

(2008) Alexander Y. Verat et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bonding and Structure of Copper Nitrenes

(2008) Thomas R. Cundari et al.   INORGANIC CHEMISTRY

Electronic Design Criteria for O−O Bond Formation via Metal−Oxo Complexes

(2008) Theodore A. Betley et al.   INORGANIC CHEMISTRY

Catalytic Tuning of a Phosphinoethane Ligand for Enhanced C−H Activation

(2008) Thomas R. Cundari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

η2-Organoazide Complexes of Nickel and Their Conversion to Terminal Imido ComplexesviaDinitrogen Extrusion

(2008) Rory Waterman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural and Spectroscopic Characterization of an Electrophilic Iron Nitrido Complex

(2008) Jeremiah J. Scepaniak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Metallonitrene/Alkyne Metathesis: A Powerful Cascade Process for the Synthesis of Nitrogen-Containing Molecules

(2008) Aaron R. Thornton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity

(2008) Elena Poverenov et al.   NATURE

Electronic structure and spectroscopy of “superoxidized” iron centers in model systems: theoretical and experimental trends

(2008) John F. Berry et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

[(tBu2PCH2SiMe2)2N]RhI? Rapidly Reversible H−C(sp3) and H−C(sp2) Bond Cleavage by Rhodium(I)

(2007) Alexander Y. Verat et al.   ORGANOMETALLICS