Highly Chemo- and Stereoselective Catalyst-Controlled Allylic C−H Insertion and Cyclopropanation Using Donor/Donor Carbenes

Palladium-catalyzed carbene/alkyne metathesis with enynones as carbene precursors: synthesis of fused polyheterocycles

(2018) Yang Zheng et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed Intramolecular Nucleophilic Addition of Carbonyl Groups to Alkynes

(2018) Lianfen Chen et al.   Chem

Catalytic C(sp3)–H Alkylation via an Iron Carbene Intermediate

(2017) Jennifer R. Griffin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic B–H Bond Insertion Reactions Using Alkynes as Carbene Precursors

(2017) Ji-Min Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent progress in the catalytic carbene insertion reactions into the silicon–hydrogen bond

(2017) Hoda Keipour et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Formal [3 + 1 + 1] Cycloaddition Reaction by Ru(II)/Iminium Cocatalysis for Construction of Multisubstituted Pyrrolidines

(2017) Mingfeng Li et al.   ORGANIC LETTERS

Rhodium-Catalyzed Intramolecular Cyclopropanation of α-Diazo β-Keto Nitriles Containing an Unsaturated Substituted Cycloalkyl Group

(2017) Jia-Liang Zhu et al.   SYNLETT

An efficient approach to generate aryl carbenes: gold-catalyzed sequential activation of 1,6-diynes

(2017) Tongxiang Cao et al.   Organic Chemistry Frontiers

Enantioselective Cyclopropanation of a Wide Variety of Olefins Catalyzed by Ru(II)–Pheox Complexes

(2016) Soda Chanthamath et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Intramolecular Carbene Insertion into C(sp3 )−H Bonds

(2016) Daniel Solé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New Approaches to the Synthesis of Metal Carbenes

(2016) Minqiang Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intramolecular C−H Insertion of Donor and Donor/Donor Carbenes by a Nondiazo Approach

(2016) Dong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Aminobenzoic Acid Derivatives via Chemoselective Carbene Insertion into the −NH Bond Catalyzed by Cu(I) Complex

(2016) Kankanala Ramakrishna et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(II)-Catalyzed C–H Functionalization of Electron-Deficient Methyl Groups

(2016) Liangbing Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Route to Polysubstituted Aziridines from Carbenes and Imines through a Nondiazo Approach

(2016) Hejiang Luo et al.   ORGANIC LETTERS

Dual Catalysis: Proton/Metal-Catalyzed Tandem Benzofuran Annulation/Carbene Transfer Reaction

(2016) Jun Ma et al.   ORGANIC LETTERS

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox

(2015) Deyun Qian et al.   CHEMICAL SOCIETY REVIEWS

Enynal/Enynone: A Safe and Practical Carbenoid Precursor

(2015) Jun Ma et al.   CURRENT ORGANIC CHEMISTRY

A Non-Diazo Approach to α-Oxo Gold Carbenes via Gold-Catalyzed Alkyne Oxidation

(2014) Liming Zhang   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Intramolecular C–H Insertion Reactions of Donor–Donor Metal Carbenoids

(2014) Cristian Soldi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient synthesis strategies by application of transition metal-catalyzed carbene/nitrene insertions into C–H bonds

(2014) Julian Egger et al.   NATURAL PRODUCT REPORTS

NHC–AuCl/Selectfluor: A Highly Efficient Catalytic System for Carbene-Transfer Reactions

(2014) Jun Ma et al.   ORGANIC LETTERS

Novel Multicomponent Reactions via Trapping of Protic Onium Ylides with Electrophiles

(2013) Xin Guo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Zinc-Catalyzed Synthesis of Functionalized Furans and Triarylmethanes from Enynones and Alcohols or Azoles: Dual XH Bond Activation by Zinc

(2013) Jesús González et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbene Migratory Insertion Using Conjugated Ene–Yne–Ketones as Carbene Precursors

(2013) Ying Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Generation of Zinc Carbenes from Alkynes: Zinc-Catalyzed Cyclopropanation and SiH Bond Insertion Reactions

(2012) Rubén Vicente et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh-Catalyzed Intermolecular Reactions of Cyclic α-Diazocarbonyl Compounds with Selectivity over Tertiary C–H Bond Migration

(2012) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Intramolecular Carbene Insertion into Primary C–H Bond of α-Diazoacetamides Mediated by a (p-Cymene)ruthenium(II) Carboxylate Complex

(2012) Vanessa Kar-Yan Lo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold α-Oxo Carbenoids in Catalysis: Catalytic Oxygen-Atom Transfer to Alkynes

(2011) Jian Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand Effect on Cobalt(II)-Catalyzed Asymmetric Cyclopropanation with Diazosulfones - Approaching High Stereoselectivity through Modular Design of D2-Symmetric Chiral Porphyrins

(2011) Shifa Zhu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions

(2010) Hongjian Lu et al.   CHEMICAL SOCIETY REVIEWS

Chemoselectivity: The Mother of Invention in Total Synthesis

(2009) Ryan A. Shenvi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chemoselectivity and the Curious Reactivity Preferences of Functional Groups

(2009) Nicholas A. Afagh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Domino reactions of rhodium(ii) carbenoids for alkaloid synthesis

(2009) Albert Padwa   CHEMICAL SOCIETY REVIEWS

Combined Experimental and Computational Studies of Heterobimetallic Bi−Rh Paddlewheel Carboxylates as Catalysts for Metal Carbenoid Transformations

(2009) Jo̷rn Hansen et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Reactions of Donor/Acceptor Carbenoids Derived from α-Aryl-α-Diazoketones

(2009) Justin R. Denton et al.   ORGANIC LETTERS

Intramolecular Huisgen-Type Cyclization of Platinum-Bound Pyrylium Ions with Alkenes and Subsequent Insertion into a Benzylic CH Bond

(2008) Chang Ho Oh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

(2008) Eloísa Jiménez-Núñez et al.   CHEMICAL REVIEWS

Chemoselective modification of proteins: hitting the target

(2008) Isaac S. Carrico   CHEMICAL SOCIETY REVIEWS

CH Insertion Processes on Stabilized Indolyl andortho-Aminophenyl Fischer Carbene Complexes: Synthesis of Azepino[3,2,1-hi] indole, Benzazepine and Indole Derivatives

(2008) José Barluenga et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cu(I)-Catalyzed Regioselective Synthesis of Polysubstituted Furans from Propargylic Esters via Postulated (2-Furyl)carbene Complexes

(2008) José Barluenga et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Intermolecular C–H functionalization versus cyclopropanation of electron rich 1,1-disubstituted and trisubstituted alkenes

(2008) Dominic L. Ventura et al.   TETRAHEDRON

Gold-catalyzed olefin cyclopropanation

(2008) Auxiliadora Prieto et al.   TETRAHEDRON

Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals

(2007) Chun-Hui (Clayton) Zhou et al.   CHEMICAL SOCIETY REVIEWS