期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 31, 页码 6271-6279出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201200940
关键词
Multifunctional chiral phosphanes; Rauhut-Currier reaction; Cyclopentene derivatives; Cyclohexene derivatives; Organocatalysis; Cyclization; Asymmetric synthesis
资金
- Shanghai Municipal Committee of Science and Technology [11JC1402600]
- National Basic Research Program of China [(973)-2010CB833302]
- Fundamental Research Funds for the Central Universities
- National Natural Science Foundation of China [20928001, 21072206, 20472096, 20872162, 20672127, 21121062, 20732008]
An asymmetric variant of the intramolecular RauhutCurrier (RC) reaction can be achieved using a highly nucleophilic multifunctional chiral phosphane; the corresponding cyclopentene and cyclohexene derivatives are produced in moderate to good yields and with good to excellent enantioselectivities.
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