Recent Advances in Direct Catalytic Asymmetric Transformations under Proton-Transfer Conditions

Catalytic Asymmetric Amination of N-Nonsubstituted α-Alkoxycarbonyl Amides: Concise Enantioselective Synthesis of Mycestericin F and G

(2011) Farouk Berhal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bifunctional Asymmetric Catalysis Based on Dinuclear Schiff Base Complexes

(2011) Masakatsu Shibasaki et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

A New Class of Urea-Substituted Cinchona Alkaloids Promote Highly Enantioselective Nitroaldol reactions of Trifluoromethylketones

(2011) Carole Palacio et al.   ORGANIC LETTERS

Catalytic Asymmetric Direct Henry Reaction of Ynals: Short Syntheses of (2S,3R)-(+)-Xestoaminol C and (−)-Codonopsinines

(2010) Daisuke Uraguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The direct catalytic asymmetric aldol reaction

(2010) Barry M. Trost et al.   CHEMICAL SOCIETY REVIEWS

Solvent-Dependent Self-Discrimination of Bis(2-hydroxyphenyl)diamides

(2010) Akinobu Matsuzawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Synthesis of 3-Amino-2-oxindole Derivatives: Catalytic Asymmetric α-Amination of 3-Substituted 2-Oxindoles with a Chiral Scandium Complex

(2010) Zhigang Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Henry Reaction Catalyzed by CuIISalt and Bipiperidine

(2010) Artur Noole et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Asymmetric Aldol Reaction of 5H-Oxazol-4-ones with Aldehydes Catalyzed by Chiral Guanidines

(2010) Tomonori Misaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones via Soft Lewis Acid/Hard Brønsted Base/Hard Lewis Base Catalysis

(2010) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Silicon-Mediated Carbon−Carbon Bond-Forming Reactions of Unactivated Amides

(2010) Shu̅ Kobayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Concise Enantioselective Synthesis of (−)-Ranirestat

(2010) Barry M. Trost et al.   ORGANIC LETTERS

Enantioselective α-Amination of 1,3-Dicarbonyl Compounds Using Squaramide Derivatives as Hydrogen Bonding Catalysts

(2010) Hideyuki Konishi et al.   ORGANIC LETTERS

Enantioselective Henry Addition of Methyl 4-Nitrobutyrate to Aldehydes. Chiral Building Blocks for 2-Pyrrolidinones and Other Derivatives

(2010) Gonzalo Blay et al.   ORGANIC LETTERS

Catalytic Asymmetric Conjugate Addition of α-Cyanoketones for the Construction of a Quaternary Stereogenic Center

(2010) Yuji Kawato et al.   ORGANIC LETTERS

Direct catalytic asymmetric aldol reaction of thioamides: a concise asymmetric synthesis of (R)-fluoxetine

(2010) Mitsutaka Iwata et al.   TETRAHEDRON-ASYMMETRY

The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups

(2009) Barry M. Trost et al.   ADVANCED SYNTHESIS & CATALYSIS

1,n-Glycols as Dialdehyde Equivalents in Iridium-Catalyzed Enantioselective Carbonyl Allylation and Iterative Two-Directional Assembly of 1,3-Polyols

(2009) Yu Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Asymmetric Mannich-Type Reaction of Thioamides

(2009) Yuta Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Henry (nitroaldol) reaction catalyzed by axially chiral guanidines

(2009) Hitoshi Ube et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Bifunctional transition metal-based molecular catalysts for asymmetric CC and CN bond formation

(2009) Takao Ikariya et al.   CHEMICAL RECORD

Catalytic Enantioselective Aldol Additions to Ketones

(2009) Shinya Adachi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Dieckmann Condensation via Memory of Chirality: Synthesis of the Key Intermediate for AS-3201, an Aldose Reductase Inhibitor

(2009) Takeo Kawabata et al.   HETEROCYCLES

Catalytic Asymmetric Synthesis of α-Alkylidene-β-hydroxy Esters via Dynamic Kinetic Asymmetric Transformation Involving Ba-Catalyzed Direct Aldol Reaction

(2009) Akitake Yamaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Aldol Reactions of Thioamides: Toward a Stereocontrolled Synthesis of 1,3-Polyols

(2009) Mitsutaka Iwata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones

(2009) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Linking Structural Dynamics and Functional Diversity in Asymmetric Catalysis

(2009) Akihiro Nojiri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Managing Highly Coordinative Substrates in Asymmetric Catalysis: A Catalytic Asymmetric Amination with a Lanthanum-Based Ternary Catalyst

(2009) Tomoyuki Mashiko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

anti-Selective Catalytic Asymmetric Nitroaldol Reaction via a Heterobimetallic Heterogeneous Catalyst

(2009) Tatsuya Nitabaru et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Elongation of 1,3-Polyols via Iterative Catalyst-Directed Carbonyl Allylation from the Alcohol Oxidation Level

(2009) Abbas Hassan et al.   ORGANIC LETTERS

Highly Enantioselective and Organocatalytic α-Amination of 2-Oxindoles

(2009) Liang Cheng et al.   ORGANIC LETTERS

Brucine-Derived Amino Alcohol Catalyzed Asymmetric Henry Reaction: An Orthogonal Enantioselectivity Approach

(2009) Hun Young Kim et al.   ORGANIC LETTERS

Organocatalytic Formation of Quaternary Stereocenters

(2009) Marco Bella et al.   SYNTHESIS-STUTTGART

Highly efficient asymmetric amination of β-keto esters catalyzed by chiral quaternary ammonium bromides

(2009) Quan Lan et al.   TETRAHEDRON LETTERS

Recent progress on the stereoselective synthesis of cyclic quaternary α-amino acids

(2009) Carlos Cativiela et al.   TETRAHEDRON-ASYMMETRY

Bifunctional Asymmetric Catalysis: Cooperative Lewis Acid/Base Systems

(2008) Daniel H. Paull et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery

(2008) Young Jun Park et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

(2008) John F. Bower et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Binaphthyl-Modified Quaternary Phosphonium Salts as Chiral Phase-Transfer Catalysts: Asymmetric Amination of β-Keto Esters

(2008) Rongjun He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Heterobimetallic Pd/La/Schiff Base Complex foranti-Selective Catalytic Asymmetric Nitroaldol Reactions and Applications to Short Syntheses of β-Adrenoceptor Agonists

(2008) Shinya Handa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Catalysis in Organic Synthesis

(2008) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure-activity relationship study and NMR analysis of fluorobenzoyl pentapeptide GPR54 agonists

(2008) Kenji Tomita et al.   BIOPOLYMERS

Multimetallic Bifunctional Asymmetric Catalysis Based on Proximity Effect Control

(2008) Shigeki Matsunaga et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

RhI-catalyzed aldol-type reaction of organonitriles under mild conditions

(2008) Akihiro Goto et al.   CHEMICAL COMMUNICATIONS

Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines

(2008) Masakatsu Shibasaki et al.   CHEMICAL REVIEWS

Aqua-aminoorganoboron Catalyst: Engineering Single Water Molecule to Act as an Acid Catalyst in Nitro Aldol Reaction

(2008) Junichi Yoshimoto et al.   CHEMISTRY LETTERS

New Highly Asymmetric Henry Reaction Catalyzed by CuII and aC1-Symmetric Aminopyridine Ligand, and Its Application to the Synthesis of Miconazole

(2008) Gonzalo Blay et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbon–Nitrogen Bond-Forming Reactions of Dialkyl Azodicarboxylate: A Promising Synthetic Strategy

(2008) Vijay Nair et al.   Chemistry-An Asian Journal

Enantioselective α-hydrazination of α-fluoro-β-ketoesters catalyzed by chiral nickel complexes

(2008) Joo Yang Mang et al.   JOURNAL OF FLUORINE CHEMISTRY

AsymmetricSyn-Selective Henry Reaction Catalyzed by the Sulfonyldiamine−CuCl−Pyridine System

(2008) Takayoshi Arai et al.   JOURNAL OF ORGANIC CHEMISTRY

Ranirestat (AS-3201), a Potent Aldose Reductase Inhibitor, Reduces Sorbitol Levels and Improves Motor Nerve Conduction Velocity in Streptozotocin-Diabetic Rats

(2008) Takafumi Matsumoto et al.   JOURNAL OF PHARMACOLOGICAL SCIENCES

Enantioselective Direct Amination of α-Cyanoacetates Catalyzed by Bifunctional Chiral Ru and Ir Amido Complexes

(2008) Yasuharu Hasegawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Diels−Alder Reactions of Danishefsky Type Dienes with Electron-Deficient Alkenes Catalyzed by Yb(III)-BINAMIDE Complexes

(2008) Yukinori Sudo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Addition of Allylic Cyanides to Ketoimines

(2008) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalysis via Dynamic Substrate/Ligand/Rare Earth Metal Conglomerate

(2008) Akihiro Nojiri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols

(2008) Jake L. Stymiest et al.   NATURE

Iterative Cr-Mediated Catalytic Asymmetric Allylation To Synthesizesyn/syn- andanti/anti-1,3,5-Triols

(2008) Zhiyu Zhang et al.   ORGANIC LETTERS

Organocatalytic Mannich-Type Reactions of Trifluoroethyl Thioesters

(2008) Naoto Utsumi et al.   ORGANIC LETTERS

Palladium−Pincer Complex Catalyzed C−C Coupling of Allyl Nitriles with Tosyl Imines via Regioselective Allylic C−H Bond Functionalization

(2008) Juhanes Aydin et al.   ORGANIC LETTERS

An Improved Lanthanum Catalyst System for Asymmetric Amination: Toward a Practical Asymmetric Synthesis of AS-3201 (Ranirestat)

(2008) Tomoyuki Mashiko et al.   ORGANIC LETTERS

Highly Enantioselective Aza-Henry Reaction of Ketoimines Catalyzed by ChiralN,N′-Dioxide−Copper(I) Complexes

(2008) Cheng Tan et al.   ORGANIC LETTERS

Catalytic enantioselective electrophilic α-hydrazination of β-ketoesters using bifunctional organocatalysts

(2008) Sun Hee Jung et al.   TETRAHEDRON LETTERS

Cooperative Catalysis: A New Development in Heterogeneous Catalysis

(2008) Jeong-Kyu Lee et al.   TOPICS IN CATALYSIS

Organocatalysed asymmetric Mannich reactions

(2007) Jorge M. M. Verkade et al.   CHEMICAL SOCIETY REVIEWS

A catalytic asymmetric anti-selective nitroaldol reaction with a neodymium–sodium heterobimetallic complex

(2007) Tatsuya Nitabaru et al.   TETRAHEDRON LETTERS