期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 31, 页码 3730-3732出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30716b
关键词
-
资金
- Cluster of Excellence Unifying Concepts in Catalysis, Berlin [EXC 314/1]
Ni(III)-intermediates are trapped by EPR and UV/Vis spectroscopy in the reaction of a Ni(II) salt with mCPBA. On the basis of their oxo-transfer and hydrogen-atom abstraction abilities the intermediates are assigned as the elusive terminal Ni(III)-oxo/hydroxo species. The findings suggest that Ni(III)-O(H) moieties are viable reactants in oxidation catalysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据