Examining the relationship between coordination mode and reactivity of dinitrogen

Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes

(2016) Hiromasa Tanaka et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands

(2016) Shogo Kuriyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of Dinitrogen into Acetonitrile under Ambient Conditions

(2016) Isabel Klopsch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes

(2016) Yoshiaki Tanabe et al.   CHEMICAL RECORD

Insights into small molecule activation by multinuclear first-row transition metal cyclophanates

(2016) David M. Ermert et al.   DALTON TRANSACTIONS

Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes

(2016) Laurence R. Doyle et al.   DALTON TRANSACTIONS

Terpyridine Molybdenum Dinitrogen Chemistry: Synthesis of Dinitrogen Complexes That Vary by Five Oxidation States

(2016) Máté J. Bezdek et al.   INORGANIC CHEMISTRY

Steric Switching from Photochemical to Thermal Reaction Pathways for Enhanced Efficiency in Metal-Mediated Nitrogen Fixation

(2016) Leila M. Duman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Catalytic Reduction of N2 to N2H4 by a Simple Fe Complex

(2016) Peter J. Hill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Model Calculations Suggest that the Central Carbon in the FeMo-Cofactor of Nitrogenase Becomes Protonated in the Process of Nitrogen Fixation

(2016) Per E. M. Siegbahn   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench 57Fe Mössbauer Data, and a Hydride Resting State

(2016) Trevor J. Del Castillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Fe-N2 Complex That Generates Hydrazine and Ammonia via Fe═NNH2: Demonstrating a Hybrid Distal-to-Alternating Pathway for N2 Reduction

(2016) Jonathan Rittle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Propargyl Alcohols by TpRu Complexes Bearing a Bidentate NHC Ligand

(2016) Manuel Jiménez-Tenorio et al.   ORGANOMETALLICS

Synthesis and Characterization of Pincer-Molybdenum Precatalysts for CO2 Hydrogenation

(2016) Yuanyuan Zhang et al.   ORGANOMETALLICS

Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand

(2016) Shogo Kuriyama et al.   Nature Communications

Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes

(2015) Sean F. McWilliams et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal-Mediated Production of Isocyanates, R3ENCO from Dinitrogen, Carbon Dioxide, and R3ECl

(2015) Andrew J. Keane et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Transformation of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions

(2015) Ryuji Imayoshi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molybdenum-catalyzed reduction of molecular dinitrogen into ammonia under ambient reaction conditions

(2015) Yoshiaki Nishibayashi   COMPTES RENDUS CHIMIE

Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers

(2015) Nitesh Khoenkhoen et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions

(2015) Yoshiaki Nishibayashi   INORGANIC CHEMISTRY

Bimetallic Cobalt–Dinitrogen Complexes: Impact of the Supporting Metal on N2 Activation

(2015) Laura J. Clouston et al.   INORGANIC CHEMISTRY

Catalytic Silylation of Dinitrogen with a Dicobalt Complex

(2015) Randall B. Siedschlag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum–Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts

(2015) Kazuya Arashiba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site

(2015) Shogo Kuriyama et al.   Chemical Science

N2 Reduction into Silylamine at Tridentate Phosphine/Mo Center: Catalysis and Mechanistic Study

(2015) Qian Liao et al.   ACS Catalysis

Synthesis and Ligand Modification Chemistry of a Molybdenum Dinitrogen Complex: Redox and Chemical Activity of a Bis(imino)pyridine Ligand

(2014) Grant W. Margulieux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Nitrogenase FeMo cofactor: an atomic structure in three simple steps

(2014) Oliver Einsle   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Fine-Tuning the Energy Barrier for Metal-Mediated Dinitrogen N≡N Bond Cleavage

(2014) Andrew J. Keane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of a (Dinitrogen)Tricopper(I) Complex

(2014) Leslie J. Murray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium

(2014) Isabel Klopsch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N–H and N–C Bond Formation with an N2-Derived Dihafnium μ-Nitrido Complex

(2014) Scott P. Semproni et al.   ORGANOMETALLICS

New Approaches to Functionalizing Metal-Coordinated N2

(2013) José G. Andino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Induced N2Hapticity Switching in Zirconocene Dinitrogen Complexes

(2013) Scott P. Semproni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of Dinitrogen-Derived Hafnium Nitrides for Nucleophilic NC Bond Formation with a Terminal Isocyanate

(2013) Scott P. Semproni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N2 coordination

(2013) Michael D. Fryzuk   CHEMICAL COMMUNICATIONS

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

Dinitrogen Borylation with Group 4 Metallocene Complexes

(2013) Scott P. Semproni et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of a Base-Free Hafnium Nitride from N2 Cleavage: A Versatile Platform for Dinitrogen Functionalization

(2013) Scott P. Semproni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex

(2013) T. Shima et al.   SCIENCE

Structure and Reactivity of a Hafnocene μ-Nitrido Prepared From Dinitrogen Cleavage

(2012) Scott P. Semproni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation

(2012) Travis M. Figg et al.   INORGANIC CHEMISTRY

Studies into the Mechanism of CO-Induced N2 Cleavage Promoted by an Ansa-Hafnocene Complex and C–C Bond Formation from an Observed Intermediate

(2012) Donald J. Knobloch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Di- and Tetrametallic Hafnocene Oxamidides Prepared from CO-Induced N2 Bond Cleavage and Thermal Rearrangement to Hafnocene Cyanide Derivatives

(2012) Scott P. Semproni et al.   ORGANOMETALLICS

Side-on Dinitrogen Complexes of Titanocenes with Disubstituted Cyclopentadienyl Ligands: Synthesis, Structure, and Spectroscopic Characterization

(2012) Scott P. Semproni et al.   ORGANOMETALLICS

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

(2012) Masahiro Yuki et al.   Nature Communications

Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

(2011) Marc-Etienne Moret et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cleavage of dinitrogen to yield a (t-BuPOCOP)molybdenum(iv) nitride

(2011) Travis J. Hebden et al.   CHEMICAL COMMUNICATIONS

N2Functionalization at Iron Metallaboratranes

(2011) Marc-Etienne Moret et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Silylation and Cleavage with a Hafnocene Complex

(2011) Scott P. Semproni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

(2011) Hiromasa Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex

(2011) M. M. Rodriguez et al.   SCIENCE

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

Carbon-Nitrogen Bond Formation by the Reaction of 1,2-Cumulenes with a Ditantalum Complex Containing Side-On- and End-On-Bound Dinitrogen

(2010) Joachim Ballmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The hydride route to the preparation of dinitrogen complexes

(2010) Joachim Ballmann et al.   CHEMICAL COMMUNICATIONS

Protonation of the Dinitrogen-Reduction Catalyst [HIPTN3N]MoIIIInvestigated by ENDOR Spectroscopy

(2010) R. Adam Kinney et al.   INORGANIC CHEMISTRY

Dinitrogen Complexation and Extent of N≡N Activation within the Group 6 “End-On-Bridged” Dinuclear Complexes, {(η5-C5Me5)M[N(i-Pr)C(Me)N(i-Pr)]}2(μ-η1:η1-N2) (M = Mo and W)

(2010) Philip P. Fontaine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Theoretical EPR Study of Jahn−Teller-Active [HIPTN3N]MoL Complexes (L = N2, CO, NH3)

(2010) Rebecca L. McNaughton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon Monoxide-Induced Dinitrogen Cleavage with Group 4 Metallocenes: Reaction Scope and Coupling to N−H Bond Formation and CO Deoxygenation

(2010) Donald J. Knobloch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

Addition of Methyl Triflate to a Hafnocene Dinitrogen Complex: Stepwise N2Methylation and Conversion to a Hafnocene Hydrazonato Compound

(2009) Donald J. Knobloch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex

(2009) Donald J. Knobloch et al.   Nature Chemistry

1,4-Addition of Alkyl Halides to a Side-on Bound Hafnocene Dinitrogen Complex

(2009) David Benito-Garagorri et al.   ORGANOMETALLICS

Dinitrogen Complexes of Bis(cyclopentadienyl) Titanium Derivatives: Structural Diversity Arising from Substituent Manipulation

(2009) Tamara E. Hanna et al.   ORGANOMETALLICS

Side-on End-on Bound Dinitrogen: An Activated Bonding Mode That Facilitates Functionalizing Molecular Nitrogen

(2008) Michael D. Fryzuk   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment

(2008) Richard R. Schrock   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First-Principles Investigation of the Schrock Mechanism of Dinitrogen Reduction Employing the Full HIPTN3N Ligand

(2008) Stephan Schenk et al.   INORGANIC CHEMISTRY

Indenyl Zirconium Dinitrogen Chemistry: N2Coordination to an Isolated Zirconium Sandwich and Synthesis of Side-on, End-on Dinitrogen Compounds

(2008) Doris Pun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylation of anansa-Zirconocene Dinitrogen Complex:  Regiospecific Hydrazine Synthesis from N2and CO2

(2008) Donald J. Knobloch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N2Hydrogenation from Activated End-On Bis(indenyl) Zirconium Dinitrogen Complexes

(2008) Doris Pun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY