Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

Oxidative Cleavage of the CarbonCarbon σ-Bond Using Reusable Copper on Iron

(2011) Ren-Jie Song et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Oxidative CO Coupling by Direct CH Bond Activation of Formamides: Synthesis of Enol Carbamates and 2-Carbonyl-Substituted Phenol Carbamates

(2011) G. Sathish Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Implanting Nitrogen into Hydrocarbon Molecules through CH and CC Bond Cleavages: A Direct Approach to Tetrazoles

(2011) Feng Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intramolecular Oxidative 6-exo-trig Cyclization of 1,6-Enynes with H2O and O2

(2011) Zhi-Qiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Isoquinolines from α-Aryl Vinyl Azides and Internal Alkynes by Rh-Cu Bimetallic Cooperation

(2011) Yi-Feng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Activation of a C sp 3H Bond Adjacent to a Nitrogen Atom: A Versatile Approach to Optically Active α-Alkyl α-Amino Acids and C1-Alkylated Tetrahydroisoquinoline Derivatives

(2011) Gen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Oxidative Coupling of Aryl Acetaldehydes with Anilines Leading to α-Ketoamides

(2011) Chun Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

(2011) Andrew T. Parsons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights

(2011) Alison E. Wendlandt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic and Direct Oxyphosphorylation of Alkenes with Dioxygen and H-Phosphonates Leading to β-Ketophosphonates

(2011) Wei Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed α-amination of aliphatic aldehydes

(2011) Jie-Sheng Tian et al.   CHEMICAL COMMUNICATIONS

Spin trapping of hydroxyl radicals on Cu/HY zeolites suspended in aqueous solution

(2011) Anette Häusser et al.   CHEMICAL COMMUNICATIONS

Direct, copper-catalyzed oxidation of aromatic C–H bonds with hydrogen peroxide under acid-free conditions

(2011) Ana Conde et al.   CHEMICAL COMMUNICATIONS

Copper-cascade catalysis: synthesis of 3-functionalized indoles

(2011) Jing Wang et al.   CHEMICAL COMMUNICATIONS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Copper-Catalyzed Oxidative Cross-Coupling ofN,N-Dimethylanilines with Heteroarenes under Molecular Oxygen

(2011) Lehao Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Azaheterocycles from Aryl KetoneO-Acetyl Oximes and Internal Alkynes by Cu–Rh Bimetallic Relay Catalysts

(2011) Pei Chui Too et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Amidation of 2-Phenylpyridine with Oxygen as the Terminal Oxidant

(2011) Alex John et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Functionalization of (Un)protected Tetrahydroisoquinoline and Isochroman under Iron and Copper Catalysis: Two Metals, Two Mechanisms

(2011) Michael Ghobrial et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Studies on a Cu-Catalyzed Aerobic Oxidative Coupling Reaction withN-Phenyl Tetrahydroisoquinoline: Structure of Intermediates and the Role of Methanol As a Solvent

(2011) Esther Boess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond Activation

(2011) Jun Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Oxidative C−N Bond Formation for the Synthesis of Carbazoles: Comparison of Reactivity between the Copper-Catalyzed and Metal-Free Conditions

(2011) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation

(2011) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Aerobic Synthesis of 3-Azabicyclo[3.1.0]hex-2-enes and 4-Carbonylpyrroles fromN-Allyl/Propargyl Enamine Carboxylates

(2011) Kah Kah Toh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis ofH-Pyrazolo[5,1-a]isoquinolines via Copper(II)-Catalyzed Oxidation of an Aliphatic C−H Bond of Tertiary Amine in Air

(2011) Shaoyu Li et al.   ORGANIC LETTERS

Copper-Catalyzed Benzylic C−H Oxygenation under an Oxygen Atmosphere viaN-H Imines as an Intramolecular Directing Group

(2011) Line Zhang et al.   ORGANIC LETTERS

Selective Synthesis of Unsymmetrical Peroxides: Transition-Metal-Catalyzed Oxidation of Malononitrile and Cyanoacetic Ester Derivatives by tert-Butyl Hydroperoxide at the α-Position

(2011) Alexander Terent’ev et al.   SYNTHESIS-STUTTGART

Copper-catalyzed direct oxidative synthesis of α-ketoamides from aryl methyl ketones, amines, and molecular oxygen

(2011) Feng-Tian Du et al.   Chemical Science

A general approach to the enantioselective α-oxidation of aldehydesvia synergistic catalysis

(2011) Scott P. Simonovich et al.   Chemical Science

Copper-Catalyzed Intermolecular Amination of Acidic Aryl CH Bonds with Primary Aromatic Amines

(2010) Huaiqing Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxaziridine-Mediated Oxyamination of Indoles: An Approach to 3-Aminoindoles and Enantiomerically Enriched 3-Aminopyrroloindolines

(2010) Tamas Benkovics et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Rearrangement of Tertiary Amines through Oxidation of Aliphatic CH Bonds in Air or Oxygen: Direct Synthesis of α-Amino Acetals

(2010) Jie-Sheng Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Oxidative Cross-Coupling Reaction of 3-Indolylmethyl CH Bonds with 1,3-Dicarbonyls Using a Chiral Lewis Acid-Bonded Nucleophile to Control Stereochemistry

(2010) Chang Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

O2 Activation and Selective Phenolate ortho Hydroxylation by an Unsymmetric Dicopper μ-η1:η1-Peroxido Complex

(2010) Isaac Garcia-Bosch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Oxidative Dehydrogenative Coupling of Anilines Leading to Aromatic Azo Compounds using Dioxygen as an Oxidant

(2010) Chun Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu(ii) catalyzed oxidation-[3+2] cycloaddition-aromatization cascade: Efficient synthesis of pyrrolo [2, 1-a] isoquinolines

(2010) Chenguang Yu et al.   CHEMICAL COMMUNICATIONS

Cu (I)-Catalyzed Synthesis of Polysubstituted Pyrroles from Dialkyl Ethylenedicarboxylates and β-Enamino Ketones or Esters in the Presence of O2

(2010) Ru-Long Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Thiolation of the Di- or Trimethoxybenzene Arene C−H Bond with Disulfides

(2010) Shouhui Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Amination of Primary Benzylic C−H Bonds with Primary and Secondary Sulfonamides

(2010) David A. Powell et al.   JOURNAL OF ORGANIC CHEMISTRY

A Direct Intramolecular C−H Amination Reaction Cocatalyzed by Copper(II) and Iron(III) as Part of an Efficient Route for the Synthesis of Pyrido[1,2-a]benzimidazoles fromN-Aryl-2-aminopyridines

(2010) Honggen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions

(2010) Gavin O. Jones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Synthesis of Azaspirocyclohexadienones from α-Azido-N-arylamides under an Oxygen Atmosphere

(2010) Shunsuke Chiba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

First C−H Activation Route to Oxindoles using Copper Catalysis

(2010) Johannes E. M. N. Klein et al.   ORGANIC LETTERS

Copper-Catalyzed Synthesis of α-Amino Imides from Tertiary Amines: Ugi-Type Three-Component Assemblies Involving Direct Functionalization of sp3C−Hs Adjacent to Nitrogen Atoms

(2010) Xin Ye et al.   ORGANIC LETTERS

Copper-Catalyzed Cross Dehydrogenative Coupling Reactions of Tertiary Amines with Ketones or Indoles

(2010) Fei Yang et al.   ORGANIC LETTERS

Generation of Iminyl Copper Species from α-Azido Carbonyl Compounds and Their Catalytic C−C Bond Cleavage under an Oxygen Atmosphere

(2010) Shunsuke Chiba et al.   ORGANIC LETTERS

Copper-Catalyzed Remote sp3C−H Chlorination of Alkyl Hydroperoxides

(2010) Rituparna Kundu et al.   ORGANIC LETTERS

Direct Transformation of Methyl Arenes to Aryl Nitriles at Room Temperature

(2009) Wang Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxindole Synthesis by Direct Coupling of C sp 2H and C sp 3H Centers

(2009) Yi-Xia Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

(2009) Florian Monnier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective iridium-catalyzed carbonyl allylation from the alcohol oxidation level via transfer hydrogenation: minimizing pre-activation for synthetic efficiency

(2009) Soo Bong Han et al.   CHEMICAL COMMUNICATIONS

Regioselective copper-catalyzed chlorination and bromination of arenes with O2 as the oxidant

(2009) Lujuan Yang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed aerobic phosphonation of sp3 C–H bonds

(2009) Olivier Baslé et al.   CHEMICAL COMMUNICATIONS

Anionic Halocuprate(II) Complexes as Catalysts for the Oxaziridine-Mediated Aminohydroxylation of Olefins

(2009) Tamas Benkovics et al.   JOURNAL OF ORGANIC CHEMISTRY

Aliphatic C−H Bond Oxidation of Toluene Using Copper Peroxo Complexes That Are Stable at Room Temperature

(2009) Christian Würtele et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toluene and Ethylbenzene Aliphatic C−H Bond Oxidations Initiated by a Dicopper(II)-μ-1,2-Peroxo Complex

(2009) Heather R. Lucas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dioxygen Activation under Ambient Conditions: Cu-Catalyzed Oxidative Amidation−Diketonization of Terminal Alkynes Leading to α-Ketoamides

(2009) Chun Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CuBr-Mediated Oxyalkylation of Vinylarenes under Aerobic Conditions via Cleavage of sp3C−H Bonds α to Oxygen

(2009) Kai Cheng et al.   ORGANIC LETTERS

Copper/Amino Acid Catalyzed Cross-Couplings of Aryl and Vinyl Halides with Nucleophiles†

(2008) Dawei Ma et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Oxidative Coupling of Benzylic C−H Bonds with 1,3-Dicarbonyl Compounds

(2008) Nadine Borduas et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Coupling of Tertiary Aliphatic Amines with Terminal Alkynes to Propargylamines via C−H Activation

(2008) Mingyu Niu et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Study of Asymmetric Oxidative Biaryl Coupling: Evidence for Self-Processing of the Copper Catalyst to Achieve Control of Oxidase vs Oxygenase Activity

(2008) J. Brian Hewgley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cu(I)-Catalyzed C−H α-Amination of Esters. Direct Synthesis of Hydantoins

(2008) Baoguo Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper Catalyzed Enantioselective Intramolecular Aminooxygenation of Alkenes

(2008) Peter H. Fuller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper Complexes of Anionic Nitrogen Ligands in the Amidation and Imidation of Aryl Halides

(2008) Jesse W. Tye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Oxidative sp3C−H Bond Arylation with Aryl Boronic Acids

(2008) Olivier Baslé et al.   ORGANIC LETTERS

CuCl-catalyzed aerobic oxidative reaction of primary aromatic amines

(2008) Wenchao Lu et al.   TETRAHEDRON LETTERS