Synthesis of Azepine Derivatives by Rhodium-Catalyzed Tandem 2,3-Rearrangement/Heterocyclization

Preparation of 2-Azarhodacyclobutanes by Rhodium(I)-Olefin Oxidation

(2012) Alexander Dauth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chromium(0)-Catalyzed Tandem Cyclization of α,β-Unsaturated Thioimidates Containing an Enyne Moiety

(2012) Yusuke Karibe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne

(2012) Suyu Huang et al.   CHEMICAL COMMUNICATIONS

Cationic Rhodium(I)-Catalyzed Regioselective Tandem Heterocyclization/[3+2] Cycloaddition of 2-(1-Alkynyl)-2-alken-1-ones with Alkynes

(2012) Hongyin Gao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Azepine Synthesis from Alkyl Azide and Propargylic Ester via Gold Catalysis

(2012) Heng Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Carbonylation of 3-Acyloxy-1,4-enynes for the Synthesis of Cyclopentenones

(2012) Xiaoxun Li et al.   ORGANIC LETTERS

Copper-Catalyzed Skeletal Rearrangement of O-Propargylic Aryloximes into Four-Membered Cyclic Nitrones - Chirality Transfer and Mechanistic Insight

(2012) Itaru Nakamura et al.   SYNTHESIS-STUTTGART

Rhodium-Catalyzed Ring Expansion of Cyclopropanes to Seven-membered Rings by 1,5 CC Bond Migration

(2011) Xiaoxun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Tandem [2,3]-Rearrangement and 6π-3-Azatriene Electrocyclization in (E)-O-Propargylic α,β-Unsaturated Oximes

(2011) Itaru Nakamura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Transformation ofO-Propargylic Arylaldoximes to Four-Membered Cyclic Nitrones by Copper-Catalyzed Skeletal Rearrangement

(2011) Itaru Nakamura et al.   ORGANIC LETTERS

Thermally-induced skeletal rearrangement of (Z)-O-propargylic α,β-unsaturated aldoximes to multisubstituted pyridine oxides

(2011) Itaru Nakamura et al.   TETRAHEDRON LETTERS

Synthesis of Highly Functionalized Cyclohexenone Rings: Rhodium-Catalyzed 1,3-Acyloxy Migration and Subsequent [5+1] Cycloaddition

(2010) Dongxu Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Tandem [2,3]-Rearrangement and 6π-3-Azatriene Electrocyclization in (E)-O-Propargylic α,β-Unsaturated Oximes

(2010) Itaru Nakamura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

ESI-MS, DFT, and Synthetic Studies on the H2-Mediated Coupling of Acetylene: Insertion of C═X Bonds into Rhodacyclopentadienes and Brønsted Acid Cocatalyzed Hydrogenolysis of Organorhodium Intermediates

(2009) Vanessa M. Williams et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium-Catalyzed [4+2+2] Cycloaddition of Dienyl Isocyanates for the Synthesis of Bicyclic Azocine Rings

(2009) Robert T. Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Azepines by a Gold-Catalyzed Intermolecular [4 + 3]-Annulation

(2008) Nathan D. Shapiro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY