Highly Enantioselective Intermolecular Cross Rauhut-Currier Reaction Catalyzed by a Multifunctional Lewis Base Catalyst

Enantioselective Organocatalyzed Formal [4+2] Cycloaddition of Ketimines with Allenoates: Easy Access to a Tetrahydropyridine Framework with a Chiral Tetrasubstituted Stereogenic Carbon Center

(2014) Shinobu Takizawa et al.   Asian Journal of Organic Chemistry

The Roles of Counterion and Water in a Stereoselective Cysteine-Catalyzed Rauhut-Currier Reaction: A Challenge for Computational Chemistry

(2013) Sílvia Osuna et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphine-Catalyzed Rauhut-Currier Domino Reaction: A Facile Strategy for the Construction of Carbocyclic Spirooxindoles Skeletons

(2013) Chongchong Hu et al.   Chemistry-An Asian Journal

Domino Cyclization Initiated by Cross-Rauhut-Currier Reactions

(2013) Peizhong Xie et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rauhut–Currier Reaction of Nitroalkenes with Vinyl Sulfones

(2013) Rahul Kumar et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Chemoselective Rauhut–Currier Reaction between Maleimides and Enones and Dual Phosphine-Mediated One-Pot Synthesis of Bicyclic and Polycyclic Skeletons

(2013) Rong Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric catalytic aza-Morita–Baylis–Hillman reaction for the synthesis of 3-substituted-3-aminooxindoles with chiral quaternary carbon centers

(2013) Fang-Le Hu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Heterocyclic Spiranes and Dispiranes via Enantioselective Phosphine-Catalyzed [3+2] Annulations

(2012) Deepti Duvvuru et al.   ADVANCED SYNTHESIS & CATALYSIS

Chiral Phosphine Catalyzed Asymmetric Michael Addition of Oxindoles

(2012) Fangrui Zhong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric [4+2] Annulation Initiated by an Aza-Rauhut-Currier Reaction: Facile Entry to Highly Functionalized Tetrahydropyridines

(2012) Zugui Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of α-Alkylidene-γ-Butyrolactones: Intramolecular Rauhut-Currier Reaction Promoted by Acid/Base Organocatalysts

(2012) Shinobu Takizawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[4+2] Annulation of Vinyl Ketones Initiated by a Phosphine-Catalyzed Aza-Rauhut-Currier Reaction: A Practical Access to Densely Functionalized Tetrahydropyridines

(2012) Zugui Shi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphine-Catalyzed Rauhut-Currier Domino Reaction: A Facile Strategy for the Construction of Highly Functionalized Cyclopentene

(2012) Chongchong Hu et al.   Chemistry-An Asian Journal

A Highly Nucleophilic Multifunctional Chiral Phosphane-Catalyzed Asymmetric Intramolecular Rauhut-Currier Reaction

(2012) Xiao-Nan Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Regiodivergent Allylic Alkylations of MBH Carbonates with Phthalides

(2012) Fangrui Zhong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New multifunctional chiral phosphines and BINOL derivatives co-catalyzed enantioselective aza-Morita–Baylis–Hillman reaction of 5,5-disubstituted cyclopent-2-enone and N-sulfonated imines

(2012) Yuan-Liang Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Intramolecular Formal [2 + 4] Annulation of Acrylates and α,β-Unsaturated Imines Catalyzed by Amino Acid Derived Phosphines

(2012) Zhichao Jin et al.   ORGANIC LETTERS

Asymmetric Construction of Functionalized Bicyclic Imides via [3 + 2] Annulation of MBH Carbonates Catalyzed by Dipeptide-Based Phosphines

(2012) Fangrui Zhong et al.   ORGANIC LETTERS

Enantioselective synthesis of spirocyclic cyclopentenes: asymmetric [3+2] annulation of 2-arylideneindane-1,3-diones with MBH carbonates derivatives catalyzed by multifunctional thiourea–phosphines

(2012) Fangle Hu et al.   TETRAHEDRON

Facile synthesis of α-methylidene-γ-butyrolactones: intramolecular Rauhut–Currier reaction promoted by chiral acid–base organocatalysts

(2012) Shinobu Takizawa et al.   TETRAHEDRON

Highly enantioselective [4 + 2] annulations catalyzed by amino acid-based phosphines: Synthesis of functionalized cyclohexenes and 3-spirocyclohexene-2-oxindoles

(2012) Fangrui Zhong et al.   Chemical Science

Chiral phosphine-squaramide-catalyzed Morita–Baylis–Hillman reaction: enantioselective synthesis of 3-hydroxy-2-oxindoles

(2012) Jing-Ying Qian et al.   RSC Advances

Enantioselective Intermolecular Rauhut-Currier Reaction of Electron-Deficient Allenes with Maleimides

(2011) Qian-Yi Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Versatile Enantioselective [3+2] Cyclization between Imines and Allenoates Catalyzed by Dipeptide-Based Phosphines

(2011) Xiaoyu Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective [3+2] Annulation of Morita-Baylis-Hillman Adducts Mediated by L-Threonine-Derived Phosphines: Synthesis of 3-Spirocyclopentene-2-oxindoles having Two Contiguous Quaternary Centers

(2011) Fangrui Zhong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene-Promoted Rauhut - Currier Reactions between Vinyl Sulfones and α,β-Unsaturated Aldehydes

(2011) Roxanne L. Atienza et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Enantioselective Intramolecular Crossed Rauhut-Currier Reactions through Cooperative Nucleophilic Activation and Hydrogen-Bonding Catalysis: Scope and Mechanistic Insight

(2011) Xu-Fan Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Substrate-Controlled, Phosphine-Catalyzed Domino Reactions of Activated Conjugated Dienes: Highly Diastereoselective Synthesis of Bicyclic Skeletons

(2011) Jianze Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bifunctional N-Acyl-Aminophosphine-Catalyzed Asymmetric [4+2] Cycloadditions of Allenoates and Imines

(2011) Hua Xiao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diastereo- and Enantioselective Construction of γ-Butenolides through Chiral Phosphane-Catalyzed Allylic Alkylation of Morita-Baylis-Hillman Acetates

(2011) Yin Wei et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Core-Structure-Motivated Design of a Phosphine-Catalyzed [3 + 2] Cycloaddition Reaction: Enantioselective Syntheses of Spirocyclopenteneoxindoles

(2011) Bin Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective [3 + 2] Cycloaddition of Allenes to Acrylates Catalyzed by Dipeptide-Derived Phosphines: Facile Creation of Functionalized Cyclopentenes Containing Quaternary Stereogenic Centers

(2011) Xiaoyu Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Morita–Baylis–Hillman reaction promoted by l-threonine-derived phosphine–thiourea catalysts

(2011) Xiaoyu Han et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Bifunctional phosphine-catalyzed cross-Rauhut–Currier/Michael/aldol condensation triple domino reaction: synthesis of functionalized cyclohexenes

(2011) Peizhong Xie et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Multifunctional chiral phosphines-catalyzed highly diastereoselective and enantioselective substitution of Morita–Baylis–Hillman adducts with oxazolones

(2011) Yuan-Liang Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

l-Threonine-Derived Novel Bifunctional Phosphine−Sulfonamide Catalyst-Promoted Enantioselective Aza-Morita−Baylis−Hillman Reaction

(2011) Fangrui Zhong et al.   ORGANIC LETTERS

Tandem cross-Rauhut–Currier/cyclization reactions of activated alkenes to give densely functionalized 3,4-dihydropyrans

(2011) Wen Liu et al.   TETRAHEDRON

Quasi-biomimetic ring contraction promoted by a cysteine-based nucleophile: Total synthesis of Sch-642305, some analogs and their putative anti-HIV activities

(2011) Alpay Dermenci et al.   Chemical Science

Enantioselective carbon–sulfur bond formation: γ additions of aryl thiols to allenoates catalyzed by a chiral phosphepine

(2011) Yuji Fujiwara et al.   Chemical Science

Aromatic hydroxyl group—a hydrogen bonding activator in bifunctional asymmetric organocatalysis

(2011) Pankaj Chauhan et al.   RSC Advances

Catalytic Asymmetric Intramolecular Cascade Reaction for the Construction of Functionalized Benzobicyclo[4.3.0] Skeletons. Remote Control of Enantioselectivity

(2010) Qing-Gang Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric [3+2] Cycloadditions of Allenoates and Dual Activated Olefins Catalyzed by Simple Bifunctional N-Acyl Aminophosphines

(2010) Hua Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Isoindolines: An Organocatalyzed Domino Process Based On the aza-Morita-Baylis-Hillman Reaction

(2010) Shinobu Takizawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective intramolecular Rauhut–Currier reaction catalyzed by chiral phosphinothiourea

(2010) Jing-Jing Gong et al.   CHEMICAL COMMUNICATIONS

Development of a Cysteine-Catalyzed Enantioselective Rauhut−Currier Reaction

(2010) Carrie E. Aroyan et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphine-Catalyzed Formation of Carbon−Sulfur Bonds: Catalytic Asymmetric Synthesis of γ-Thioesters

(2010) Jianwei Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rauhut–Currier type homo- and heterocouplings involving nitroalkenes and nitrodienes

(2010) Pramod Shanbhag et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective intramolecular Morita–Baylis–Hillman reaction using chiral bifunctional phosphinothiourea as an organocatalyst

(2010) Kui Yuan et al.   TETRAHEDRON-ASYMMETRY

Enantioselective Trifunctional Organocatalysts for Rate- Enhanced Aza-Morita-Baylis-Hillman Reactions at Room Temperature

(2009) Jean-Marc Garnier et al.   ADVANCED SYNTHESIS & CATALYSIS

Tertiary Amine Mediated Tandem Cross-Rauhut-Currier/Acetalization Reactions: Access to Functionalized Spiro-3,4-Dihydropyrans

(2009) Weijun Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-Catalyzed Enantioselective Synthesis of Oxygen Heterocycles

(2009) Ying Kit Chung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intermolecular Crossed-Conjugate Additions between Nitroalkenes and α,β-Enals through a Dual Activation Strategy

(2009) Cheng Zhong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amide-based bifunctional organocatalysts in asymmetric reactions

(2009) Xiaohua Liu et al.   CHEMICAL COMMUNICATIONS

Asymmetric Carbon−Carbon Bond Formation γ to a Carbonyl Group: Phosphine-Catalyzed Addition of Nitromethane to Allenes

(2009) Sean W. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crossed Intramolecular Rauhut−Currier-Type Reactions via Dienamine Activation

(2009) Eugenia Marqués-López et al.   ORGANIC LETTERS

The Rauhut–Currier reaction: a history and its synthetic application

(2009) Carrie E. Aroyan et al.   TETRAHEDRON

Valine-derived phosphinothiourea as organocatalyst in enantioselective Morita–Baylis–Hillman reactions of acrylates with aromatic aldehydes

(2009) Jing-Jing Gong et al.   TETRAHEDRON-ASYMMETRY

Total Synthesis of (−)-Spinosyn A:  Examination of Structural Features That Govern the Stereoselectivity of the Key Transannular Diels−Alder Reaction

(2008) SusAnn M. Winbush et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Phosphine-Catalyzed Enantioselective Construction of γ-Butenolides Through Substitution of Morita−Baylis−Hillman Acetates with 2-Trimethylsilyloxy Furan

(2008) Ying-Qing Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

2-Phospha[3]ferrocenophanes with Planar Chirality: Synthesis and Use in Enantioselective Organocatalytic [3 + 2] Cyclizations

(2008) Arnaud Voituriez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative, Highly Enantioselective Phosphinothiourea Catalysis of Imine−Allene [3 + 2] Cycloadditions

(2008) Yuan-Qing Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid-Catalyzed Conjugate Additions of Silyloxyallenes: A Selective Solution to the Intermolecular Rauhut−Currier Problem

(2008) Troy E. Reynolds et al.   ORGANIC LETTERS

Chiral phosphinothiourea organocatalyst in the enantioselective Morita–Baylis–Hillman reactions of aromatic aldehydes with methyl vinyl ketone

(2008) Kui Yuan et al.   TETRAHEDRON LETTERS

Dendritic Chiral Phosphine Lewis Bases-Catalyzed Asymmetric Aza-Morita–Baylis–Hillman Reaction ofN-Sulfonated Imines with Activated Olefins

(2007) Ying-hao Liu et al.   ADVANCED SYNTHESIS & CATALYSIS