Chemoselectivity and the Curious Reactivity Preferences of Functional Groups

Chemoselectivity: The Mother of Invention in Total Synthesis

(2009) Ryan A. Shenvi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Amphoteric Amino Aldehydes Reroute the Aza-Michael Reaction

(2009) Ryan Hili et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Protecting-group-free synthesis as an opportunity for invention

(2009) Ian S. Young et al.   Nature Chemistry

Copper/Ascorbic Acid Dyad as a Catalytic System for Selective Aerobic Oxidation of Amines

(2009) Jiri Srogl et al.   ORGANIC LETTERS

Chemoselective Ligation and Modification Strategies for Peptides and Proteins

(2008) Christian P. R. Hackenberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselective Peptide Cyclization by Traceless Staudinger Ligation

(2008) Rolf Kleineweischede et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Method formeta andpara Functionalization of Arenes Using TMP2Mg⋅2 LiCl

(2008) Christoph J. Rohbogner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (±)-Axinellamines A and B

(2008) Daniel P. O'Malley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concise Total Synthesis of (+)-WIN 64821 and (−)-Ditryptophenaline

(2008) Mohammad Movassaghi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

(2008) Pablo García-Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methylation of arenes via Ni-catalyzed aryl C–O/F activation

(2008) Bing-Tao Guan et al.   CHEMICAL COMMUNICATIONS

A Two-State Reactivity Rationale for Counterintuitive Axial Ligand Effects on the CH Activation Reactivity of Nonheme FeIVO Oxidants

(2008) Hajime Hirao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium- and Nickel-Catalyzed Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Protons with Organozinc Reagents

(2008) Georg Manolikakes et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Direct Arylation of Tautomerizable Heterocycles with Aryl Boronic Acids via C−OH Bond Activation Using Phosphonium Salts

(2008) Fu-An Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Syntheses of (±)-Massadine and Massadine Chloride

(2008) Shun Su et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enzyme-Like Chemoselective Acylation of Alcohols in the Presence of Amines Catalyzed by a Tetranuclear Zinc Cluster

(2008) Takashi Ohshima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Orthogonal Pd- and Cu-Based Catalyst Systems for C- and N-Arylation of Oxindoles

(2008) Ryan A. Altman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiospecific Total Synthesis of the Hapalindoles, Fischerindoles, and Welwitindolinonesviaa Redox Economic Approach

(2008) Jeremy M. Richter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Enolate Heterocoupling: Scope, Mechanism, and Application

(2008) Michael P. DeMartino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Benzylic Alkylation via Ni-Catalyzed Selective Benzylic sp3C−O Activation

(2008) Bing-Tao Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total synthesis of bryostatin 16 using atom-economical and chemoselective approaches

(2008) Barry M. Trost et al.   NATURE

Carbon–heteroatom bond formation catalysed by organometallic complexes

(2008) John F. Hartwig   NATURE

Biologically inspired oxidation catalysis

(2008) Lawrence Que et al.   NATURE

Regio- and chemoselective magnesiation of protected uracils and thiouracils using TMPMgCl·LiCl and TMP2Mg·2LiCl

(2008) Marc Mosrin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regio- and Chemoselective Multiple Functionalization of Pyrimidine Derivatives by Selective Magnesiations using TMPMgCl·LiCl

(2008) Marc Mosrin et al.   ORGANIC LETTERS

Platinum- and Gold-Catalyzed Hydrative Carbocyclization of Oxo Diynes for One-Pot Synthesis of Benzopyrones and Bicyclic Spiro Ketones

(2008) Arindam Das et al.   ORGANIC LETTERS

Negishi Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Hydrogen Atoms with Organozinc Reagents

(2008) Georg Manolikakes et al.   ORGANIC LETTERS

The Fe(PDP)-catalyzed aliphatic C–H oxidation: a slow addition protocol

(2008) Nicolaas A. Vermeulen et al.   TETRAHEDRON

Function-Oriented Synthesis, Step Economy, and Drug Design

(2007) Paul A. Wender et al.   ACCOUNTS OF CHEMICAL RESEARCH

Alkyne versus Allene Activation in Platinum- and Gold-Catalyzed Cycloisomerization of Hydroxylated 1,5-Allenynes

(2007) Riadh Zriba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chlorination/Cyclodehydration of Amino Alcohols with SOCl2:  An Old Reaction Revisited

(2007) Feng Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Chemoselective Metal-Free Reduction of Tertiary Amides

(2007) Guillaume Barbe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY