Access to P - and Axially Chiral Biaryl Phosphine Oxides by Enantioselective Cpx IrIII -Catalyzed C−H Arylations

Rhodium-Catalyzed Enantioposition-Selective Hydroarylation of Divinylphosphine Oxides with Aryl Boroxines

(2018) Zhe Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Planar-Chiral Rhodium(III) Catalyst with a Sterically Demanding Cyclopentadienyl Ligand and Its Application in the Enantioselective Synthesis of Dihydroisoquinolones

(2018) Evgeniya A. Trifonova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Readily Accessible Class of Chiral Cp Ligands and their Application in RuII -Catalyzed Enantioselective Syntheses of Dihydrobenzoindoles

(2018) Shou-Guo Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Late stage modifications of P-containing ligands using transition-metal-catalysed C–H bond functionalisation

(2018) Zhuan Zhang et al.   CHEMICAL COMMUNICATIONS

Stereoselective arene formation

(2018) Achim Link et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Tailored trisubstituted chiral CpxRhIII catalysts for kinetic resolutions of phosphinic amides

(2018) Y. Sun et al.   Chemical Science

Catalyst-Controlled Stereoselective Synthesis of Atropisomers

(2018) Bouthayna Zilate et al.   ACS Catalysis

Theoretical Elucidation of Potential Enantioselectivity in a Pd-Catalyzed Aromatic C–H Coupling Reaction

(2017) Yoshio Nishimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

P(O)R2-Directed Enantioselective C–H Olefination toward Chiral Atropoisomeric Phosphine–Olefin Compounds

(2017) Shi-Xia Li et al.   ORGANIC LETTERS

Ir(III)-Catalyzed Direct C–H Functionalization of Arylphosphine Oxides: A Strategy for MOP-Type Ligands Synthesis

(2017) Zhong Liu et al.   ORGANIC LETTERS

Ketene Aminal Phosphates: Competent Substrates for Enantioselective Pd(0)-Catalyzed C–H Functionalizations

(2017) Daria Grosheva et al.   ACS Catalysis

Enantioselective Synthesis of Indole-Based Biaryl Atropisomers via Palladium-Catalyzed Dynamic Kinetic Intramolecular C–H Cyclization

(2017) Congfa He et al.   ACS Catalysis

Rhodium(III)-Catalyzed Enantiotopic C−H Activation Enables Access to P -Chiral Cyclic Phosphinamides

(2016) Yang Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals

(2016) Pauline Loxq et al.   COORDINATION CHEMISTRY REVIEWS

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands

(2016) Christopher G. Newton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes

(2016) Jun Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Monophosphorus Ligands for Asymmetric Catalytic Reactions

(2016) Wenzhen Fu et al.   ACS Catalysis

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Enantioselective CH Arylation for the Synthesis of P-Stereogenic Compounds

(2015) Zi-Qi Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp*Rh(iii) and Cp*Ir(iii)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols

(2015) Shang-Shi Zhang et al.   CHEMICAL COMMUNICATIONS

TADDOL-based phosphorus(iii)-ligands in enantioselective Pd(0)-catalysed C–H functionalisations

(2015) Julia Pedroni et al.   CHEMICAL COMMUNICATIONS

Pd(II)-Catalyzed Enantioselective Synthesis of P-Stereogenic Phosphinamides via Desymmetric C–H Arylation

(2015) Zhi-Jun Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of P-Stereogenic Phosphinic Amides via Pd(0)-Catalyzed Enantioselective Intramolecular C–H Arylation

(2015) Lantao Liu et al.   ORGANIC LETTERS

Dual role of carboxylic acid additive: mechanistic studies and implication for the asymmetric C–H amidation

(2015) Donghyeon Gwon et al.   TETRAHEDRON

Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization

(2015) Guangqing Xu et al.   Organic Chemistry Frontiers

Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes

(2014) Jun Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of binaphthyl based phosphine and phosphite ligands

(2013) Mariette M. Pereira et al.   CHEMICAL SOCIETY REVIEWS

Asymmetric C(sp2)H Activation

(2013) Joanna Wencel-Delord et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic C–H coupling with hindered arylboronic acids by Pd/Fe dual catalysts

(2013) Kazuya Yamaguchi et al.   Chemical Science

Recent development of direct asymmetric functionalization of inert C–H bonds

(2013) Chao Zheng et al.   RSC Advances

Chiral Monodentate Phosphines and Bulky Carboxylic Acids: Cooperative Effects in Palladium-Catalyzed Enantioselective C(sp3)-H Functionalization

(2012) Tanguy Saget et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Hindered biaryls by C–H coupling: bisoxazoline-Pd catalysis leading to enantioselective C–H coupling

(2012) Kazuya Yamaguchi et al.   Chemical Science

The Synthesis of Chiral Phosphorus Ligands for use in Homogeneous Metal Catalysis

(2011) Susan Lühr et al.   ChemCatChem

Palladium(0)-Catalyzed Arylative Dearomatization of Phenols

(2011) Sophie Rousseaux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalytic Reactions Using P*-Mono-, P*,N- and P*,P*-Bidentate Diamidophosphites with BINOL Backbones and 1,3,2-Diazaphospholidine Moieties: Differences in the Enantioselectivity

(2010) Konstantin N. Gavrilov et al.   ADVANCED SYNTHESIS & CATALYSIS

A General and Special Catalyst for Suzuki-Miyaura Coupling Processes

(2010) Wenjun Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Diastereoselective Route to Dinaphtho[c,e][1,2]oxaphosphinines and Their Application as Ligands in Homogeneous Catalysis

(2010) Ivan A. Shuklov et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Modular Furanoside Phosphite-Phosphoroamidites, a Readily Available Ligand Library for Asymmetric Palladium-Catalyzed Allylic Substitution Reactions. Origin of Enantioselectivity

(2009) Eva Raluy et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Enantioselective α-Arylation and α-Vinylation of Oxindoles Facilitated by an Axially Chiral P-Stereogenic Ligand

(2009) Alexander M. Taylor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY