Copper-Catalyzed Borylative Cross-Coupling of Allenes and Imines: Selective Three-Component Assembly of Branched Homoallyl Amines

Hydroaminomethylation Beyond Carbonylation: Allene-Imine Reductive Coupling by Ruthenium-Catalyzed Transfer Hydrogenation

(2015) Susumu Oda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β-Hydride Elimination

(2015) Brannon Sam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide

(2015) H. Yoshida et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed Silylative Allylation of Ketones and Aldehydes Employing Allenes and Silylboranes

(2015) Yosuke Tani et al.   CHEMISTRY LETTERS

Enantioselective Ruthenium-Catalyzed Carbonyl Allylation via Alkyne–Alcohol C–C Bond-Forming Transfer Hydrogenation: Allene Hydrometalation vs Oxidative Coupling

(2015) Tao Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Silylation of Alkynes: A Traceless 2-Pyridylsulfonyl Controller Allows Access to Either Regioisomer on Demand

(2015) Alfonso García-Rubia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity

(2015) Yi-Shuang Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

The Isomerization of Allylrhodium Intermediates in the Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines

(2014) Hamish B. Hepburn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Borylative Allyl-Allyl Coupling Reaction

(2014) Kazuhiko Semba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Cross-Coupling of Boronic Esters with Aryl Iodides and Application to the Carboboration of Alkynes and Allenes

(2014) Yiqing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereoselective and Enantiospecific Allylation of Ketones and Imines Using Borinic Esters: Contiguous Quaternary Stereogenic Centers

(2014) Jack L.-Y. Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of multi-substituted vinylsilanes via copper(i)-catalyzed hydrosilylation reactions of allenes and propiolate derivatives with silylboronates

(2014) Yun-He Xu et al.   CHEMICAL COMMUNICATIONS

Cu(I)-NHC-Catalyzed Silylation of Allenes: Diastereoselective Three-Component Coupling with Aldehydes

(2014) James Rae et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regulation of Diastereoselectivity in the Carbocyclization of Allenyl (S)-N-tert-Butylsulfinimines through a Three-Component Assembly

(2014) Jihyun Kim et al.   JOURNAL OF ORGANIC CHEMISTRY

Alkynes as Allylmetal Equivalents in Redox-Triggered C–C Couplings to Primary Alcohols: (Z)-Homoallylic Alcohols via Ruthenium-Catalyzed Propargyl C–H Oxidative Addition

(2014) Boyoung Y. Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Regiodivergent Silacarboxylation of Allenes with Carbon Dioxide and a Silylborane

(2014) Yosuke Tani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional organoboron compounds for scalable natural product synthesis

(2014) Fanke Meng et al.   NATURE

Copper-Catalyzed Regio- and Stereoselective Intermolecular Three-Component Oxyarylation of Allenes

(2014) Taisuke Itoh et al.   ORGANIC LETTERS

Catalytic Enantioselective Protoboration of Disubstituted Allenes. Access to Alkenylboron Compounds in High Enantiomeric Purity

(2014) Hwanjong Jang et al.   ORGANIC LETTERS

Stereoselective allylboration of imines and indoles under mild conditions. An in situ E/Z isomerization of imines by allylboroxines

(2014) Rauful Alam et al.   Chemical Science

Asymmetric allylation of sulfonyl imines catalyzed by in situ generated Cu(ii) complexes of chiral amino alcohol based Schiff bases

(2014) Debashis Ghosh et al.   RSC Advances

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In situ Catalytic Generation of Allylcopper Species for Asymmetric Allylation: Toward 1H-Isochromene Skeletons

(2013) Junya Kawai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Allenes by the [3+2] Annulation of Aryl Ketimines

(2013) Duc N. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amide-Controlled Highly Selective Catalytic Borylcupration of Allenes

(2013) Weiming Yuan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium Catalyzed Reductive Coupling of Paraformaldehyde to Trifluoromethyl Allenes: CF3-Bearing All-Carbon Quaternary Centers

(2013) Brannon Sam et al.   ORGANIC LETTERS

NHC–Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism

(2013) Fanke Meng et al.   ORGANIC LETTERS

Thermodynamically Controlled, Dynamic Binding of Diols to a 1,2-BN Cyclohexane Derivative

(2013) Gregory P. Harlow et al.   ORGANOMETALLICS

Catalytic enantioselective synthesis of 2-(2-hydroxyethyl)indole scaffolds via consecutive intramolecular amido-cupration of allenes and asymmetric addition of carbonyl compounds

(2013) Prasanna Kumara Chikkade et al.   Chemical Science

Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron

(2012) Weiming Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Diastereocontrol in the Synthesis of 2,3,4-Trisubstituted Pyrrolidines and Tetrahydrofurans via a Palladium(II)-Catalyzed Three-Component Coupling Reaction

(2012) Helena Malinakova et al.   SYNTHESIS-STUTTGART

Selective 1:2 Coupling of Aldehydes and Allenes with Control of Regiochemistry

(2011) Takeharu Toyoshima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines

(2011) Miguel Yus et al.   CHEMICAL REVIEWS

Enantioselective Synthesis of Homoallylic Amines through Reactions of (Pinacolato)allylborons with Aryl-, Heteroaryl-, Alkyl-, or Alkene-Substituted Aldimines Catalyzed by ChiralC1-Symmetric NHC−Cu Complexes

(2011) Erika M. Vieira et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalysed direct C–C coupling of methanol and allenes

(2011) Joseph Moran et al.   Nature Chemistry

syn-Selective Rhodium(I)-Catalyzed Allylations of Ketimines Proceeding through a Directed CH Activation/Allene Addition Sequence

(2010) Duc N. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron

(2010) Steven B. Thorpe et al.   CHEMICAL COMMUNICATIONS

Preparation of Stereodefined Homoallylic Amines from the Reductive Cross-Coupling of Allylic Alcohols with Imines

(2010) Ming Z. Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Arylzincation of Terminal Allenes Providing Allylzinc Reagents and Its Application to Versatile Three-component Coupling Reaction

(2010) Yuji Yoshida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allenamide Hydro−Hydroxyalkylation: 1,2-Amino Alcohols via Ruthenium-Catalyzed Carbonylanti-Aminoallylation

(2010) Jason R. Zbieg et al.   ORGANIC LETTERS

Rhenium-Catalyzed Diastereoselective Synthesis of Aminoindanes via the Insertion of Allenes into a C−H Bond

(2010) Yoichiro Kuninobu et al.   ORGANIC LETTERS

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

anti-Aminoallylation of Aldehydes via Ruthenium-Catalyzed Transfer Hydrogenative Coupling of Sulfonamido Allenes: 1,2-Aminoalcohols

(2009) Eduardas Skucas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Carbonyl Reverse Prenylation from the Alcohol or Aldehyde Oxidation Level Employing 1,1-Dimethylallene as the Prenyl Donor

(2009) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Palladium Complex Catalyzed Diastereo- and Enantioselective Tandem Annulation of 2-Formylarylboronic Acids with Allenoates

(2009) Xufen Yu et al.   ORGANIC LETTERS

Transition metal-catalyzed three-component coupling of allenes and the related allylation reactions

(2008) Masilamani Jeganmohan et al.   CHEMICAL COMMUNICATIONS

Enantioselective Arylative Cyclization of Allenyl Aldehydes with Arylboronic Acids under Pd(II)-diphosphine Catalysis

(2008) Hirokazu Tsukamoto et al.   ORGANIC LETTERS

Ruthenium Catalyzed C−C Bond Formation via Transfer Hydrogenation: Branch-Selective Reductive Coupling of Allenes to Paraformaldehyde and Higher Aldehydes

(2008) Ming-Yu Ngai et al.   ORGANIC LETTERS

Stereoselective synthesis of chiral β2,3-disubstituted-β-amino acid derivatives using Pd/In transmetallation cascade processes

(2008) Ronald Grigg et al.   TETRAHEDRON